Copper(I) hydride complexes often exhibit diverse aggregation behavior that can profoundly influence their structure and reactivity. In this study we use a combined experimental and computational approach to identify key structural an electronic factors that govern aggregation in PNNP dicopperhydride complexes.
Roel Laurentius Maria Bienenmann +5 more
wiley +1 more source
From CO<sub>2</sub> to C<sub>1</sub> Liquid Fuels: Molecular Electrochemical Production of Formic Acid and Methanol. [PDF]
Karapapa P, Mondal S, Zeglio E, Das B.
europepmc +1 more source
in Reactive Hydride Composites Containing Complex Borohydrides.
Ruediger Bormann +3 more
core +1 more source
Synthesis of Dithienylcycloalkene Molecular Switches Enabled by a Bench‐Stable Ti‐Complex
Herein we report a set of cycloalkene‐bridged DTEs with ring sizes ranging from 4‐ to 7‐membered rings. The synthesis of these analogs was performed via a key McMurry coupling step, which was enabled by a practical, bench‐stable Ti(IV)‐complex. Remarkably, it is shown that the strained cyclobutene bridge outperforms other rings, even the most commonly ...
Marcell M. Bogner +4 more
wiley +1 more source
Room-Temperature Thermal Cycling Driven Pyro-Catalysis over g-C<sub>3</sub>N<sub>4</sub>/ZnO Composites for Efficient Dye Degradation. [PDF]
Cheng C +8 more
europepmc +1 more source
ABSTRACT Over the past twenty years, main group chemistry has significantly expanded its scope to include reactivities once considered the exclusive domain of transition metals. Among the emerging concepts, element‐ligand cooperation has proven to be a powerful strategy for enabling bond activation reactions but remains relatively unexplored for ...
Lennart Hensle, Viktoria H. Gessner
wiley +1 more source
Enhanced environmental remediation through hybrid adsorption-photocatalysis using ZnO/TiO<sub>2</sub>-CaAlg composite catalysts. [PDF]
Ammouchi N +14 more
europepmc +1 more source
Alkene Hydrogenation by a Cationic, Nine‐Coordinate Molybdenum(VI) Pentahydride Catalyst
While late 3d metals dominate efforts to replace precious metals in homogeneous hydrogenation, molybdenum has remained largely ignored. This work reveals that a nine‐coordinate pentahydrido molybdenum complex can hydrogenate a broad range of alkenes efficiently, demonstrating that early‐metal polyhydrides can serve as genuine catalysts rather than mere
Arno Estival +9 more
wiley +1 more source
DFT study on tunable electronic and adsorption properties of poly(vinyl alcohol)/copper oxide/graphene oxide hybrid nanostructures. [PDF]
Ibrahim A +3 more
europepmc +1 more source
Monosubstituted N‐arylhydroxylamines represent a unique subclass of hydroxylamines that act as pivotal intermediates in redox transformations and as versatile platforms for further synthetic transformations. They serve as key building blocks in the synthesis of architecturally complex heterocycles and other valuable organic compounds.
Michael G. Kallitsakis +2 more
wiley +1 more source

