A linker‐desymmetrization‐modulator‐compensation (LDMC) strategy for constructing structurally diverse Zr‐MOFs is reported. This approach reduces linker symmetry to create defects in Zr‐clusters, which can be compensated for by modulator coordination. Using this approach, we synthesized PCN‐1005 and PCN‐1006, featuring unprecedented Zr‐clusters. In PCN‐
Rong‐Ran Liang +8 more
wiley +1 more source
Propuesta de estabilización química de la red vial terciaria del municipio de Cogua
La malla vial terciaria del municipio de Cogua presenta un deterioro continuo, por falta de definición de una alternativa de solución que permita mejorar las condiciones de transitabilidad y el desarrollo agrícola del sector rural, reduciendo los costos de mantenimiento en los vehículos y de igual manera reduciendo el tiempo de desplazamiento de un ...
openaire +1 more source
Hacia un abordaje interdisciplinario del sistema vial : medidas efectivas y de alto impacto [PDF]
Fil: Campana, Juan M. Universidad de Buenos Aires. Facultad de Ingeniería; Argentina.La seguridad vial no puede abordarse únicamente desde la óptica de la infraestructura porque un sistema vial está conformado por tres importantes componentes: la ...
Campana, Juan M.
core
Porous Iridium Oxide Inverse Opal Catalysts Enable Efficient PEM Water Electrolysis
Porous iridium‐based inverse opal (IrOx‐IO) structures are introduced as high‐performance, unsupported PEM‐WE anode catalysts. Their electrochemical behavior is analyzed through porosity/surface area tuning, voltage breakdown, and circuit modeling.
Sebastian Möhle +4 more
wiley +1 more source
An Application for Through-Vial Impedance Spectroscopy (TVIS) in the Qualification of the Pirani-Gauge Assessment of the Ice Sublimation Endpoint. [PDF]
Wijesekara PS +3 more
europepmc +1 more source
Eutectozymes as Soft Hybrid Materials for Advanced Biocatalysis
Eutectozymes are sustainable hybrid materials that embed a GOx–HRP cascade within hydrophobic eutectogels featuring a dual supramolecular–covalent network. This architecture preserves native enzyme structure and stability, enables efficient heterogeneous biocatalysis in aqueous media, and positions eutectogels as robust platforms for next‐generation ...
Manuel Eduardo Martinez Cartagena +10 more
wiley +1 more source
Economics of compliance for mixing allergy immunotherapy. [PDF]
Trapanotto KI +3 more
europepmc +1 more source
High Charge Carrier Mobility in Non‐Conjugated 3D Covalent Organic Frameworks
A non‐conjugated 3D COF constructed via boronate ester linkages from tetraphenylene and pyrene‐based monomers is reported, which exhibits a high charge carrier mobility of 14 ± 1 cm2 V−1 s−1. ABSTRACT π‐Conjugation, π–π stacking, and long‐range order play a central role in determining charge transport efficiency in organic materials.
Joaquín Almarza +11 more
wiley +1 more source
Seven-Coordinate Lanthanide Bis-Halide Bis-Tetrathiometallate Complexes: A Compelling Platform for Luminescent and Magnetic Properties. [PDF]
Perrin MA +8 more
europepmc +1 more source
The selective hydrogenation of acetylene over laterally condensed Pd and Pd–Au catalysts (LCCs) was investigated using operando X‐ray absorption and photoelectron spectroscopy in combination with density functional theory. Pd‐LCCs were found to incorporate significantly more carbon into the metal lattice than Pd–Au LCCs, where the carbon uptake governs
Eylül Öztuna +22 more
wiley +1 more source

