Zero‐Valent Nickel Stabilized in Surface‐Supported Metal–Organic Chains
9,10‐Dicyanoanthracene coordinates Ni atoms on Ag(100) to form metal–organic chains that stabilize zero‐valent Ni(0) (d10) centers with quasi‐one‐dimensional metal–ligand electronic coupling. ABSTRACT The stabilization of zero‐valent nickel Ni(0) centers in extended coordination networks remains a major challenge due to their pronounced reactivity and ...
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