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Special Issue: “Advances in Homogeneous Catalysis” [PDF]

Molecules, 2020
The use of enzymes, organo-catalysts or transition metal catalysts, as opposed to the employment of stoichiometric quantities of other traditional promoters of different organic synthetic processes (like, inorganic/organic bases, Brønsted acids ...
Joaquín García-Álvarez
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Added Complexity!—Mechanistic Aspects of Heterobimetallic Complexes for Application in Homogeneous Catalysis [PDF]

Molecules, 2023
Inspired by multimetallic assemblies and their role in enzyme catalysis, chemists have developed a plethora of heterobimetallic complexes for application in homogeneous catalysis.
Zeno Fickenscher, Evamarie Hey-Hawkins
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An autonomous lab for data-driven homogeneous catalysis [PDF]

Nature Communications
The discovery and optimization of homogeneous catalysts remain bottlenecks in the development of efficient and selective chemical transformations. Here we report Flex-Cat, a closed-loop autonomous catalysis platform that couples parallel miniaturized ...
J. A. Bennett, N. Orouji, A. Velayati, Eamon F. Reynolds, Matthew E. Porowski, M. Saha, D. Billodeaux, Alexander J. M. Miller, M. Abolhasani   +8 more
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Homogeneous catalysis in continuous flow integrating photocatalysis, electrocatalysis, and automation technologies [PDF]

Communications Chemistry
In recent years, homogeneous catalysis in continuous flow has undergone remarkable advances, driving significant progress across a broad range of chemical transformations.
Laura F. Peña, Lucía G. Parte, Carlos Díez-Poza, Javier Guerra, Enol López   +4 more
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Synthesis of novel phthalimido oxime pseudoesters and evaluation of their cytotoxicity [PDF]

Journal of the Serbian Chemical Society, 2020
A series of novel optically pure oxime pseudoesters derivatives were synthesized by the reaction of substitute keto oximes with various N-substituted α-amino acids chlorides in the presence of triethylamine and dichloromethane at 0°C, and their ...
Mehrez Asma, Chakroun Ibtissem, Mtat Dalila, Ben Mansour Hédi, Touati Ridha   +4 more
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Cu-Catalyzed Arylation of Bromo-Difluoro-Acetamides by Aryl Boronic Acids, Aryl Trialkoxysilanes and Dimethyl-Aryl-Sulfonium Salts: New Entries to Aromatic Amides

Molecules, 2021
We describe a mechanism-guided discovery of a synthetic methodology that enables the preparation of aromatic amides from 2-bromo-2,2-difluoroacetamides utilizing a copper-catalyzed direct arylation.
Satenik Mkrtchyan, Michał Jakubczyk, Suneel Lanka, Michael Pittelkow, Viktor O. Iaroshenko   +4 more
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Arene-Osmium(II) Complexes in Homogeneous Catalysis

Inorganics, 2021
Although the application of arene-osmium(II) complexes in homogeneous catalysis has been much less studied than that of their ruthenium analogues, different works have shown that, in some instances, a comparable or even superior effectiveness can be ...
Pascale Crochet, Victorio Cadierno
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Monitoring New Long-Lasting Intravitreal Formulation for Glaucoma with Vitreous Images Using Optical Coherence Tomography

Pharmaceutics, 2021
Intravitreal injection is the gold standard therapeutic option for posterior segment pathologies, and long-lasting release is necessary to avoid reinjections.
Maria Jesus Rodrigo, Amaya Pérez del Palomar, Alberto Montolío, Silvia Mendez-Martinez, Manuel Subias, Maria Jose Cardiel, Teresa Martinez-Rincon, José Cegoñino, José Maria Fraile, Eugenio Vispe, José Antonio Mayoral, Vicente Polo, Elena Garcia-Martin   +12 more
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3-Methylindole-Based Tripodal Tetraphosphine Ruthenium Complexes in N2 Coordination and Reduction and Formic Acid Dehydrogenation

Inorganics, 2017
The ruthenium(II) complexes RuCl2L1H, RuCl2L1CF3, RuCl2L1OMe and RuCl2L2H were synthesized from [Ru(η6-benzene)Cl(μ-Cl)]2 and the corresponding tripodal tris-3-methylindolephosphine-based ligands L1H, L1CF3, L1OMe, and L2H.
Fenna F. van de Watering, Nicol Heijtbrink, Jarl Ivar van der Vlugt, Wojciech I. Dzik, Bas de Bruin, Joost N. H. Reek   +5 more
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ML meets MLn: Machine learning in ligand promoted homogeneous catalysis

Artificial Intelligence Chemistry, 2023
The benefits of using machine learning approaches in the design, optimisation and understanding of homogeneous catalytic processes are being increasingly realised.
Jonathan D. Hirst, Samuel Boobier, Jennifer Coughlan, Jessica Streets, Philippa L. Jacob, Oska Pugh, Ender Özcan, Simon Woodward   +7 more
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