Results 61 to 70 of about 74,434 (294)

Synthesis of Block Copolymers of Varying Architecture Through Suppression of Transesterification during Coordinated Anionic Ring Opening Polymerization

International Journal of Biomaterials, 2012
Well-defined di- and triblock copolymers consisting of ε-caprolactone (CL), L-lactide (LA), and trimethylene carbonate (TMC) were synthesized via “PLA first route” in coordinated anionic ring opening polymerization/copolymerization (CAROP) with tin (II ...
Vitali T. Lipik, Marc J. M. Abadie
doaj   +1 more source

Toward industrial use of anionically activated lactam polymers: Past, present and future

Advanced Industrial and Engineering Polymer Research, 2018
This paper gives an overview of lactam-based polymers and related composites produced via anionic ring opening polymerization (AROP). Recent and past achievements, grouped into academic and industrial research works, and covering also the chemistry ...
Ilya Sibikin, József Karger-Kocsis
doaj   +1 more source

Novel "green" catalysts for controlled ring-opening polymerization of lactide [PDF]

, 2010
Syntéza polylaktidu (PLA) polymerací za otevření kruhu cyklického monomeru (ROP) může být uskutečněna různými způsoby. Literatura uvádí více než 100 katalytických systémů, jejichž pomocí lze polylaktid a jiné biodegradabilní alifatické polyestery získat.
Surman, František
core  

Zinc calixarene complexes for the ring opening polymerization of cyclic esters [PDF]

, 2014
Reaction of Zn(C₆F₅)₂·toluene (two equivalents) with 1,3-dipropoxy-p-tert-butyl-calix[4]arene (L¹H₂) led to the isolation of the complex [{Zn(C₆F₅)}₂L¹] (1), whilst similar use of Zn(Me)₂ resulted in the known complex [{Zn(Me)}₂L¹] (2). Treatment of L¹H₂
Elsegood, Mark R. J., Lancaster, Simon J., Redshaw, Carl, Walton, Mark J., Wright, Joseph A.   +4 more
core   +2 more sources

COMP–PMEPA1 axis promotes epithelial‐to‐mesenchymal transition in breast cancer cells

Molecular Oncology, EarlyView.
This study reveals that cartilage oligomeric matrix protein (COMP) promotes epithelial‐to‐mesenchymal transition (EMT) in breast cancer. We identify PMEPA1 (protein TMEPAI) as a novel COMP‐binding partner that mediates EMT via binding to the TSP domains of COMP, establishing the COMP–PMEPA1 axis as a key EMT driver in breast cancer.
Konstantinos S. Papadakos, Gilar Gorji‐bahri, Lejla Gradjan, Julia Zajac, Kacper Gil, Yvonne Thokozile Nduku, Anna M. Blom   +6 more
wiley   +1 more source

Melt block copolymerization of ε-caprolactone and L-lactide [PDF]

, 1997
AB block copolymers of ε-caprolactone and (L)-lactide could be prepared by ring-opening polymerization in the melt at 110°C using stannous octoate as a catalyst and ethanol as an initiator provided ε-caprolactone was polymerized first.
Dijkstra, Pieter J., Feijen, Jan, Hamhuis, Jennie, Veld, Peter J.A. in 't, Velner, Esther M., Witte, P. van de   +5 more
core   +1 more source

Anilido-aldimine aluminum complexes: Synthesis, characterization and lactide polymerization [PDF]

, 2012
The synthesis of six bimetallic dimethyl aluminum anilido-aldimine complexes, active for the ring opening polymerization of rac-lactide, is reported.
Allan, Laura E. N., Belanger, Justin A., Callaghan, Laura M., Cameron, Donald J. A., Decken, Andreas, Shaver, Michael P.   +5 more
core   +1 more source

Interrogating the immune landscape of microsatellite stable RAS‐mutated colon cancer

Molecular Oncology, EarlyView.
COLOSSUS project RAS‐mutated MSS colon cancer study explored transcriptomics and immune cell density by immunohistochemistry (IHC), Immunoscore (IS), ISIC/TuLIS scores, mutation counts, and detected different prevalences but similar microenvironment composition across immune markers with clinical relevance for future immunotherapy combination ...
Rodrigo Dienstmann, Eduardo García‐Galea, Alice O'Farrell, Zak Kinsella, Maxime Meylan, Florent Petitprez, Ingrid Arijs, Tom Venken, Hari Ps, Adrian Lärkeryd, Ian Miller, Janick Selves, Nadja Meindl‐Beinker, Fiorella Ruiz‐Pace, Elena Élez, Raquel Comas‐Navarro, Frank Lincoln, Dirk Fey, Gift Nyamundanda, Aoife Nolan, Joern Lewin, Raquel Perez‐Lopez, Jonathan Briody, Kathleen Bennett, Walter Kolch, David Matallanas, Alexander Kel, Enrique Arenas, Joaquín Arribas, Bart Ghesquière, Josep Tabernero, Julie Meilleroux, Deborah McNamara, Ray McDermott, Marvin Lim, Mary O'Reilly, Brian Bird, Lisa Stack, Lucia Moloney, Patrick Morris, Keith Egan, Maciej Milewski, Lars Scheuer, Joachim Behringer, Georg Bolz, Ramon Salazar, Cristina Santos, Andrea Ruiz, Orla Casey, Verena Murphy, Matthias Ebert, Livio Trusolino, Diether Lambrechts, Anguraj Sadanandam, Catherine Sautès‐Fridman, Jochen Prehn, Paolo Nuciforo, Jacques Fieschi, Florence Monville, Darran O'Connor, Wolf Fridman, Annette Byrne   +61 more
wiley   +1 more source

Free radical ring-opening polymerization [PDF]

Die Makromolekulare Chemie, 1985
Although unstrained five- or six-membered carbocyclic systems undergo free radical ring-closing polymerization, the introduction of an oxygen into the ring will promote free radical ring-opening polymerization, since the resulting carbon–oxygen double bond is approximately 50 kcal more stable than a carbon-carbon double bond.
openaire   +1 more source

Organoaluminium complexes derived from Anilines or Schiff bases for ring opening polymerization of epsilon-caprolactone, delta-valerolactone and rac-lactide [PDF]

, 2017
Reaction of R¹R²CHN=CH(3,5-tBu₂C₆H₂-OH-2) (R¹ = R² = Me L¹H; R¹ = Me, R² = Ph L²H; R¹ = R2 = Ph L³H) with one equivalent of R³3Al (R³ = Me, Et) afforded [(L¹-³)AlR³₂] (L¹, R³ = Me 1, R³ = Et 2; L², R³ = Me 3, R³ = Et 4; L³ R³ = Me 5, R³ = Et 6); complex ...
Al-Khafaj, Yahya, Al-Khafaji, Yahya, Elsegood, Mark, Elsegood, Mark R. J., Elsegood, Mark R.J., Mo, Shangyan, Mo, Shanyan, Prior, Timothy, Prior, Timothy J., Redshaw, Carl, Wang, X., Wang, Xue, Zhao, K.-Q., Zhao, Ke-Qing   +13 more
core   +3 more sources