Results 221 to 230 of about 35,109,077 (302)

Evidence for a Cu(II)‐Catalysed CuAAC Reaction: A Combined Experimental and Computational Study

open access: yesAngewandte Chemie, EarlyView.
A new mechanistic pathway for the CuAAC reaction has been found to operate under specific reaction conditions. The pathway is catalysed by Cu(II) through a self‐assembled dinuclear Cu(II) complex that incorporates the triazole product. Computational analysis and assessment of generality are reported.
Matthew J. Andrews   +12 more
wiley   +1 more source

Sanomalehden luonnonhistoria

open access: yesMedia & Viestintä, 1981
Robert E. Park
doaj  

Borosulfates Hosting Se42+ Ions—Crystal Structures, Chemical Bonding, Optical Spectroscopy, and Magnetism

open access: yesAngewandte Chemie, EarlyView.
Apart from (transition) metal (oxo)halides only few hosts stabilize chalcogenide cations in purely oxoanionic coordination environment. Herein, we report on five borosulfates containing the Se42+ ion and characterize the compounds using X‐ray diffraction, diffuse reflectance spectroscopy, density functional theory (DFT) calculations along with magnetic
Erich Turgunbajew   +11 more
wiley   +1 more source

Sociología, comunidad y sociedad

open access: yesEMPIRIA: Revista de Metodología de Ciencias Sociales, 2013
Robert E. Park
doaj  

Multiple Myeloma-Derived Cellular Lipids Enhance Targeting and Efficacy of Nanoliposome Formulations In Vitro. [PDF]

open access: yesInt J Mol Sci
Amorin M   +8 more
europepmc   +1 more source

De Novo Design and Structural Optimization of Mn(salen)‐Based Artificial Metalloenzymes for Asymmetric Sulfoxidation

open access: yesAngewandte Chemie, EarlyView.
We report the computational design of de novo proteins that bind Mn(salen)‐based complexes (L1) using Rosetta FastDesign and verified by AlphaFold2. After screening, the catalytic activity for the promising design (dnMSBP) toward enantioselective sulfoxidation of thioanisole was optimized based on its crystal structure. With 10 different substrates, we
Jing‐Xiang Wang   +6 more
wiley   +1 more source

Luminescence Vapochromism of a Cu(I)/Na Phosphane Iodide Assembly Based on a Secondary‐Sphere Sodium Response

open access: yesAngewandte Chemie, EarlyView.
The luminescence of a heterometallic d‐s {Cu2I2Na2} phosphane‐phosphinate aggregate is regulated by an interplay of Na+–π/I– contacts and reversible coordination of oxygen‐containing organic molecules to Na ions. Structural variations caused by the incoming guest lead to a wide and selective variation of the emission color and illustrate a new approach
Henna Korhonen   +10 more
wiley   +1 more source

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