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Recent Advances in Heterogeneous Hydroformylation at Metal–Oxide Interfaces [PDF]
MoleculesThis article reviews recent advances in heterogeneous hydroformylation, with a particular focus on rhodium-based catalysts supported on oxide surfaces.
Maxwell Gillum +6 more
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Morita–Baylis–Hillman modifications on hydroformylated (R)-limonene [PDF]
Royal Society Open ScienceWe report the sequential hydroformylation of (R)-limonene followed by Morita–Baylis–Hillman (MBH) coupling to give two new MBH adducts derived from methyl acrylate (adduct 1, 32% isolated yield) and acrylonitrile (adduct 2, 95% isolated yield).
José Ribeiro Gregório +3 more
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P(V)-Promoted Rh-Catalyzed Highly Regioselective Hydroformylation of Styrenes under Mild Conditions [PDF]
MoleculesHydroformylation of olefins is widely used in the chemical industry due to its versatility and the ability to produce valuable aldehydes with 100% atom economy.
Tong Ru +5 more
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Elucidation of hemilabile-coordination-induced tunable regioselectivity in single-site Rh-catalyzed heterogeneous hydroformylation [PDF]
Nature CommunicationsRevealing key factors that modulate the regioselectivity in heterogeneous hydroformylation requires identifying and monitoring the dynamic evolution of the truly active center under real reaction conditions. However, unambiguous in situ characterizations
Benhan Fan +11 more
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Monofluorophos–Metal Complexes: Ripe for Future Discoveries in Homogeneous Catalysis [PDF]
MoleculesThe discovery that cyclic (ArO)2PF can support Rh-catalysts for hydroformylation with significant advantages in tuning regioselectivity transformed the study of metal complexes of monofluorophos ligands from one of primarily academic interest to one with
Alexandra M. Miles-Hobbs +3 more
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Amino functionalized SBA-15 Loaded Rh Catalyst for Asymmetric Hydroformylation of Styrene [PDF]
E3S Web of Conferences, 2023 A recoverable Rh/N-SBA-15 heterogeneous catalyst for asymmetric hydroformylation of styrene was prepared by post grafting method. XRD, TG, 29Si MAS NMR and ICP characterization, revealed that the introduction of amino silane and RhCl3 had no adverse ...
Tao Yong +3 more
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Transition metal-catalyzed branch-selective hydroformylation of olefins in organic synthesis
Green Synthesis and Catalysis, 2021 Hydroformylation of olefins can generate linear and branched aldehydes, and the branched aldehydes are attractive precursors for the synthesis of fine chemicals and pharmaceuticals.
Yingtang Ning +2 more
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ChemTexts, 2021 AbstractHydroformylation is one of the most important homogeneously catalyzed reactions on an industrial scale. The manufacture of bulk chemicals clearly dominates. Large cobalt- and rhodium-based processes are mature technologies that have been developed over the past 80 years.
Baoxin Zhang +2 more
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Single-atom catalysts for hydroformylation of olefins
iScience, 2023 Summary: Hydroformylation is one of the most significant homogeneous reactions. Compared with homogeneous catalysts, heterogeneous catalysts are easy to be separated from the system. However, heterogeneous catalysis faces the problems of low activity and
Shu Tao +7 more
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Nature Communications, 2023 Hydroformylation is one of the largest industrially homogeneous processes that strongly relies on catalysts with phosphine ligands such as the Wilkinson’s catalyst (triphenylphosphine coordinated Rh).
Yifeng Liu +12 more
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