The construction of well-ordered nanoarrays, particularly invoking metastable material phases, remains a challenge. Here, authors prepared a well-ordered, rhodium nanoarray on two-dimensional, metastable rhodium oxide to enhance hydrogen evolution ...
Zhenglong Fan +15 more
doaj +1 more source
Dry impregnation in fluidized bed: Drying and calcination effect on nanoparticles dispersion and location in a porous support [PDF]
The synthesis of metal nanoparticles dispersed inside the grains of a porous inorganic support was carried out by ‘‘dry impregnation’’ in a fluidized bed.
B. Chaudret +8 more
core +3 more sources
Synthesis of Solution-Phase Phosphoramidite and Phosphite Ligand Libraries and Their In Situ Screening in the Rhodium-Catalyzed Asymmetric Addition of Arylboronic Acids [PDF]
Herein, we report the automated parallel synthesis of solution-phase libraries of phosphoramidite ligands for the development of enantioselective catalysts.
Feringa, Ben L., +5 more
core +1 more source
Rhodium-modified as well as palladium-modified and non-modified aluminide coatings on CMSX-4 Ni-based superalloy were oxidized in air atmosphere at 1100 °C. Uncoated substrate of CMSX-4 superalloy was also oxidized.
Maryana Zagula-Yavorska
doaj +1 more source
Catalytic coatings on steel for low-temperature propane prereforming to solid oxide fuel cell (SOFC) application [PDF]
Catalyst layers (4–20 lm) of rhodium (1 wt%) supported on alumina, titania, and ceria–zirconia (Ce0.5Zr0.5O2) were coated on stainless-steel corrugated sheets by dip-coating in very stable colloidal dispersions of nanoparticles in water.
Alphonse, Pierre, Ansart, Florence
core +2 more sources
Metallo-intercalators and metallo-insertors [PDF]
Since the elucidation of the structure of double helical DNA, the construction of small molecules that recognize and react at specific DNA sites has been an area of considerable interest.
Barton, Jacqueline K. +2 more
core +1 more source
For the combustion of methane, a partial replacement of platinum by rhodium leads to a significantly improved light-off behavior of the corresponding mixed Pt-Rh/γ-Al2O3 catalysts compared to a catalyst containing only Pt supported on γ-Al2O3. For all Pt-
Stefan Neuberg +4 more
doaj +1 more source
Rhodium and copper 6-methylpicolinate complexes. Structural diversity and supramolecular interaction study [PDF]
Seven new coordination compounds with 6-methylpicolinic acid (6-HMepic) and rhodium(III) or copper(II) of formula [Rh(6-Mepic)3] (1), [Rh(6-Mepic)2(H2O)Cl] (2), [Rh(6-HMepic)(6-Mepic)Cl2]·3.5(H2O) (3), [Cu(6-Mepic)2(H2O)]·H2O (4), [Cu(6-Mepic)2]n, (5 ...
Amo-Ochoa, P. +3 more
core +2 more sources
Asymmetric Hydrogenation in Water by a Rhodium Complex of Sulfonated 2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl (binap) [PDF]
The synthesis of sulfonated 2,2′-bis(diphenylphosphino)-1,1′-binaphthyl (binap) is reported; a rhodium complex of this ligand is the first to perform asymmetric hydrogenation in neat water with optical yields as high as those obtained in nonaqueous ...
Davis, Mark E., Wan, Kam-to
core +1 more source
The reconstruction of Ni and Rh (001) surfaces upon Carbon, Nitrogen, or Oxygen adsorption
Nickel and Rhodium (001) surfaces display a similar - as from STM images - clock reconstruction when half a monolayer of C/Ni, N/Ni or O/Rh is adsorbed; no reconstruction is observed instead for O/Ni.
Alfè +33 more
core +1 more source

