Results 141 to 150 of about 9,678 (253)

Enhanced environmental remediation through hybrid adsorption-photocatalysis using ZnO/TiO<sub>2</sub>-CaAlg composite catalysts. [PDF]

open access: yesRSC Adv
Ammouchi N   +14 more
europepmc   +1 more source

Monosubstituted N‐Arylhydroxylamine Chemistry: Integrating Contemporary Synthetic Approaches for the Efficient Construction of Diverse Heterocyclic Scaffolds

open access: yesChemistry – A European Journal, EarlyView.
Monosubstituted N‐arylhydroxylamines represent a unique subclass of hydroxylamines that act as pivotal intermediates in redox transformations and as versatile platforms for further synthetic transformations. They serve as key building blocks in the synthesis of architecturally complex heterocycles and other valuable organic compounds.
Michael G. Kallitsakis   +2 more
wiley   +1 more source

State‐of‐the‐Art and Synthetic Challenges for Hydrosilane Production

open access: yesChemistry – A European Journal, EarlyView.
The synthesis of hydrosilanes is currently energy intensive and their recycling is not considered. However, these compounds are important in many industrial fields but also for the valorization of oxygenated waste, towards a circular economy. This review compares the available synthetic routes and highlights the remaining challenges for the production ...
Gabriel Durin   +3 more
wiley   +1 more source

An Electron‐Poor Nickel Diphosphine Complex: Synthesis, Structure, and Reactivity of Ni(dFppe)2

open access: yesChemistry – A European Journal, EarlyView.
Fluorinated diphosphine ligands such as 1,2‐bis[bis(pentafluorophenyl)phosphino]ethane (dFppe) offer powerful electronic tunability and unusual reactivity. Despite known analogues of the heavier congeners Pd and Pt, Ni complexes of dFppe remain conspicuously absent.
A. Dina Dilinaer, Marcus W. Drover
wiley   +1 more source

Lewis‐Acidic Properties and Catalytic Behavior of Hydroboration‐ and Diolysis‐Derived NHC‐Stabilized Borenium Cations

open access: yesChemistry – A European Journal, EarlyView.
A series of thirteen (N‐heterocyclic carbene) NHC‐stabilized borenium cations is synthesized from NHC→BH3 complexes via hydroboration and condensation with diols. The novel compounds are fully characterized. Eight crystal structures are presented. Kinetic and NMR data show how the structural features translate to catalytic activity in hydrosilylation ...
Michał Jakubczyk   +4 more
wiley   +1 more source

Cationic Sulfonium‐Based Tripodal Ligand and Its Rh(I) Complexes

open access: yesChemistry – A European Journal, EarlyView.
We report a cationic EP3‐type tripodal ligand based on an aromatic sulfonium cation (E = S+) along with a series of its Rh(I) complexes. Structural, spectroscopic, electrochemical, and computational analyses of these complexes compared to isostructural analogs (E = Si− or P) reveal pronounced electron density depletion at Rh in the sulfonium congener ...
Nitsan Barel   +5 more
wiley   +1 more source

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