Nucleophilic Gallyl Anions Enable Ga─Au Bimetallic Ammonia Activation
Angewandte Chemie, EarlyView.Unlocking gallyl nucleophiles: Counterion control enables formation of an unsupported gallyl─gold complex. Gold coordination induces a polarity switch at gallium, enabling cooperative activation of NH3 and related N─H/O─H substrates under mild conditions.
Hellen Videa +3 more
wiley +2 more sources
A natural deduction system for the Byzantine Generals Oral Messages algorithm. [PDF]
Acta InformVolpano DM.
europepmc +1 more source
Unlocking a Nitrosuccinate Lyase for Decarboxylative Enzymatic Hydronitration
Angewandte Chemie, EarlyView.The nitrosuccinate lyase CreD catalyzes C–NO2 bond formation using nitrite in water and shows synthetic practicality with high turnover numbers up to 102,000. A combination of protein engineering and computational methods helped to reveal the mechanistic principles that underpin this unique enzymatic activity.
Matteo Aleotti +9 more
wiley +2 more sources
Integrated physiological and molecular insights into photosynthetic responses of maize following relay-cropping of tobacco. [PDF]
Front Plant SciMa R +13 more
europepmc +1 more source
Cobalt‐Catalyzed Radical Ligand Transfer (RLT) Enables Remote‐Markovnikov Hydroamination of Alkenes
Angewandte Chemie, EarlyView.A cobalt‐catalyzed remote‐Markovnikov 1,3‐hydroamination of allyl carboxylates proceeds through MHAT, 1,2‐radical acyloxy migration (1,2‐RAM), and radical ligand transfer (RLT) from a Co‐N intermediate, providing protected amino alcohols. ABSTRACT Amino alcohols are prevalent in pharmaceuticals, agrochemicals, and functional materials, yet ...
Arman Khosravi +7 more
wiley +2 more sources
A Deep Learning-Assisted Multi-Relay DCSK Communication System. [PDF]
Sensors (Basel)Huang T, Hong S, Chen J, Kang L.
europepmc +1 more source
An Optimized Clustering Routing Algorithm for Wireless Sensor Networks Based on Spotted Hyena and Improved Energy-Efficient Non-Uniform Clustering. [PDF]
Sensors (Basel)Jia S, Jia S, Shao W, Li F.
europepmc +1 more source
A Novel Directional Element for AC Lines in Systems with Inverter-Based Resources. [PDF]
Sensors (Basel)Qian K, Wen M, Xue X, Sun Z.
europepmc +1 more source
A Reliable and Secure Cluster-Routing Framework for Drone-Assisted Disaster Management in Smart Cities. [PDF]
Sensors (Basel)Alwasel B +4 more
europepmc +1 more source
Multi-Probing Opportunistic Routing in Buffer-Constrained Wireless Sensor Networks. [PDF]
Sensors (Basel)Sun N, Cao S, Liu X, Gao Y, Xu Y, Liu J.
europepmc +1 more source