Results 131 to 140 of about 2,420,955 (221)

Step‐Associated Cu‐Ceria Interfaces Enhance Catalytic Activity and Selectivity

Angewandte Chemie, EarlyView.
The catalytic activity and selectivity of supported Cu nanoparticles depends on their interfacial environments, with Cu nanoparticles at step‐associated environments converting CO2 to methanol much faster than those on terrace facets, indicating that step sites create more active metal–oxide interfaces.
Shuxuan Feng, Shan Jiang, Chengyu Song, Chaochao Dun, Yang Deng, Hao Xu, Zihao Zhang, Xiong He, Temitayo Ojuetimi Ikuerowo, Mark R. Hoffmann, Jeffrey T. Miller, Yong Wang, Weixin Huang   +12 more
wiley   +2 more sources

Autonomous AI‐Driven Design for Skin Product Formulations

Advanced Intelligent Discovery, EarlyView.
This review presents a comprehensive closed‐loop framework for autonomous skin product formulation design. By integrating artificial intelligence‐driven experiment selection with automated multi‐tiered assays, the approach shifts development from trial‐and‐error to intelligent optimisation.
Yu Zhang, Yongrui Xiao, Chunlin Chen, Dimitrios Tsaoulidis, Kai Yang, Tao Chen   +5 more
wiley   +1 more source

Modulating Covalent Organic Framework Nanochannel Microenvironments for Sustainable Hydrogen Peroxide Photosynthesis

Angewandte Chemie, EarlyView.
Alkoxy side chains regulate hydrazone‐linked COF nanochannel microenvironments by tuning pore polarity, reactant adsorption, and charge‐separation behavior. The optimized framework facilitates oxygen activation and hydrogen peroxide photosynthesis in real water and a 1 L natural‐sunlight reactor. LCA further shows that natural sunlight and larger‐scale
Ruixue Sun, Shaoyang Gao, Luqiao Feng, Peixuan Xie, Wenyu Shen, Nikita Rog, Marwan Mohammed, Qi Huang, Giulio Santori, Xianfeng Fan, Bien Tan, Cher Hon Lau   +11 more
wiley   +2 more sources

Revealing Hidden Raman Signatures Through Attention‐Based Spectral Unmixing

Advanced Intelligent Systems, EarlyView.
Weak Raman signatures are recovered from background‐dominated spectra using a transformer‐based, reference‐free spectral unmixing AI framework. Self‐attention reconstructs substrate contribution directly from mixed data, enabling reliable extraction of previously inaccessible vibrational features.
Dmitriy A. Poteryayev, Pietro Novelli, Annalisa Coriolano, Riccardo Dettori, Valentina Tozzini, Fabio Beltram, Massimiliano Pontil, Antonio Rossi, Stiven Forti, Camilla Coletti   +9 more
wiley   +1 more source

Electrocatalytic Polarity Inversion of Azlactones: Access to α‐Quaternary Amino Acids with Electron‐Rich SOMOphiles

Angewandte Chemie, EarlyView.
Electrocatalytic polarity inversion of azlactones unlocks their coupling with electron‐rich reaction partners. Triarylamine‐mediated oxidation of the azlactone enolate generates an electrophilic radical intermediate that undergoes selective C4 functionalization with diverse SOMOphiles.
Paula Rodríguez, David Buedo, Alberto Vega‐Peñaloza, Kian Gosling, Stuart C. D. Kennington, Bart Limburg, Xavier Companyó   +6 more
wiley   +2 more sources

Covalent Organic Framework Colloids With Core‐Shell Donor/Acceptor Architecture and Ultralong‐Lived Charge‐Separated States

Angewandte Chemie, EarlyView.
Uniform core‐shell colloidal particles of Covalent Organic Frameworks (COFs) are synthesized by a seeded growth of electron‐acceptor COF shells on electron‐donor COF cores. The resulting p‐n heterojunction enables efficient separation of photogenerated charges, which persist for minutes. These core‐shell COFs show efficient CO2 photoreduction to CO and
Ting Yu, Cory Ruchlin, Tong Li, Mohammad Hossein Gohari, Zhechang He, Zeina Chamseddine, Chang Wan Kang, Dongling Ma, Dmytro F. Perepichka   +8 more
wiley   +2 more sources

Pathway Complexity Defines the Shape of Nucleic Acid‐Loaded Polyion Complex Micelles: Spheroids vs. Hexagonal Disks

Angewandte Chemie, EarlyView.
Same building blocks, different destinies. Pathway complexity directs nucleic acid–loaded polyion complex micelles along distinct assembly trajectories, resulting in either hexagonally shaped or spheroidal nanoparticles with distinct internal structuring.
Lennart van den Hoven, Neshat Moslehi, Eline F. Brink, Austin Hubley, Ilja K. Voets, Tina Vermonden, Elham Mirzahossein, Bas G. P. van Ravensteijn   +7 more
wiley   +2 more sources

Natural Sunlight IR‐Driven Highly Efficient Synthesis of Acetaldehyde From Bioethanol Over Cu/Fe2O3

Angewandte Chemie, EarlyView.
This work reports a Cu/Fe2O3 catalyst for the conversion of bioethanol into valuable acetaldehyde and green hydrogen under both infrared (IR) light and natural sunlight. This IR‐driven system sets a new performance benchmark, with TON and initial TOF enhanced by at least one order of magnitude, enabled by a constructed IR photon‐to‐phonon channel and ...
Xiyi Li, Jiangting Zhao, Junjun Guo, Ze‐Kai Yu, Enqi Chen, Qiong Liu, Tieou Wang, Asterios Gavriilidis, Xue‐Qing Gong, Yang Lan, Junwang Tang   +10 more
wiley   +2 more sources

Separation and Valorization of Chlorine From Tail Gas Streams

Angewandte Chemie International Edition, EarlyView.
A commercially available ion exchange resin was found to adsorb chlorine gas selectively in the presence of other gases reversibly forming the corresponding trichloride species [IEx][Cl3]. This discovery was telescoped to an efficient process for the recycling and valorization of chlorine from industrially abundant tail gas streams to base chemicals ...
Gesa H. Dreyhsig, Merlin Kleoff, Patrick Voßnacker, Elisabeth Dorn, Jacob H. Richter, Sebastian Riedel   +5 more
wiley   +1 more source

Bioconvective Unsteady Casson Hybrid Nanofluid Flow on a Variable Darcy Regime Between Two Rotating Disks With Variable Heat Source

Asia-Pacific Journal of Chemical Engineering, EarlyView.
ABSTRACT This study carries significant consequences in various engineering applications, such as cooling rotating disk surfaces, improving chemical reactor performance, and designing filtration systems. Considering these main applications in view, the aim of this study is to investigate time‐dependent Casson hybrid nanofluid flow on a permeable ...
Ebrahem A. Algehyne, Abdul Bariq, Mounirah Areshi, Fahad Maqbul Alamrani, Zehba Raizah, Izharul Haq, Anwar Saeed   +6 more
wiley   +1 more source