Results 61 to 70 of about 4,379 (197)

AI‐Assisted IoT‐Enabled ECG Monitoring: Integrating Foundational and Generative AI Tools for Sustainable Smart Healthcare—Recent Trends

AI &Innovation, EarlyView.
ABSTRACT The rapid evolution of the Internet of Things (IoT) has significantly advanced the field of electrocardiogram (ECG) monitoring, enabling real‐time, remote, and patient‐centric cardiac care. This paper presents a comprehensive survey of AI assisted IoT‐based ECG monitoring systems, focusing on the integration of emerging technologies such as ...
Amrita Choudhury, Kandarpa Kumar Sarma, Lachit Dutta   +2 more
wiley   +1 more source

Isolation of a Highly Reactive CBNC Heterocumulene via Azidoborylene Photolysis: Facile Access to a Crystalline Dioxaborirane

Angewandte Chemie, EarlyView.
Azidoborylene photolysis results in the isolation of a reactive C═B═N═C heterocumulene bearing an ambiphilic boron centre. Addition of 3O2 to this species results in the clean conversion to a unique example of a dioxaborirane. ABSTRACT Oxidation of the formal boron(0) complex MeCAAC2B in the presence of tetrabutylammonium azide leads to the formation ...
Hayley King, Vignesh Pattathil, William Kennedy, Robert K. Szilagyi, Conor Pranckevicius   +4 more
wiley   +2 more sources

Structural and kinetic investigation of the hydride composite $\mathrm{Ca(BH_{4})_{2} + MgH_2}$ system doped with $\mathrm{NbF_5}$ for solid-state hydrogen storage [PDF]

, 2015
Designing safe, compact and high capacity hydrogen storage systems is the key step towards introducing a pollutant free hydrogen technology into a broad field of applications. Due to the chemical bonds of hydrogen–metal atoms, metal hydrides provide high
Martin Tolkiehn, Chiara Milanese, Vainio, U., Stefan Boerrie, Emmler, T., Klassen, Thomas, P. Klaus Pranzas, Emmler, Thomas, Minella, Christian B., Dornheim, Martin, Andreas Schreyer, Enzo, S., Chaudhary, Anna-Lisa, Tolkiehn, Martin, Milanese, C., Tolkiehn, M., Antonio Santoru, Buckley, Craig E., Ulla Vainio, Karimi, F., Santoru, Antonio, Rapee Utke, Klaus Pranzas, P., Klassen, T., Schreyer, Andreas, Minella, C., Thomas Emmler, Utke, R., Claudio Pistidda, Vainio, Ulla, Chaudhary, Anna Lisa, Craig E. Buckley, Buckley, Craig, Pranzas, P. Klaus, Julian A. Puszkiel, Puszkiel, Julián A., Boerries, S., Martin Dornheim, Boerries, Stefan, Anna Lisa Chaudhary, Milanese, Chiara, Paskevicius, M., Thomas Klassen, Karimi, Fahim, Fahim Karimi, Chaudhary, A., Schreyer, A., Chaudhary, A. L., Mark Paskevicius, Pistidda, Claudio, Utke, Rapee, Buckley, C. E., Enzo, Stefano, Santoru, A., Puszkiel, Julián Atilio, Puszkiel, J., Pistidda, C., Christian B. Minella, Dornheim, M., Minella, C. B., Paskevicius, Mark   +60 more
core   +1 more source

Enantioselective Synthesis of a New Class of Stable and Functionalized Cyclopentadienes via CuH‐Catalysis

Angewandte Chemie, EarlyView.
Cyclopentadienes (CpHs) are fundamental building blocks with widespread applications in chemistry. However, their inherent acidity and isomeric instability have long limited access to chiral variants in an asymmetric fashion. Here, we introduce a CuH‐catalyzed asymmetric transformation that provides an unprecedented entry into a new class of ...
Piero Soppelsa, Riccardo Bellin, Besma Boulila, Francesco Vaghi, Manuel Orlandi   +4 more
wiley   +2 more sources

