Results 41 to 50 of about 9,893 (141)
Acta Crystallographica Section E: Crystallographic Communications, 2015 The crystal structures of two solvates of fac-trichloridotris(trimethylphosphane-κP)rhodium(III) are reported, i.e. one with water in the crystal lattice, fac-[RhCl3(Me3P)3]·H2O, and one with methanol in the crystal lattice, fac-[RhCl3(Me3P)3]·0.5CH3OH ...
Joseph S. Merola, Marion A. Franks
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Experimental time-resolved photoemission and ab initio study of lifetimes of excited electrons in Mo and Rh [PDF]
Phys. Rev. B 74, 035102 (2006), 2006 We have studied the relaxation dynamics of optically excited electrons in molybdenum and rhodium by means of time resolved two-photon photoemission spectroscopy (TR-2PPE) and ab initio electron self-energy calculations performed within the GW and GW+T approximations. Both theoretical approaches reproduce qualitatively the experimentally observed trends
arxiv +1 more source
The MWCNTs-Rh Nanocomposite Obtained By The New High-Temperature Method
Archives of Metallurgy and Materials, 2015 A nanocomposite was fabricated during the research undertaken, consisting of multiwalled carbon nanotubes coated with rhodium nanoparticles by the new high-temperature method being the subject of the patent claim.
Dobrzańska-Danikiewicz A.D. +2 more
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Data in Brief, 2020 Density functional theory (DFT) free energy data and the reaction mechanism of the rhodium(triphenylphosphine)carbonyl-2,4-dioxo-3-pentyl-4-hydroxybenzoate plus iodomethane reaction are presented.
Marrigje M Conradie
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Química Nova, 2011 A simple ion pair-dispersive liquid-liquid microextraction method was proposed for preconcentration trace amounts of rhodium. An ion association complex of RhCl4- and tetradecyldimetylbenzylamonium was extracted into cholorobenzene.
Daryoush Afzali +2 more
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IUCrData, 2023 The crystal-structure determination of the title compound, [RhH(C46H44O8P2)2(CO)]·2.25C7D8, is reported. The bisphosphite ligand, C46H44O8P2, is well known as Biphephos.
Benedict N. Leidecker +4 more
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Pressure-induced formation of rhodium zigzag chains in the honeycomb rhodate Li$_2$RhO$_3$ [PDF]
Phys. Rev. B 100, 064105 (2019), 2019 We use powder x-ray diffraction to study the effect of pressure on the crystal structure of the honeycomb rhodate Li$_2$RhO$_3$. We observe low-pressure ($P$$<$$P_{c1}$ = 6.5 GPa) and high-pressure ($P$$>$$P_{c2}$ = 14 GPa) regions corresponding to the monoclinic $C2/m$ symmetry, while a phase mixture is observed at intermediate pressures. At $P$$>$$P_{
arxiv +1 more source
Molecules, 2000 The rhodium(II)-catalyzed reaction of α-diazo ketones bearing tethered alkyne units represents a new and useful method for the construction of a variety of substituted cyclopentenones.
Albert Padwa
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Hidroformilação do oleato de metila catalisada por complexos de ródio
Química Nova, 2012 In this work, we describe the hydroformylation of methyl oleate catalyzed by several rhodium complexes. Parameters including total pressure, phosphorous/rhodium and CO/H2 ratio, temperature and phosphorous ligands were scanned.
Ana Nery Furlan Mendes +2 more
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Preparation of Mixed Bis-N-Heterocyclic Carbene Rhodium(I) Complexes
Molecules, 2022 A series of mixed bis-NHC rhodium(I) complexes of type RhCl(η2-olefin)(NHC)(NHC’) have been synthesized by a stepwise reaction of [Rh(μ-Cl)(η2-olefin)2]2 with two different NHCs (NHC = N-heterocyclic carbene), in which the steric hindrance of both NHC ...
Ramón Azpíroz +5 more
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