Results 11 to 20 of about 53,119 (305)

Rhodium-Catalyzed Sulfimidation Reactions: A Computational Study

open access: yes, 2021
The rhodium-catalyzed sulfimidation of thioethers using N-mesyloxycarbamates is a powerful tool to access chiral sulfilimines. 4-Dimethylaminopyridine (DMAP) and bis-(DMAP)­CH2Cl2 additives were found to be crucial to achieving high yields and ...
Emna Azek   +7 more
core   +2 more sources

Kinetics of hydroformylation of 1-octene in ionic liquid-organic biphasic media using rhodium sulfoxantphos catalyst [PDF]

open access: yes, 2011
Biphasic hydroformylation of 1-octene was performed using rhodium sulfoxantphos catalyst dissolved in [BuPy][BF4] ionic liquid. Preliminary experiments proved this system to retain the catalytic complex within the ionic liquid phase and to maintain a ...
Kelkar, Ashutosh A.   +9 more
core   +1 more source

Global Downscaled Projections for Climate Impacts Research (GDPCIR): preserving quantile trends for modeling future climate impacts [PDF]

open access: yesGeoscientific Model Development
Global climate models (GCMs) are important tools for understanding the climate system and how it is projected to evolve under scenario-driven emissions pathways.
D. R. Gergel   +12 more
doaj   +1 more source

Data of the rhodium(triphenylphosphine)carbonyl-2,4-dioxo-3-pentyl-4-hydroxybenzoate plus iodomethane oxidative addition and follow-up reactions

open access: yesData in Brief, 2020
Density functional theory (DFT) free energy data and the reaction mechanism of the rhodium(triphenylphosphine)carbonyl-2,4-dioxo-3-pentyl-4-hydroxybenzoate plus iodomethane reaction are presented.
Marrigje M Conradie
doaj   +1 more source

NastaranT/rhodium-swmm: Rhodium-SWMM version 1.0 Initial Release

open access: yes, 2022
This is the initial public release of Rhodium-SWMM version 1 ...
Nastaran Tebyanian
core   +1 more source

Multiferroic Rhodium Clusters

open access: yesPhysical Review Letters, 2014
Simultaneous magnetic and electric deflection measurements of rhodium clusters (Rh(N), 6 ≤ N ≤ 40) reveal ferromagnetism and ferroelectricity at low temperatures, while neither property exists in the bulk metal. Temperature-independent magnetic moments (up to 1 μ(B) per atom) are observed, and superparamagnetic blocking temperatures up to 20 K ...
Ma, L.   +4 more
openaire   +3 more sources

Extraction spectrophotometric determination of rhodium(III) with o-methylphenyl thiourea

open access: yesJournal of Saudi Chemical Society, 2015
Trivalent rhodium was determined spectrophotometrically as its 1:2 rhodium o-methylphenyl thiourea (OMPT) complex, extracted into chloroform from aqueous acetate buffer media at pH 5.4.
Y.S. Shelar, S.R. Kuchekar, S.H. Han
doaj   +1 more source

Coupling of nanocrystal hexagonal array and two-dimensional metastable substrate boosts H2-production

open access: yesNature Communications, 2022
The construction of well-ordered nanoarrays, particularly invoking metastable material phases, remains a challenge. Here, authors prepared a well-ordered, rhodium nanoarray on two-dimensional, metastable rhodium oxide to enhance hydrogen evolution ...
Zhenglong Fan   +15 more
doaj   +1 more source

Kinetic analysis of homogeneous catalytic reactions [PDF]

open access: yes, 2012
Reaction progress kinetic analysis (RPKA) is a powerful tool for determining kinetic parameters of catalytic reactions. Many of the published articles that have used RPKA have employed reaction calorimetry for obtaining sufficient data to be reliable ...
Robb, Lynzi M.
core   +2 more sources

Oxidation Behavior of Non-Modified and Rhodium- or Palladium-Modified Aluminide Coatings Deposited on CMSX-4 Superalloy

open access: yesMetals, 2018
Rhodium-modified as well as palladium-modified and non-modified aluminide coatings on CMSX-4 Ni-based superalloy were oxidized in air atmosphere at 1100 °C. Uncoated substrate of CMSX-4 superalloy was also oxidized.
Maryana Zagula-Yavorska
doaj   +1 more source

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