Results 201 to 210 of about 87,486 (287)

Design of experiments‐driven optimization of Porphyridium marinum cultivation: impact of operational variables on phycoerythrin and exopolysaccharide production

Biofuels, Bioproducts and Biorefining, EarlyView.
Abstract Among the Porphyridium genus, Porphyridium marinum exhibits the highest phycoerythrin (PE) content. In this study, the metabolic trade‐off between biomass, PE, and sulfated exopolysaccharide (EPS) production was assessed under varying nitrogen and sulfur availability, light intensity, residence time, and cultivation mode.
Rosaria Tizzani, Agnese Torrisi, Fabrizio Bezzo, Eleonora Sforza   +3 more
wiley   +1 more source

Disordered light-harvesting aggregates can host functional vibronic couplings at room temperature. [PDF]

Nat Commun
Thomas AS, Roy C, Roy I, Bhat VN, Ghosh S, Tiwari V.   +5 more
europepmc   +1 more source

Ultra‐High‐Efficiency On‐Chip CO2 Conversion by Nanosecond Self‐Pulsing Micro‐Plasma Devices

Carbon Energy, EarlyView.
A micro‐plasma chip with sub‐10‐μm electrode gaps is introduced for efficient CO2‐to‐CO conversion. The device self‐converts a DC power supply into nanosecond pulses, producing field‐emission electrons that vibrationally excite CO2, driving dissociation via the ladder‐climbing mechanism. A scaled‐up chip array achieves 30% single‐pass conversion and 50%
Guangyu Sun, Bartu Karakurt, Hongkeng Zhu, Onder Soydal, Jeremy S. Luterbacher, Elison Matioli   +5 more
wiley   +1 more source

Shedding Light on Synthetic Autocatalysis: From Conventional Closed‐Shell Chemistries to Overlooked Open‐Shell Occurrences

Chemistry – A European Journal, EarlyView.
Why add another catalyst when the product itself holds the power to catalyze its own formation? Autocatalysis in synthetic chemistry enhances reaction efficiency and uncovers novel catalytic behavior across both closed‐shell and open‐shell systems, expanding reactivity and enabling innovative design strategies.
Jaspreet Kaur, Joshua P. Barham
wiley   +1 more source

Theoretical Insight on the Tautomerism and ESIPT Process in Some Hydroxyaryl(hetaryl)idene Azomethine Imines. [PDF]

Molecules
Kircheva N, Angelova S, Dobrev S, Antonov L.   +3 more
europepmc   +1 more source

Photochemistry of Aromatic N‐Oxides in Water Probed by Time‐Resolved X‐ray Absorption Spectroscopy

Chemistry – A European Journal, EarlyView.
Time‐resolved XAS at the nitrogen and oxygen K‐edges is applied to the photorearrangement of two N‐oxides in water. Pyridine N‐oxide rapidly forms the oxaziridine isomer. Pyridazine N‐oxide undergoes ring opening to the diazo compound, without any evidence of intermediates.
Maximilian Paradiz Domínguez, Robby Büchner, Mattis Fondell, Albert M. Brouwer   +3 more
wiley   +1 more source

Optimizing photon conversion routes in cinnamate derivatives. [PDF]

Commun Chem
Hymas M, Dalton J, Romanov I, Sanders H, Barbatti M, Toldo JM, Buma WJ, Stavros VG.   +7 more
europepmc   +1 more source

Design Principles for Next Generation of Small Organic Molecules for Photodynamics Therapy Revealed by Nonadiabatic Molecular Dynamics

Chemistry – A European Journal, EarlyView.
Molecular design reshapes the landscape of excited‐state relaxation. Nonadiabatic dynamics reveal how electronic structure guides population flow between competing pathways beyond static energetic arguments. ABSTRACT Nitrobenzochalcogenadiazole derivatives are emerging candidates for photodynamic therapy (PDT), yet the precise mechanisms governing ...
Vinícius N. da Rocha, Davide Avagliano, Paulo C. Piquini   +2 more
wiley   +1 more source

Tuning the Excited State Character of Amine/Carbonyl Thermally Activated Delayed Fluorescence Emitters with Ring Fusion. [PDF]

Chemistry
Kalab T, Gogoulis AT, Patrick BO, Hudson ZM.   +3 more
europepmc   +1 more source

Three‐Step Synthesis Toward Fluorene‐Based Non‐Fused‐Ring Acceptors for Organic Solar Cells

Chemistry – A European Journal, EarlyView.
Applying a simple three step synthesis strategy leads to two fluorene‐based non‐fused‐ring electron acceptors, FHM‐Cl and FHM‐F for organic solar cells. The chlorinated variant delivers markedly higher efficiency due to broader light harvesting and favorable molecular packing, resulting in improved charge transport and reduced recombination losses ...
Virginia Lafranconi, Suman Mallick, Lisa Nauta, Lisa Inzko, Julia Hönigsberger, Danijel Babic, Bettina Schlemmer, Daniele Padula, Heinz Amenitsch, Thomas Rath, Gregor Trimmel   +10 more
wiley   +1 more source