Hydrides as high capacity anodes in lithium cells: an Italian “Futuro in Ricerca di Base FIRB-2010” project [PDF]
Automotive and stationary energy storage are among the most recently-proposed and still unfulfilled applications for lithium ion devices. Higher energy, power and superior safety standards, well beyond the present state of the art, are actually ...
Brutti, Sergio +10 more
core +4 more sources
Role of additives in LiBH4–MgH2 reactive hydride composites for sorption kinetics [PDF]
The influence of additives on the reaction kinetics and microstructure refinement in LiBH4–MgH2 composites is investigated in detail. Indications of the rate-limiting processes during the reactions are obtained by comparison of the measured reaction kinetics with simulations with one specific rate-limiting process.
Bösenberg, Ulrike +14 more
openaire +2 more sources
Microstructural study of the LiBH4–MgH2 reactive hydride composite with and without Ti-isopropoxide additive [PDF]
Ministerio de Ciencia e Innovación CTQ2009 ...
Deprez, E. +8 more
openaire +4 more sources
Polymer-stable magnesium nanocomposites prepared by laser ablation for efficient hydrogen storage [PDF]
Hydrogen is a promising alternative energy carrier that can potentially facilitate the transition from fossil fuels to sources of clean energy because of its prominent advantages such as high energy density (142 MJ per kg), great variety of potential ...
A.K. Stubos +68 more
core +2 more sources
Microstructural study of hydrogen desorption in 2NaBH4 + MgH2 reactive hydride composite
Abstract The desorption mechanism of as-milled 2NaBH 4 + MgH 2 was investigated by volumetric analysis, X-ray diffraction and electron microscopy. Hydrogen desorption was carried out in 0.1 bar hydrogen pressure from room temperature up to 450 °C at a heating rate of 3 °C min −1 . Complete dehydrogenation was achieved in two steps releasing 7.84 wt.
Nwakwuo, C +4 more
openaire +2 more sources
Hydrogen absorption study of high-energy reactive ball milled Mg composites with palladium additives [PDF]
Hydrogenation behaviour, structure, morphology and dehydrogenation/re-hydrogenation performances of Mg–Pd nanocomposites prepared by high-energy reactive ball milling in H2 (HRBM) of Mg in the presence of amorphous and crystalline Pd black (0.1–5 wt ...
Lototskyy, Mykhaylo +3 more
core +1 more source
On the chemical state and distribution of Zr- and V-based additives in reactive hydride composites [PDF]
Reactive hydride composites (RHCs) are very promising hydrogen storage materials for future applications due to their reduced reaction enthalpies and high gravimetric capacities. At present, the materials' functionality is limited by the reaction kinetics.
Boesenberg, U. +8 more
openaire +4 more sources
Hydrogen Motion in Magnesium Hydride by NMR [PDF]
In coarse-grained MgH2, the diffusive motion of hydrogen remains too slow (
Bormann, Rüdiger +11 more
core +1 more source
Sorption and desorption properties of a CaH2/MgB2/CaF2 reactive hydride composite as potential hydrogen storage material [PDF]
The hydrogenation behavior of 3CaH{sub 2}+4MgB{sub 2}+CaF{sub 2} composite was studied by manometric measurements, powder X-ray diffraction, differential scanning calorimetry and attenuated total reflection infrared spectroscopy. The maximum observed quantity of hydrogen loaded in the composite was 7.0 wt%.
K. Suarez Alcantara +7 more
openaire +2 more sources
Characterization of LiBH4–MgH2 Reactive Hydride Composite System with Scattering and Imaging Methods Using Neutron and Synchrotron Radiation [PDF]
Reversible solid‐state hydrogen storage in metal hydrides is a key technology for pollution‐free energy conversion systems. Herein, the LiBH2–MgH2 composite system with and without ScCl3 additive is investigated using synchrotron‐ and neutron‐radiation‐based probing methods that can be applied to characterize such lightweight metal–hydrogen systems ...
Fahim Karimi +11 more
openaire +2 more sources

