Results 71 to 80 of about 53,119 (305)

Rhodium-Catalyzed Enantioselective N‑Allylation of Sulfoximines

open access: yes, 2023
The N-functionalization of free sulfoximines is an important approach to modifying their chemical and biological properties for downstream applications.
Bing Gao (487338)   +3 more
core   +1 more source

A Novel Modified Petroresin Particle (MPRP) With Enhanced Oil–Water Selectivity for Cold Production in Heavy Oil Reservoirs

open access: yesAdvanced Functional Materials, EarlyView.
A novel oil–water selective conformance control agent, MPRP, is prepared via hydrophilic grafting and mechanical granulation. MPRP uniformly disperses in water, cohesively expands upon aging, and readily dissolves in the oil phase. During conformance control, it selectively aggregates in water channeling pathways to form effective plugs without ...
Guang Zhao   +6 more
wiley   +1 more source

Rhodium-Catalyzed Asymmetric Alcoholysis and Aminolysis of Oxabenzonorbornadiene:  A New Enantioselective Carbon−Heteroatom Bond Forming Process

open access: yes, 2016
Rhodium-Catalyzed Asymmetric Alcoholysis and Aminolysis of Oxabenzonorbornadiene:  A New Enantioselective Carbon−Heteroatom Bond Forming ...
Mark Lautens (1391935)   +2 more
core   +2 more sources

Hidroformilação do oleato de metila catalisada por complexos de ródio

open access: yesQuímica Nova, 2012
In this work, we describe the hydroformylation of methyl oleate catalyzed by several rhodium complexes. Parameters including total pressure, phosphorous/rhodium and CO/H2 ratio, temperature and phosphorous ligands were scanned.
Ana Nery Furlan Mendes   +2 more
doaj   +1 more source

Rhodium-Catalyzed Expeditious Synthesis of Indenes from Propargyl Alcohols and Organoboronic Acids by Selective 1,4-Rhodium Migration over β‑Oxygen Elimination

open access: yes, 2019
An expeditious synthetic route to 1,1-disubstituted indenes from propargyl alcohols and organoboronic acids was developed under rhodium catalysis, and selective 1,4-rhodium migration over β-oxygen elimination was involved as the key step.
Xiaowei Dou   +11 more
core   +1 more source

Balancing Hydrophobicity and Hydrophilicity: Dual Filler‐Engineered Proton Exchange Membranes for Durable, High‐Power Fuel Cells

open access: yesAdvanced Functional Materials, EarlyView.
Polarity‐matched Zr–MOFs program Nafion's nanoscale morphology during solution casting. Hydrophilic UiO‐66 preserves hydrated pathways, while hydrophobic UiO‐67 increases the proton hopping sites by densifying ionic clusters. Combining both fillers yields a membrane that delivers 176 mS cm−1 conductivity, reaches 1.46 W cm−2 under 200 kPa, and triples ...
Yonghwi Cho   +13 more
wiley   +1 more source

Roll‐to‐Roll Processable EC/TC Hybrid Smart Windows Driven by a Bidirectional Dual‐Chromic Polymer Electrolyte

open access: yesAdvanced Functional Materials, EarlyView.
We present a scalable EC/TC hybrid smart window using a DCPE that enables tunable solar modulation (ΔTsol:15–43%), fast electrochromic switching (<90 s), and strong thermal blocking (10–14°C reduction). HPMC improves thermal stability, while an optimized ISL enhances EC performance.
Soyeon Kim   +4 more
wiley   +1 more source

A Thorough Understanding of Methylrhodium(III)–Porphyrin Photophysics: A DFT/TDDFT Study

open access: yesMolecules
Rhodium–porphyrin complexes are characterised by their ability to activate C-H and C-C bonds and, therefore, find applications in synthesis and catalysis. Axial rhodoporphyrin ligands are susceptible to photodissociation under the influence of light. DFT
Piotr Lodowski, Maria Jaworska
doaj   +1 more source

Bacterial Cellulose‐Based Bilayer Passive Cooler for High‐Performance Radiative/Evaporative Cooling

open access: yesAdvanced Functional Materials, EarlyView.
A sustainable bilayer passive cooler based on bacterial cellulose integrates radiative and evaporative cooling for efficient zero‐energy temperature reduction. The scalable, low‐carbon material shows strong potential for food preservation, low‐temperature storage, and cold‐chain logistics.
Yibing Zhang   +6 more
wiley   +1 more source

Sky‐Directional Radiative Cooling Meta‐Films for Daylighting Windows

open access: yesAdvanced Functional Materials, EarlyView.
A geometry‐mediated microprism meta‐film enables transparent, sky‐directional radiative cooling for daylighting windows. By decoupling control of visible transmittance from mid‐infrared emissivity, ground‐emitted heat absorption is suppressed while skyward heat dissipation is enhanced.
Seung‐Ah Yu   +7 more
wiley   +1 more source

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