Results 101 to 110 of about 55,441 (308)

Rhodium-Catalyzed Linear Codimerization and Cycloaddition of Ketenes with Alkynes

Molecules, 2010
A novel rhodium-catalyzed linear codimerization of alkyl phenyl ketenes with internal alkynes to dienones and a novel synthesis of furans by an unusual cycloaddition of diaryl ketenes with internal alkynes have been developed.
Teruyuki Kondo, Masatsugu Niimi, Yuki Yoshida, Kenji Wada, Take-aki Mitsudo, Yu Kimura, Akio Toshimitsu   +6 more
doaj   +1 more source

“Smelltronics”—From Gas to Smell Sensing

Advanced Materials, EarlyView.
The emerging field of smelltronics, encompassing sensing technologies for complex volatile organic compounds, holds significant potential for extracting valuable chemical information. It facilitates the noninvasive, real‐time monitoring of humans, food, and the environment.
Takeshi Ono, Tsunaki Takahashi, Jiangyang Liu, Haruka Honda, Zeng Jing, Wataru Tanaka, Takuro Hosomi, Takeshi Yanagida   +7 more
wiley   +1 more source

Rhodium-Catalyzed Alkenylation of Toluene Using 1‑Pentene: Regioselectivity To Generate Precursors for Bicyclic Compounds

, 2019
Rhodium catalysts for arene alkenylation reported by our group (e.g., Science 2015, 348, 421; J. Am. Chem. Soc. 2017, 139, 5474; J. Am. Chem. Soc. 2018, 140, 17007) have demonstrated selectivity for 1-aryl alkenes over y-aryl alkenes (y > 1).
William L. Schinski (7464140), Nichole S. Liebov (7464137), Michael S. Webster-Gardiner (2830571), Weihao Zhu (7026167), Junqi Chen (577869), T. Brent Gunnoe (1438375)   +5 more
core   +1 more source

Pulsed Laser‐Assisted Phase Engineering of Multimetallic Colloidal Nanocrystals With Complex Compositions

Advanced Materials, EarlyView.
The engineering of colloidal nanocrystals with complex compositions has emerged as a highly active area of research within nanomaterials science. This review covers key aspects of colloidal solid‐solution nanocrystal formation using pulsed laser irradiation.
Marina T. Candela, Sergio Triviño‐Sánchez, Andrés Guerrero‐Martínez, Luis M. Liz‐Marzán, Guillermo González‐Rubio   +4 more
wiley   +1 more source

Recent Progress in the Phase‐Controlled Synthesis of Ruthenium Nanocrystals for Catalytic Applications

Advanced Materials, EarlyView.
Template effect and kinetic control enable crystal‐phase engineering of Ru nanocrystals, granting access to either metastable fcc‐Ru or stable hcp‐Ru with distinct surface structures, thermal stabilities, and catalytic behaviors. Moreover, the hcp‐Ru can further serve as an epitaxial template to direct Pd and Rh nanocrystals into the metastable hcp ...
Jianlong He, Zhiqi Wang, Jiaqi Guan, Younan Xia   +3 more
wiley   +1 more source

Phase Engineering of Nanomaterials (PEN): Evolution, Current Challenges, and Future Opportunities

Advanced Materials, EarlyView.
This review summarizes the synthesis, phase transition, advanced characterization spanning ex situ to in situ and operando techniques, and diverse applications of phase engineering of nanomaterials (PEN). It further outlines key challenges and future opportunities, such as phase stability, architecture control, and artificial intelligence (AI)‐driven ...
Ye Chen, Zhanxi Fan, Jingjie Ge, Qiyuan He, Zhuangchai Lai, Jiawei Liu, Chaoliang Tan, Hua Zhang   +7 more
wiley   +1 more source

Extraction of rhodium from supported liquid-phase hydroformylation catalysts with supercritical carbon dioxide

Journal of CO2 Utilization
The continuous extraction of the rhodium inventory in supported liquid-phase (SLP) catalytic materials utilized in the hydroformylation (HyFo) of 1-butene was investigated by supercritical carbon dioxide (scCO2).
Mahtab Madani, Leonhard Schill, Blete Hulaj, Jakob Willner, Andreas Limbeck, Katharina Bica-Schröder, Rasmus Fehrmann, Anders Riisager   +7 more
doaj   +1 more source

Catalytic Decomposition of Nitrogen Oxides by Bimetallic Catalysts Synthesized by Dielectric Barrier Discharge Plasma Technology

E3S Web of Conferences, 2018
Nitrous oxide (N2O) is a common greenhouse gas and urgent need to be contained. Direct catalytic decomposition of N2O by high activity catalyst into N2 and O2 is a low-cost and harmless method.
Shi Libin, Qi Suitao, Jiao Tianyou, Qu Jifeng, Tan Xiao, Yi Chunhai, Yang Bolun   +6 more
doaj   +1 more source

Rhodium-Catalyzed 1,4-Addition of Arylboronic Acids to α,β-Unsaturated Carbonyl Compounds:  Large Accelerating Effects of Bases and Ligands

, 2016
The effects of ligands and bases in the rhodium(I)-catalyzed 1,4-addition of arylboronic acids to α,β-unsaturated carbonyl compounds were reinvestigated to carry out the reaction under mild conditions. Rhodium(I) complexes possessing a 1,5-cyclooctadiene
Yuki Iguchi (2884628), Norio Miyaura (2143414), Ryoh Itooka (3025221)   +2 more
core   +1 more source

Rational Tuning of Hygroscopic Oscillation of Stacked Nanoflake Assemblies for Continuous Ambient Energy Harvesting

Advanced Materials, EarlyView.
Stacked nanoflake assembly (SNA) membranes can oscillate autonomously, offering opportunities for soft actuation and energy harvesting. This work uncovers the physical mechanism behind the sustained oscillation of SNA membranes in gradient humidity and identifies three governing dimensionless parameters, enabling rational design for optimizing SNA ...
Zijing Zhang, Jimin Fu, Gesa Zhang, Zhihua Liang, Boxun Zhang, Haimin Yao   +5 more
wiley   +1 more source