Results 11 to 20 of about 6,547 (205)
Asymmetric Olefines Hydroformylation
CHIMIA, 1972 Optically active bis-(N-α-methylbenzylsalicylaldiminato)cobalt(II) and octacarbonyldicobalt in the presence of optically active N-α-methylbenzylsalicylaldimine promote asymmetric hydroformylation of styrene and α-methylstyrene.
Carlo Botteghi +2 more
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Biobased Oligo- and Polyesters from Fatty Acids with Demonstrated Biodegradability or Recyclability for Industrial Applications in a Circular Economy. [PDF]
ChemSusChemThis “Perspectives”‐article describes and discusses two recent developments in the field of biobased as well as biodegradable or chemically recyclable oligomers/polymers for applications in the lubricant and plastics product segments, which are efficiently accessible and which are based on the utilization of unsaturated fatty acids as feedstocks. This “
Gröger H.
europepmc +2 more sources
Nature Communications, 2021 Single-atom Rh catalysts present superior activity in olefins hydroformylation, yet with limited success in regioselectivity control. Here the authors develop a Rh1 single-atom catalyst with nanodiamond as support, with which good to excellent ...
Peng Gao +6 more
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Catalysis Communications, 2023 This paper investigates the effect of coordination modes on the selectivity and activity of hydroformylation catalysts using Rhodium complexes. DFT calculations are performed on monophosphine (1P) and bisphosphine (2P) catalysts to study the impact of ...
Xiuqin Dong, Hongkun Mo, Yifei Chen
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上海师范大学学报. 自然科学版, 2022 A self-developed low normal/isomer ratio(N/I) hydroformylation catalyst (HY-IH) was used for 1-butene hydroformylation to low N/I ratio mixed valeraldehyde.
YANG Xushi, MA Liqun, LAI Chunbo
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Synthesis of chiral nitrogen heterocycles using hydroformylation – cyclisation reactions [PDF]
, 2023 This thesis concerns the investigation of hydroformylation-cyclisation reactions for the synthesis of chiral, saturated nitrogen heterocycles. The first chapter is a literature review that details the work that has previously been carried out in this ...
Jeffrey, Nina
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Hydroformylation in fluorous biphasic media [PDF]
, 2007 The hydroformylation of oct-1-ene is investigated under fluorous biphasic conditions, utilising the facile catalyst recovery that is provided by the temperature dependent miscibility of the perfluorinated solvent with normal organic solvents.
Mathison, Clare R.
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Reductive Hydroformylation of Isosorbide Diallyl Ether
Molecules, 2021 Isosorbide and its functionalized derivatives have numerous applications as bio-sourced building blocks. In this context, the synthesis of diols from isosorbide diallyl ether by hydrohydroxymethylation reaction is of extreme interest.
Jérémy Ternel +7 more
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Metal-organic frameworks as kinetic modulators for branched selectivity in hydroformylation
Nature Communications, 2020 The Co-catalysed hydroformylation of olefins produces selectively linear but not branched aldehydes. Here, the authors show that microporous MOFs increase the olefins density in the pores beyond neat conditions allowing high branched selectivity through ...
Gerald Bauer +8 more
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Kinetics of hydroformylation of 1-octene in ionic liquid-organic biphasic media using rhodium sulfoxantphos catalyst [PDF]
, 2011 Biphasic hydroformylation of 1-octene was performed using rhodium sulfoxantphos catalyst dissolved in [BuPy][BF4] ionic liquid. Preliminary experiments proved this system to retain the catalytic complex within the ionic liquid phase and to maintain a ...
Kelkar, Ashutosh A. +9 more
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