Isohexide and sorbitol-derived, enzymatically synthesized renewable polyesters with enhanced Tg [PDF]
Sugar-based polyesters derived from sorbitol and isohexides were obtained via solvent-free enzymatic catalysis. Pendant hydroxyl groups, coming from the sorbitol units, were present along the polyester backbone, whereas the two isohexides, namely ...
Gustini, Liliane +4 more
core +2 more sources
Block copolymers of poly(L-lactide) and poly(ε-caprolactone) or poly(ethylene glycol) prepared by reactive extrusion [PDF]
Blends of poly(L-lactide) (PLLA) and poly(-caprolactone) (PCL) were prepared in a co-rotating twin screw miniextruder (40 rpm, 200°). It was attempted to prepare multiblock copolymers by allowing a controlled number of transesterification reactions ...
Bernard, A. +4 more
core +3 more sources
Testing of residual monomer content reduction possibility on acrilic resins quality [PDF]
Poly (methyl methacrylate) (PMMA) is material widely used in dentistry. Despite the various methods used to initiate the polymerization of acrylic resins, the conversion of monomer to polymer is not complete thus leaving some unreacted methyl ...
Kostić Milena +8 more
doaj +1 more source
Copper(0)-mediated radical polymerisation in a self-generating biphasic system [PDF]
Herein, we demonstrate the synthesis of well-defined poly(n-alkyl acrylate)s via copper(0)-mediated radical polymerisation in a self-generating biphasic system. During the polymerisation of n-butyl acrylate in DMSO, the polymer phase separates to yield a
Amir Atme +53 more
core +1 more source
Safety assessment of the substance dimethyl carbonate for use in food contact materials [PDF]
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Bolognesi, Claudia +24 more
core +3 more sources
Structure of rabbit liver fructose 1,6-bisphosphatase at 2.3 Å resolution [PDF]
The three-dimensional structure of the R form of rabbit liver fructose 1,6-bisphosphatase (Fru-1,6-Pase; E.C. 3.1.3.11) has been determined by a combination of heavy-atom and molecular-replacement methods.
Erman, M. +5 more
core +2 more sources
Background:The aim of this study was to evaluate the effect of adding four different monomers on the flexural strength, elastic modulus, impact strength and residual monomer content of denture base resins polymerized by copolymerization mechanism.Methods:
Ayşegül Köroğlu +4 more
doaj +1 more source
The ring-opening polymerization of D,L-lactide in the melt initiated with tetraphenyltin [PDF]
Melt polymerization conditions for D,L-lactide initiated with tetraphenyltin were studied with regard to polymer molecular weight and weight distributions.
Berg, J.W.A. van den +3 more
core +2 more sources
In the scientific context, the environmental and healthy impact of polymers is more related to the residual monomer content rather than their macromolecular structure, due to the monomer capability to interact with membrane cells. For this a novel method
Genny Pastore +6 more
doaj +1 more source
The effect of UDMA and Bis-GMA irradiation period on residual monomers in resin packable composite
Background: Residual monomers are non-polymerized monomers which can cause clinical harm, for example inflammation, to oral cavity tissue while the remaining monomers can potentially be carcinogenic.
Jayanti Rosha +3 more
doaj +1 more source

