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Rhodium-Catalyzed Allylation Reactions

Synthesis, 2019
Rhodium-catalyzed allylation reactions are well known for their unique selectivity and reactivity due to the high memory effect of Rh as compared to other metals.
M. B. Thoke, Q. Kang
semanticscholar   +1 more source

Formation of supported rhodium clusters from mononuclear rhodium complexes controlled by the support and ligands on rhodium

Phys. Chem. Chem. Phys., 2014
Extremely small supported rhodium clusters were prepared from rhodium complexes on the surfaces of solids with contrasting electron-donor properties. The samples were characterized by infrared and extended X-ray absorption fine structure spectroscopies to determine the changes occurring in the rhodium species resulting from treatments in hydrogen ...
Joseph D. Kistler   +4 more
openaire   +3 more sources

Rhodium(I)-Catalyzed C8-Alkylation of 1-Naphthylamide Derivatives with Alkenes through a Bidentate Picolinamide Chelation System

ACS Catalysis, 2018
The rhodium(I)-catalyzed C–H alkylation of 1-naphthylamide derivatives with alkenes at the C8-position using a picolinamide directing group is reported.
Supriya Rej, N. Chatani
semanticscholar   +1 more source

Rhodium Catalyzed Synthesis of Benzopyrans via Transannulation of N-Sulfonyl-1,2,3-triazoles with 2-Hydroxybenzyl Alcohols.

Organic Letters, 2018
An efficient and novel rhodium-catalyzed transannulation of N-sulfonyl-1,2,3-triazoles with in situ generated o-quinone methides ( o-QMs) from 2-hydroxybenzyl alcohols has been achieved for the synthesis of substituted benzopyrans in good yields.
Dongari Yadagiri   +3 more
semanticscholar   +1 more source

NO dissociation on rhodium

Catalysis Letters, 1995
The desorption and dissociation of nitric oxide on a polycrystalline Rh foil were studied by means of combined temperature-programmed desorption (TPD) and static secondary ion mass spectrometry (SSIMS). The latter method was employed either under isothermal conditions or in a temperature-programmed mode (TPSSIMS).
Sellmer, C.   +2 more
openaire   +2 more sources

Thionitrosyl Complexes of Rhodium

Zeitschrift für anorganische und allgemeine Chemie, 1980
Abstract(NSCl)3 reacts with Rhodium(I) complexes and with RhCl3 · 3H2O in the presence of triphenylphosphine and triphenylarsine to give thionitrosyl and carbonyl thionitrosyl complexes which are characterised by elemental analyses, magnetic measurements are i.r. spectra.
Krishna K. Pandey   +2 more
openaire   +3 more sources

Rhodium on Alumina

2001
[7440-16-6] Rh (MW 102.91) InChI = 1S/Rh InChIKey = MHOVAHRLVXNVSD-UHFFFAOYSA-N (active catalyst under mild conditions for hydrogenation of unsaturated compounds including aldehydes, ketones,1h,7 and aromatic carbocyclic1 and heterocyclic structures;1a,g,k high stereospecificity and low hydrogenolytic activity) Form ...
openaire   +2 more sources

Rhodium-96 and Rhodium-95

Physica, 1967
A.H.W. Aten Junior, Johanna C. Kapteyn
openaire   +2 more sources

Mild oxidation of methane to methanol or acetic acid on supported isolated rhodium catalysts

Nature, 2017
Junjun Shan   +4 more
semanticscholar   +1 more source

Rhodium and iridium

1997
Rhodium and iridium were discovered independently in the same year and also share many resemblances in their chemistry [1–10]. They form a wide range of conventional complexes as well as those of π-bonding ligands. Both metals exhibit an extensive chemistry, principally in the +3 oxidation state, with +1 also being important, and a significant ...
openaire   +2 more sources

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