Synergistic effects of nano SnO<sub>2</sub> and TiO<sub>2</sub> on the mechanical and antibacterial properties of HDPE. [PDF]
Syala E +3 more
europepmc +1 more source
The Role of Iron‐Hyponitrite Intermediates in Biology and Insights From Synthetic Model Complexes
Despite the difference in active site architecture, NO reduction by different NOR enzymes is expected to be linked by a common intermediate: hyponitrite (N2O22−). However, experimentally, very little is known about the coordination chemistry of iron with hyponitrite and the expected Fe‐hyponitrite intermediates.
Michael O. Lengel, Nicolai Lehnert
wiley +1 more source
Adsorptive and photocatalytic strategies for carmoisine removal: mechanisms, material innovations, and environmental implications. [PDF]
Arif M.
europepmc +1 more source
Late‐Stage Modification of Halotryptophan‐Containing Peptides Via Negishi Cross‐Coupling
Negishi cross‐coupling provides access to the late‐stage functionalization of bromotryptophan‐containing peptides under comparatively mild conditions and is applicable to a range of peptide substrates in the investigated model systems. The examined alkyl iodides and variation of N‐terminal residues demonstrate the feasibility of the transformation in a
Laura Cerveson +2 more
wiley +1 more source
Flame-Retardant Properties of a Styrene-Vinyl Tetrazole Copolymer Additive in an LDPE/EVA Blend. [PDF]
Ramírez KFR +8 more
europepmc +1 more source
Organo‐functionalized molecular molybdenum sulfides were synthesized using bidentate N‐donor ligands and investigated as light‐driven homogeneous hydrogen evolution reaction (HER) catalysts. Trends observed in the HER activity of these catalysts were elucidated by combining photophysical, electrochemical and computational studies.
Moritz Jahn +9 more
wiley +1 more source
Oxidative Generation and Reactivity of the Cyclopropyl Radical From a Martin Silicate
A photoredox strategy employing Martin silicates enables the oxidative generation and controlled capture of cyclopropyl radicals, including the naked one, long considered challenging intermediates. The method affords functionalized cyclopropanes through both Giese‐type additions and dual nickel/photoredox C(sp3)−C(sp2) cross‐couplings.
Amal Lakhal +3 more
wiley +1 more source
Graphitic Carbon Nitride in Oral Health: Emerging Applications, Antimicrobial Potential, and Future Perspectives. [PDF]
Paltinean GA +7 more
europepmc +1 more source
Catalyst‐Free Selective Reduction of Nitrogen Dioxide to Nitric Oxide
Common main group reductants selectively convert nitrogen dioxide to nitric oxide in a catalyst‐free manner. Computational studies suggest divergent reaction pathways depending on the reductant employed. Where boranes and silanes proceed via a two‐electron process, and hydrogen surrogates undergo stepwise one‐electron processes.
Awais W. Seyyad +3 more
wiley +1 more source

