Results 171 to 180 of about 3,063,283 (292)

Bolapolyphiles With Bulky Carbosilane‐Based Lateral Groups—Reticular Design of Liquid Crystalline Pentagonal Honeycombs

open access: yesChemistry – A European Journal, EarlyView.
T‐shaped bolapolyphiles with highly branched carbosilane‐based side‐groups self‐assemble into liquid crystalline honeycombs composed of type‐2 pentagonal prismatic cells and p2gg plane group symmetry. ABSTRACT Periodic pentagon tessellations are rarely observed in self‐assembled molecular systems.
Christian Anders   +3 more
wiley   +1 more source

Persilylated and Related Silyl Anion‐Induced Synthesis of Group 3–10 Metal–Silyl Complexes

open access: yesChemistry – A European Journal, EarlyView.
Persilylated and related silyl anions serve as powerful tools for constructing metal–silyl complexes across group 3–10 elements. Their strong σ‐donating ability and steric bulk stabilize low‐coordinate, reactive species and enable unique bonding motifs.
Yusuke Sunada
wiley   +1 more source

A Solid‐Phase Approach to Chiral C2‐Substituted Cyclen and DOTA‐Like Lanthanoid Ligands

open access: yesChemistry – A European Journal, EarlyView.
Chiral C2‐substituted cyclen derivatives have been designed and synthesized from chiral cyclic peptoids. Their conversion into the corresponding DOTA‐type ligands opens new avenues for the development of high‐relaxivity MRI contrast agents. ABSTRACT Magnetic resonance imaging (MRI) is a powerful diagnostic modality that relies on Gd+3‐based contrast ...
Rosaria Schettini   +9 more
wiley   +1 more source

Self‐Assembly of a Chiral Pyrene–Bifuran–Imide Into Helical and Spherical Nanostructures

open access: yesChemistry – A European Journal, EarlyView.
A chiral bifuran–imide derivative (1‐Py2) functionalized with pyrene units and an L‐alanine side chain exhibits solvent‐switchable self‐assembly. Increasing water fraction drives a transition from chiral helical fibers with periodic tail‐to‐tail bilayer packing to achiral nanospheres with orange photoluminescence.
Hadar R. Yakir   +5 more
wiley   +1 more source

A Trans‐1,2‐Diphenyl‐Substituted EDTA Platform for High‐Relaxivity Mn(II) MRI Probes

open access: yesChemistry – A European Journal, EarlyView.
Symmetric diphenyl substitution of the EDTA backbone enhances the rigidity of the Mn(II) complex and enables strong multisite interactions, providing a versatile platform for further functionalisation and conjugation towards high‐performance Mn(II)‐based MRI contrast agents.
Federico Forgione   +7 more
wiley   +1 more source

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