1,7‐Digallatetracarborane: Between Nucleophilic closo‐Cluster and “Inverse Sandwich” Digallylene

Angewandte Chemie, EarlyView.
A dianionic π‐ligand is used to make a Janus‐type twofold complex with low‐valent gallium Ga(+I). The resulting compound can be seen as and reveals the reactivity of both: a Wade‐type closo‐carborane cluster with nucleophilic Ga‐sites, as well as π‐ligand stabilized Ga(I) atoms in an inverse sandwich compound.
Julijan Sarcevic, Tobias Heitkemper, Niklas Mehner, Maximilian Kubis, Christian P. Sindlinger   +4 more
wiley   +2 more sources

In-Situ Deposition of Alkali and Alkaline Earth Hydride Thin Films To Investigate the Formation of Reactive Hydride Composites

, 2016
We investigate the critical steps in the formation of Ca(BH4)2 starting from CaH2−MgB2 thin films. As a first step, thin films of CaH2 are successfully deposited by reactive sputtering using a mixture of Ar/H2 as sputter plasma. The films are analyzed by
M. J. van Setten (2005999), M. Gonzalez-Silveira (1284696), B. Dam (2238379), W. Lohstroh (2274478), R. Gremaud (2274475), H. Schreuders (2238382), E. Batyrev (2274481), A. Rougier (2274490), E. G. Bardají (2274487), L. Dupont (2274484)   +9 more
core   +1 more source

Heavier Alkyne‐Ni0 Complexes, [R2E2·Ni] (E = Sn, Pb), Exhibiting σ‐Complex Character

Angewandte Chemie, EarlyView.
Using a reductive group elimination strategy, heavier alkyne (LEEL; E = Sn, Pb) complexes of Ni0 are accessed. In contrast to classical alkyne coordination, these systems are best described as σ‐complexes, driven by ligand‐induced constraints and the established poor π‐bonding in heavier alkyne analogues.
Leopold Junge, Emeric Schubert, Israel Fernández, Terrance J. Hadlington   +3 more
wiley   +2 more sources

Thermal Decomposition of Mn(BH₄)₂–M(BH₄)_x and Mn(BH₄)₂–MH_x Composites with M = Li, Na, Mg, and Ca

, 2016
The aim of this study is to investigate the thermal decomposition and hydrogen release of salt-free manganese borohydride composites with metal hydrides and metal borohydrides of lithium, sodium, magnesium, and calcium.
Torben R. Jensen (1267908), Elsa Roedern (1441402)   +1 more
core   +1 more source

Attractive Ni…O Interactions Enable Non‐Alternating Ethylene‐Carbon Monoxide Copolymerization

Angewandte Chemie, EarlyView.
Attractive Ni···O interactions are established in phosphine‐imidated and phosphine‐phenolate nickel catalysts, enabling non‐alternating ethylene‐carbon monoxide copolymerization, resulting in superior CO tolerance, productivity and stability compared to the state‐of‐the‐art benchmark.
Yajun Zhao, Michele Tomasini, Inigo Göttker‐Schnetmann, Laura Falivene, Lucia Caporaso, Stefan Mecking   +5 more
wiley   +2 more sources

Polarity‐Directed Synthesis of an Exfoliable 2D Polyoxometalate‐Based Metal‐Organic Framework for Noble Metal‐Free Alkyne Transfer Semi‐Hydrogenation

Angewandte Chemie, EarlyView.
Exfoliation of 2D nanosheets based on polyoxometalate metal‐organic frameworks (POMOFs) gives access to nanostructures with selective catalytic reactivity for the alkyne transfer semi‐hydrogenation which outperform the bulk references and rival some classical noble metal‐based catalysts.
Xusheng Dai, Yalei Zhang, Yue Zhao, Shujun Li, Nana Ma, Qingchun Xia, Yiwei Liu, Rongji Liu, Shuxia Liu, Xuenian Chen, Carsten Streb   +10 more
wiley   +2 more sources