Results 121 to 130 of about 9,678 (253)

Arene Incorporation and Ring Expansion in the Thermal Decomposition of a Divanadium(III) Complex With Four Bridging Methyl Groups

Chemistry – A European Journal, EarlyView.
Thermolysis of [{VCp*(µ‐CH3)2}2] (Cp* = η5‐C5Me5) in hexane leads to a tetranuclear cube‐type methylidene complex [{VCp*(µ3‐CH2)}4], while in benzenic solvents C6H5R produces the formal insertion of a CH fragment into the six‐membered aromatic ring of a solvent molecule to give trovacene derivatives with η7‐cycloheptatrienyl ligands [VCp*(η7‐C7H6R ...
Adrián Calvo‐Molina, Rodrigo González‐Prieto, Jesús Jover, Adrián Pérez‐Redondo, José Luis Priego, Carlos Yélamos   +5 more
wiley   +1 more source

An efficient mechanochemical synthesis of alpha-aluminum hydride: Synergistic effect of TiF3 on the crystallization rate and selective formation of alpha-aluminum hydride polymorph [PDF]

, 2019
Cao, Yizheng, Duan, Congwen, Fu, Dong, Hu, Lianxi, Ma, Jinlong, Youngblood, Jeffrey   +5 more
core  

Spectral and Acoustic Characterization of Nanoenergetic Devices Based on Sodium Perchlorate-Impregnated Porous Silicon. [PDF]

Nanomaterials (Basel)
Apaza Quispe A, Bueno Borges AC, Salcedo WJ.   +2 more
europepmc   +1 more source

Synthesis and Isolation of Bismuth Scorpionate Complexes: Toward Bond Activation via Bismuth‐Ligand Cooperation

Chemistry – A European Journal, EarlyView.
ABSTRACT Over the past twenty years, main group chemistry has significantly expanded its scope to include reactivities once considered the exclusive domain of transition metals. Among the emerging concepts, element‐ligand cooperation has proven to be a powerful strategy for enabling bond activation reactions but remains relatively unexplored for ...
Lennart Hensle, Viktoria H. Gessner
wiley   +1 more source

Metal Nanoparticles on Halloysite Applied in Stereoselective Hydrogenation of Tetrasubstituted Alkenes

Chemistry – A European Journal, EarlyView.
Composite materials based on metal nanoparticles supported on a naturally occurring nanotubular clay, halloysite (HAL), led to the diastereoselective hydrogenation of tetra‐substituted alkenes under relatively smooth conditions, mainly oxazolidinone‐based heterocycles.
Rosa Pich, Gabriel Domínguez, Leo Westrey, Pierre Lavedan, Sonia Mallet‐Ladeira, Jérôme Esvan, Jean‐François Lahitte, Jean‐Christophe Remigy, Daniel Pla, Montserrat Gómez   +9 more
wiley   +1 more source

Reversible H₂ storage at moderate temperature by a trilayered lithium borohydride nanocomposite. [PDF]

Nat Commun
Zhang W, Zhang X, Li C, Zhang L, Liu H, Lou Z, Huang Z, Xia G, Gao M, Sun W, Liu Y, Pan H.   +11 more
europepmc   +1 more source

Unlocking Heterobimetallic Architectures in a Symmetric PNNP Ligand Environment

Chemistry – A European Journal, EarlyView.
A symmetric PNNP ligand enables the modular assembly of heterobimetallic ZnRu and CoRu complexes from a mononuclear Ru(II) precursor. Ligand deprotonation triggers dearomatization and contraction of the metal–metal distance. Combined DFT and QTAIM analyses reveal metallophilic interaction in CoRu but not in ZnRu, highlighting controllable geometric and
Stanislav Melnikov, Menne W. P. Verkooijen, Jop Verduin, Martin Lutz, Daniël L. J. Broere   +4 more
wiley   +1 more source

Regulation of hydrogen and oxidative stress in treating intestinal mucosa from ulcerative colitis. [PDF]

Int J Pharm X
Yu N, Xu J, Fan J, Gao H, Wu T, Zhu Y, Xu J, Li X, Xu H, Lu X.   +9 more
europepmc   +1 more source

Alkene Hydrogenation by a Cationic, Nine‐Coordinate Molybdenum(VI) Pentahydride Catalyst

Chemistry – A European Journal, EarlyView.
While late 3d metals dominate efforts to replace precious metals in homogeneous hydrogenation, molybdenum has remained largely ignored. This work reveals that a nine‐coordinate pentahydrido molybdenum complex can hydrogenate a broad range of alkenes efficiently, demonstrating that early‐metal polyhydrides can serve as genuine catalysts rather than mere
Arno Estival, Michel Sigrist, Nicolas Queyriaux, Jorge J. Cabrera‐Trujillo, Nina Durvin, Marie‐Christine Boegli, Laure Vendier, Mary Grellier, Karinne Miqueu, Antoine Simonneau   +9 more
wiley   +1 more source

Functional Cement-Based Composites Materials for Future Applications. [PDF]

Materials (Basel)
Oti J.
europepmc   +1 more source