Ligand‐Level Chemical Activation: Coordination with Benefits
While often perceived as a liability, ligand‐based reactivity in carefully designed settings becomes a powerful synthetic tool. The key to streamlined processes overriding classical ionic reactivity is the selective electron redistribution induced by metal coordination. This enables storage of electrons and protons or incorporation of functional groups
Oscar Charpentier +2 more
wiley +1 more source
High-Yield Precursor-Derived Si-O Ceramics: Processing and Performance. [PDF]
Zhang X, Xiao B, Hou Y, Wen G.
europepmc +1 more source
Synthesis of ferrocenyl thioketone‐functionalized triphenylamine and triphenylamine‐(bi)thiophene derivatives as proligands for the assembly of artificial [FeFe]‐hydrogenase active site models. Thiocarbonyl compounds, especially thioketones, have emerged as promising precursors for constructing [FeFe]‐hydrogenase mimics that can mediate hydrogen ...
Hassan Abul‐Futouh +5 more
wiley +1 more source
Synthetic Strategies for High Dielectric Constant Silicone Elastomers [PDF]
Madsen, Frederikke Bahrt
core
One-Pot Synthesis for Doped Amorphous Carbon-Based Compounds: Influence of ZnO Dopant on the Charge Transfer Efficiency. [PDF]
Vargas-Vidal BA +4 more
europepmc +1 more source
Push–Pull Ynamines and Push–Pull Ynamides: Synthesis, Structure, Reactivity, and Application
Push–pull ynamines and push–pull ynamides, which carry an EWG and an amino or amido group as EDG, are highly interesting classes of EDG‐EWG alkynes that have been intensively studied due to their exceptional reactivity. In this review, the synthesis, structure, reactivity, and application of push–pull ynamines, push–pull ynecarbamates, push–pull ...
Hans‐Joachim Gais
wiley +1 more source
Recent Advances of g-C<sub>3</sub>N<sub>4</sub>/LDHs Composite Photocatalysts in Water Pollution Treatment. [PDF]
Li J, Guo Y, Bai J.
europepmc +1 more source
1,1‐Disubstituted vinylbromides are key intermediates for constructing nitrogen‐containing heterocycles. This review provides an overview of the synthetic applications of 1,1‐disubstituted vinylbromides and summarizes recent developments in reaction methodologies, mechanistic insights, and the structural diversity of N‐heterocyclic compounds accessible
Anne Westermeyer +6 more
wiley +1 more source
Functional evaluation of compatibilization systems for recycled PP-PET blends [PDF]
Delva, Laurens +4 more
core
Reduced Metal-Codoped TiO<sub>2</sub>/LSX Zeolite Catalysis: A Sustainable Solution for Crystal Violet Dye Degradation. [PDF]
Jogezai Z +8 more
europepmc +1 more source

