Results 21 to 30 of about 882 (198)

Water Permeates and Plasticizes Amorphous Carbon Dots: Unraveling the Inner Accessibility of the Nanoparticles by Glass Transition Studies

Advanced Materials, EarlyView.
The water permeability of amorphous carbon dots (CDs) is demonstrated by investigating their plasticization. Novel polyamide‐based and amorphous nanoparticles are synthesized by controlling their inner packing density. Water plasticization is evidenced by the decrease of the CDs glass transition temperature with increasing the hydration degree.
Elisa Sturabotti, Valerio Di Lisio, Lucia Cardo, Alessandro Camilli, Estela Moretón Alfonsín, Daniele Cangialosi, Amaia Iturrospe Ibarra, Arantxa Arbe, Maurizio Prato   +8 more
wiley   +1 more source

Solvent‐Free Thermal Defect Engineering in Molecular Frameworks With Volatile Linkers

Advanced Materials, EarlyView.
Thermal removal of neutral volatile linkers enables precise and solvent‐free generation of metal vacancies in MOFs. This strategy affords redox‐stable, coordinatively unsaturated FeII sites with tunable spin, ligand coordination, and catalytic behavior. The approach offers a general route to design defect‐functional materials through local coordination
Sonia Martínez‐Giménez, Alejandro Orellana‐Silla, Marta Galbiati, Efrén Navarro‐Moratalla, Luca Braglia, Sara Stolfi, José Antonio Real, Víctor Rubio‐Giménez, Sergio Tatay, Carlos Martí‐Gastaldo   +9 more
wiley   +1 more source

Design Principles for Fluid Molecular Ferroelectrics

Advanced Materials, EarlyView.
A major challenge for soft condensed matter is predicting whether a fluid molecular material will form ferroelectric phase with nematic or smectic order. Through systematic synthesis, and by analogy to solid molecular ferroelectrics, it is shown that subtle hydrogen–fluorine (H/F) substitution(s) allows for tuneable syn‐parallel pairing motifs ...
Calum J. Gibb, Jordan Hobbs, William C. Ogle, Richard. J. Mandle   +3 more
wiley   +1 more source

Resolving Heterogeneity of Targeted Lipid Nanoparticles Through Solution‐Based Biophysical Analyses

Advanced Materials, EarlyView.
AF4‐UV‐DLS‐MALS‐SAXS resolves previously inaccessible targeted lipid nanoparticle (tLNP) subpopulations that differ in size, shape, and composition. Correlation of subpopulation‐resolved biophysical properties with in vivo RNA delivery reveals that targeted placental transfection is associated with distinct tLNP subpopulations rather than ensemble ...
Hannah C. Geisler, Hannah C. Safford, Ajay S. Thatte, Marshall S. Padilla, Elisa Battistini, Hannah M. Yamagata, Violet M. Ullman, Alex Chan, Benjamin E. Nachod, Anushka Agrawal, Maxwell B. Watkins, Jesse B. Hopkins, Andrew Tsourkas, Kushol Gupta, Michael J. Mitchell   +14 more
wiley   +1 more source

Can Elastomers Combine Stiffness, Toughness and Fatigue Resistance?

Advanced Materials, EarlyView.
This review studies how the molecular and macroscopic architecture of elastomers influence their mechanical properties including: stiffness, stretchability, toughness, fatigue resistance, and damping behavior. By linking the structure to performance, it proposes design principles for advanced elastomeric systems that combine mechanical properties ...
Eva Baur, Esther Amstad
wiley   +1 more source

High‐Entropy Ceramic‐Enhanced Deformable Triboelectric Nanogenerator for Noncontact Biomechanical and Raindrop Energy Harvesting

Advanced Materials, EarlyView.
A large‐area, deformable high‐entropy‐ceramic (HEC)‐doped triboelectric nanogenerator with a trilayer architecture is developed, consisting of an HEC‐doped triboelectric layer, a graphite‐like textile charge‐storage layer, and stretchable carbon black electrodes.
Shengyou Li, Wei‐Chen Peng, Syun‐Hong Chou, Zhi‐Xian Yan, Jiann‐Yeu Chen, Dun‐Jie Jhan, Wei‐Chun Yang, Shi‐Hong Chen, Yi‐Lin Huang, Cheng‐Hung Tsai, Ming‐Yen Lu, Heng‐Jui Liu, Cheolmin Park, Ying‐Chih Lai   +13 more
wiley   +1 more source

A Chemical Framework for Engineering Extracellular Vesicles’ Biointerface to Advance Precision Therapeutics

Advanced Materials, EarlyView.
Extracellular vesicles (EVs) are cell‐derived nanoparticles that mediate intercellular communication through their dynamic biointerfaces. Owing to their intrinsic biological functions, EVs have emerged as promising platforms for biomedical applications.
Leila Pourtalebi Jahromi, Felix Geng, Jan‐Noël Frenzke, Gregor Fuhrmann   +3 more
wiley   +1 more source

Negotiating in a Foreign Land: Understanding the Curious Interactions Between Intracellular Mitochondria and Internalized Nanoparticles

Advanced Materials Interfaces, EarlyView.
Therapeutic nano‐drug delivery systems interact with cellular mitochondria in a multitude of ways. While the complexity of such interactions disrupts the mitochondrial electron transport chain and increases reactive oxygen species production, thereby contributing to nanoparticle toxicity, they also present unique theranostic opportunities in diseases ...
Sourav Bhattacharjee
wiley   +1 more source

Cyanide residues biotreatment and their relation with public health

Revista Facultad Nacional de Salud Pública, 2010
Objective: To propose a bio-treatment for cyanide residues generated by medico-legal procedures and to identify risk factors from handling. Methodology: cyanide residues, from the Institute of Legal Medicine, Medellin, were characterized by their physical state and identified its management, and risk factors.
Carmen L. Jaramillo C, Judith Betancur U, Ruth M. Agudelo C, Carmen L. Jaramillo C, Judith Betancur U, Ruth M. Agudelo C, Carmen L. Jaramillo C, Ruth M. Agudelo C, Judith Betancur U   +8 more
openaire   +1 more source

Light Switchable Ionic Conductivity of Arylazopyrazole Modified Polysiloxanes

Advanced Materials Technologies, EarlyView.
We present a polysiloxane functionalized with a novel arylazopyrazole dye that undergoes reversible photoisomerization. Upon lithium bis(trifluoromethanesulfonyl)imide addition and UV irradiation, the polymer exhibits a shift in tan(d) toward higher frequencies and enhanced ionic conductivity.
Malte S. Beccard, Thulasinath Raman Venkatesan, Michael Bauer, Valentin Razvan Lupu, Philipp Scheidegger, Francesco Taddei, Frank A. Nüesch, Dorina M. Opris   +7 more
wiley   +1 more source