Results 31 to 40 of about 44,104 (300)
Efficient Synthesis of Narrowly Dispersed Brush Copolymers and Study of Their Assemblies: The Importance of Side Chain Arrangement [PDF]
, 2009 Efficient, one-pot preparation of synthetically challenging, high molecular weight (MW), narrowly dispersed brush block copolymers and random copolymers in high conversions was achieved by ring-opening metathesis (co)polymerization (ROMP) of various ...
Grubbs, Robert H. +3 more
core +1 more source
Ruthenium Olefin Metathesis Catalysts Bearing Carbohydrate-Based N-Heterocyclic Carbenes [PDF]
, 2010 Ru-based olefin metathesis catalysts containing carbohydrate-derived NHCs from glucose and galactose were synthesized and characterized by NMR spectroscopy. 2D-NMR spectroscopy revealed the presence of Ru−C (benzylidene) rotamers at room temperature, and
Grubbs, Robert H., Keitz, Benjamin K.
core +2 more sources
Journal of Applied Polymer Science, 2017 ABSTRACTThe present work focuses on the investigation of the thermal and dielectric properties of composites obtained by surface‐modified hexagonal boron nitride (hBN) and ring‐opening metathesis polymerization (ROMP) based polymer. A new kind of high performance composites was developed based on using amino silane functionalized hBN (AS‐hBN) and ...
Keziban Hüner +4 more
openaire +4 more sources
Beilstein Journal of Organic Chemistry, 2016 A straightforward synthesis utilizing the ring-opening metathesis polymerization (ROMP) reaction is described for acid-triggered N,O-chelating ruthenium-based pre-catalysts bearing one or two 8-quinolinolate ligands.
Julia Wappel +4 more
doaj +1 more source
Branched Polymers via ROMP of Termimers [PDF]
Macromolecular Rapid Communications, 2016 Today's olefin metathesis catalysts show high reactivity, selectivity, and functional group tolerance and allow the design of new syntheses of precisely functionalized polymers. Here the synthesis of a new end-capping reagent is investigated allowing the introduction of a highly reactive activated ester end-group at the polymer chain end as well as its
Hanik Nils, Kilbinger A.F.M.
openaire +3 more sources
Beilstein Journal of Organic Chemistry, 2019 This mini-review summarizes the applications of olefin metathesis in synthesis and functionalization of polyhedral oligomeric silsesquioxanes (POSS) and POSS-containing polymeric materials.
Patrycja Żak, Cezary Pietraszuk
doaj +1 more source
Drug-Loaded, Bivalent-Bottle-Brush Polymers by Graft-through ROMP [PDF]
, 2010 Graft through ring-opening metathesis polymerization (ROMP) using ruthenium N heterocyclic carbene catalysts has enabled the synthesis of bottle-brush polymers with unprecedented ease and control Here we report the first bivalent-brush polymers, these ...
Burts, Alan O. +6 more
core +1 more source
EPR Study of Spin Labeled Brush Polymers in Organic Solvents [PDF]
, 2011 Spin-labeled polylactide brush polymers were synthesized via ring-opening metathesis polymerization (ROMP), and nitroxide radicals were incorporated at three different locations of brush polymers: the end and the middle of the backbone, and the end of ...
Burts, Alan O. +7 more
core +2 more sources
Chemoselective Sequential Polymerization: An Approach Toward Mixed Plastic Waste Recycling
Advanced Functional Materials, EarlyView.Inspired by biological protein metabolism, this study demonstrates the closed‐loop recycling of mixed synthetic polymers via ring‐closing depolymerization followed by a chemoselective sequential polymerizations process. The approach recovers pure polymers from mixed feedstocks, even in multilayer formats, highlighting a promising strategy to overcome a
Gadi Slor +5 more
wiley +1 more source
SI‐bioATRP in Mesoporous Silica for Size‐Exclusion Driven Local Polymer Placement
Advanced Functional Materials, EarlyView.An enzyme‐catalyzed surface‐initiated atom transfer radical polymerization (SI‐bioATRP) of an anionic monomer within mesoporous silica particles, using hemoglobin as a catalyst, allows for controlling the location of the formed polymer via size‐exclusion effects between the nanopores and the biomacromolecules, thereby opening routes to functional ...
Oleksandr Wondra +8 more
wiley +1 more source