Developments of time-resolved XAFS spectroscopy techniques - applications in homogeneous catalysis [PDF]
, 2004 Catalysis is one of the most important methods to obtain products in a selective and sustainable manner, i.e. in an environmental responsible manner.
Tromp, Moniek
core +4 more sources
Paramagnetic species in catalysis research: A unified approach towards (the role of EPR in) heterogeneous, homogeneous and enzyme catalysis [PDF]
, 2021 Paramagnetic (open-shell) systems, including transition metal ions, radical intermediates and defect centres, are often involved in catalytic transformations.
Thangavel, K. +10 more
core +1 more source
EPR spectroscopy as a tool in homogeneous catalysis research [PDF]
, 2015 In the context of homogeneous catalysis, open-shell systems are often quite challenging to characterize. Nuclear magnetic resonance (NMR) spectroscopy is the most frequently applied tool to characterize organometallic compounds, but NMR spectra are ...
Christophe Rebreyend +7 more
core +2 more sources
Computational Study of Homogeneous Multimetallic Cooperative Catalysis [PDF]
, 2021 Cooperative multimetallic catalysis is a fascinating field of research further expanding the role of homogeneous catalysis. The simultaneous activation of two substrates or functionalities by different catalytic entities and their subsequent coupling are
Maseras Cuní, Feliu +3 more
core +1 more source
Inorganics, 2019 The synthesis, reactivity, and potential of well-defined dinuclear gold complexes as precursors for dual-gold catalysis is explored. Using the preorganizing abilities of well-known wide bite angle diphosphine ligands, DBFPhos and DPEPhos, dinuclear Au(I)&
Marianne Lankelma +3 more
doaj +1 more source
Porphyrin Co(III)-Nitrene Radical Mediated Pathway for Synthesis of o-Aminoazobenzenes
Molecules, 2018 Azobenzenes are versatile compounds with a range of applications, including dyes and pigments, food additives, indicators, radical reaction initiators, molecular switches, etc.
Monalisa Goswami, Bas de Bruin
doaj +1 more source
Synthesis of 2-Substitued Indoles via Pd-Catalysed Cyclization in an Aqueous Micellar Medium
Molecules, 2021 The synthesis of 2-substituted indoles starting from the corresponding unprotected 2-alkynylanilines was made possible in 3% TPGS-750-M water using Pd(OAc)2 alone as the catalyst.
Sofia Siciliano +3 more
doaj +1 more source
SYNERGISMS BETWEEN METAL AND PHOTOREDOX CATALYSIS: DECONVOLUTING COMPLEX SYSTEMS [PDF]
Química Nova, 2020 This review briefly describes the evolution of organometallic chemistry and photoredox catalysis as independent fields; followed by a more in-depth presentation and discussion of representative examples derived from their synergistic combination, which ...
Alessandra A. G. Fernandes +1 more
doaj +2 more sources
Silylation of Dinitrogen Catalyzed by Hydridodinitrogentris(Triphenylphosphine)Cobalt(I)
Inorganics, 2016 Recently, homogeneous cobalt systems were reported to catalyze the reductive silylation of dinitrogen. In this study the investigations on the silylation of dinitrogen catalyzed by CoH(PPh3)3N2 are presented.
Wojciech I. Dzik
doaj +1 more source
Frustrated Lewis Pairs in Heterogeneous Catalysis: Theoretical Insights
Molecules, 2022 Frustrated Lewis pair (FLP) catalysts have attracted much recent interest because of their exceptional ability to activate small molecules in homogeneous catalysis.
Qiang Wan, Sen Lin, Hua Guo
doaj +1 more source