Results 41 to 50 of about 4,379 (197)
, 2015 Combinations of complex metal borohydrides ball milled with the transition metal complex hydride, Mg2FeH6, are analysed and compared. Initially, the Reactive Hydride Composite (RHC) of Mg2+ cation mixtures of Mg2FeH6 and γ-Mg(BH4)2 is combined in a range
Stefano Deledda +19 more
core +1 more source
A Strong Lewis Acidic Diethylsilylium Catalyst for Direct Sulfonamidation of Challenging Ketones
Advanced Science, EarlyView.Low‐substitution‐order silylium ions (R2HSi+) exhibit exceptional Lewis acidic activity. We report diethylsilylium‐catalyzed reductive sulfonamidation of functionalized ketones to access β‐amino esters. The in situ generated ion pair shows enhanced reactivity, with diethylsilane serving as both reductant and precatalyst. The developed protocol proceeds
Woo Hee Kim +5 more
wiley +1 more source
Preparation and characterization of borohydrides-based reactive hydride composites (RHCs)
, 2011 The preparation by high energy mechanical milling and the chemico-physical characterization of different reactive hydride composites (borohydride-MgH2 based) is ...
Pellicer, E +16 more
core
, 2018 Solid-state hydride compounds are a promising option for efficient and safe hydrogen-storage systems. Lithium reactive hydride composite system 2LiBH4 + MgH2/2LiH + MgB2 (Li-RHC) has been widely investigated owing to its high theoretical hydrogen ...
Michael Krumrey (1421116) +17 more
core +1 more source
Junction Physics and Architectural Paradigms in Optoelectronic Semiconductor Fibers
Advanced Science, EarlyView.Optoelectronic fibers are emerging as a key platform for distributed sensing, energy harvesting, and optical communication in deformable systems. Their performance is fundamentally governed by junction formation under confined, dynamic processing conditions.
Hailiang Wang +4 more
wiley +1 more source
Adaptive Coordination Engineering for Efficient and Robust H2 Release
Advanced Science, EarlyView.β‐H elimination is a pivotal but challenging step in homogeneous formic acid dehydrogenation reactions due to strict hydride‐metal matching. By using a rationally designed Pd1Ag2 bimetallic system with adaptive Pd1‐Ag2/L2 coordination and formate bridges, it enables boosted formic acid dehydrogenation under ambient air (7.7 times higher than a Pd ...
Xiaolin Jiang +8 more
wiley +1 more source
Composite Materials for Hazard Mitigation of Reactive Metal Hydrides. [PDF]
, 2012 In an attempt to mitigate the hazards associated with storing large quantities of reactive metal hydrides, polymer composite materials were synthesized and tested under simulated usage and accident conditions.
Pratt, Joseph William +4 more
core
Exceptional CO2 Hydrogenation to Gasoline Enabled by GaZrOx/Ga‐ZSM‐5 Tandem Catalyst
Advanced Science, EarlyView.A GaZrOx/Ga‐ZSM‐5 tandem catalyst achieves 17.2% CO2 conversion with 83.2% C5+ selectivity and >400 h stability relies on optimized O‐vacancies and Ga‐H coverage for CO2 hydrogenation. ABSTRACT CO2 hydrogenation to gasoline offers a promising route for addressing energy challenges and enabling the effective utilization of carbon resources. However, the
Wenhui Li +5 more
wiley +1 more source
Mechanochemistry Meets Catalysis: Metal Complexes for Greener Organic Transformations
Angewandte Chemie, EarlyView.Mechanochemistry is redefining metal catalysis by controlling catalyst formulation, speciation, and deployment. This Review shows how milling, LAG, RAM, and TSE enable rapid metal‐complex assembly, distinctive catalytic manifolds, and scalable synthesis beyond solution chemistry.
Sourav Behera +2 more
wiley +2 more sources
Advanced Science, EarlyView.Rational engineering of terminal substituents in symmetric azobenzene‐based molecules enables precise control over conformationally coupled charge‐transfer processes. This design yields tunable nonvolatile resistive memory behaviors, ranging from write‐once‐read‐many‐times (WORM) to rewritable switching.
Yanze Liu +11 more
wiley +1 more source