From Mechanisms in Homogeneous Metal Catalysis to Applications in Chemical Synthesis [PDF]
Inorganics, 2018 Man-made homogeneous catalysis with the aid of transition metal compounds looks back on a long history of almost one hundred years. Still, more detailed insight into the underlying mechanisms is warranted.
Axel Klein +2 more
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Developments of time-resolved XAFS spectroscopy techniques – applications in homogeneous catalysis [PDF]
, 2004 Catalysis is one of the most important methods to obtain products in a selective and sustainable manner, i.e. in an environmental responsible manner.
Tromp, Moniek, Tromp. Moniek
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Inorganics, 2019 The synthesis, reactivity, and potential of well-defined dinuclear gold complexes as precursors for dual-gold catalysis is explored. Using the preorganizing abilities of well-known wide bite angle diphosphine ligands, DBFPhos and DPEPhos, dinuclear Au(I)&
Marianne Lankelma +3 more
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Homogeneous Catalysts Based on First‐Row Transition‐Metals for Electrochemical Water Oxidation [PDF]
, 2021 Strategies that enable the renewable production of storable fuels (i. e. hydrogen or hydrocarbons) through electrocatalysis continue to generate interest in the scientific community.
Fengshou Yu +9 more
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Porphyrin Co(III)-Nitrene Radical Mediated Pathway for Synthesis of o-Aminoazobenzenes
Molecules, 2018 Azobenzenes are versatile compounds with a range of applications, including dyes and pigments, food additives, indicators, radical reaction initiators, molecular switches, etc.
Monalisa Goswami, Bas de Bruin
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Synthesis of 2-Substitued Indoles via Pd-Catalysed Cyclization in an Aqueous Micellar Medium
Molecules, 2021 The synthesis of 2-substituted indoles starting from the corresponding unprotected 2-alkynylanilines was made possible in 3% TPGS-750-M water using Pd(OAc)2 alone as the catalyst.
Sofia Siciliano +3 more
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SYNERGISMS BETWEEN METAL AND PHOTOREDOX CATALYSIS: DECONVOLUTING COMPLEX SYSTEMS [PDF]
Química Nova, 2020 This review briefly describes the evolution of organometallic chemistry and photoredox catalysis as independent fields; followed by a more in-depth presentation and discussion of representative examples derived from their synergistic combination, which ...
Alessandra A. G. Fernandes +1 more
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EPR spectroscopy as a tool in homogeneous catalysis research [PDF]
, 2015 In the context of homogeneous catalysis, open-shell systems are often quite challenging to characterize. Nuclear magnetic resonance (NMR) spectroscopy is the most frequently applied tool to characterize organometallic compounds, but NMR spectra are ...
Christophe Rebreyend +7 more
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Silylation of Dinitrogen Catalyzed by Hydridodinitrogentris(Triphenylphosphine)Cobalt(I)
Inorganics, 2016 Recently, homogeneous cobalt systems were reported to catalyze the reductive silylation of dinitrogen. In this study the investigations on the silylation of dinitrogen catalyzed by CoH(PPh3)3N2 are presented.
Wojciech I. Dzik
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Frustrated Lewis Pairs in Heterogeneous Catalysis: Theoretical Insights
Molecules, 2022 Frustrated Lewis pair (FLP) catalysts have attracted much recent interest because of their exceptional ability to activate small molecules in homogeneous catalysis.
Qiang Wan, Sen Lin, Hua Guo
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