Results 91 to 100 of about 4,426,538 (221)

Aggregation‐Controlled Triplet Exciton Regulation Enables Single‐Emitter Color‐Evolving Afterglow

open access: yesAdvanced Science, EarlyView.
A single‐emitter system based on DTP‐R luminophores enables time‐evolving afterglow through aggregation‐regulated excited‐state dynamics. The coexistence and suppression of delayed fluorescence and phosphorescence are controlled via concentration tuning and host‐guest engineering, revealing the RISC origin of delayed fluorescence and enabling ...
Yu Zhang   +14 more
wiley   +1 more source

Dopant‐Tailored Matrices: A Crystal Engineering Strategy for Organic Room‐Temperature Phosphorescent Host–Guest Systems and Beyond

open access: yesAngewandte Chemie, EarlyView.
Rather than selecting dopants to match a pre‐existing host matrix, the dopant‐tailored matrix strategy involves rational engineering of host matrices around a preselected class of dopants by targeting matrix packing motifs that promote synergistic host‐dopant interactions upon doping.
Catherine Demangeat   +7 more
wiley   +2 more sources

TADF‐Active Tetrazole Luminophores for Visible‐Light Functionalization of Nanoparticles and Surfaces

open access: yesAngewandte Chemie, EarlyView.
A series of tetrazoles are reported that undergo 1,3‐dipolar cycloadditions with alkene and alkyne substrates, generating (dihydro)pyrazole products that exhibit thermally activated delayed fluorescence (TADF). The “photo‐click” reactivity of these tetrazoles is leveraged to functionalize nanoparticles and surfaces with TADF‐active chromophores ...
Ryoga Hojo   +11 more
wiley   +2 more sources

Early Spatial and Contextual Coding Deficits in Hippocampal CA1 Precede Performance Decline in an Alzheimer's Disease Model

open access: yesAdvanced Science, EarlyView.
Two‐photon calcium imaging in behaving 5xFAD mice reveals early CA1 coding deficits before behavioral decline. Task‐related place cell activity and splitter cell trajectory coding are impaired, with reduced retrospective dominance and greater prospective weighting.
Yimei Li   +8 more
wiley   +1 more source

Force‐Induced Control of Circularly Polarized Luminescence With Rotaxane Architecture

open access: yesAngewandte Chemie, EarlyView.
Force‐induced reversible on/off switching of circularly polarized luminescence is achieved with a rotaxane‐based supramolecular mechanophore. The mechanophore, featuring a chiral helicene luminophore, is incorporated as a first network cross‐linker into a double‐network organogel.
Keigo Nonaka   +10 more
wiley   +2 more sources

Tuning Steric Hindrance and Intermolecular Interactions in Tetrahydroindolocarbazoles for Dual Thermally Activated Delayed Fluorescence and Room‐Temperature Phosphorescence

open access: yesChemistryEurope
Synthesizing organic luminescent materials exhibiting long‐lived afterglow at room temperature, through room‐temperature phosphorescence (RTP) and thermally activated delayed fluorescence (TADF), properties in pure organic derivatives remains a challenge,
Nagham Ibrahim   +3 more
doaj   +1 more source

Fluorene‐Framework Engineering Enables Narrowband Red Multi‐Resonance Emitters for High‐Efficiency With Negligible Roll‐Off Toward BT.2020

open access: yesAngewandte Chemie, EarlyView.
σ‐Decoupled C9 fluorene‐framework topology control enables narrowband red MR emitters. SF‐BNO and PF‐BNO share the same BNO core, but differ in closed/open fluorene ring closure. SF‐BNO improves steric shielding and stability, while PF‐BNO enhances PLQY, orientation, and efficiency. Ex‐PSF and TE‐OLED architectures deliver ultra‐low efficiency roll‐off
Aradhya Rajput   +7 more
wiley   +2 more sources

Integrated Optoelectronic Model to Predict the External Quantum Efficiency of Single‐Layer TADF Organic Light‐Emitting Diodes

open access: yesAdvanced Electronic Materials, EarlyView.
An experimentally validated optoelectronic device model is presented to describe the efficiency and roll‐off behavior of single‐layer TADF OLEDs. By coupling charge transport, exciton dynamics, and optical outcoupling, the model reproduces the External Quantum Efficiency (EQE) across different emission layer thicknesses and temperatures, offering ...
Jawid Nikan   +4 more
wiley   +1 more source

Roles of Localized Electronic Structures Caused by π Degeneracy Due to Highly Symmetric Heavy Atom‐Free Conjugated Molecular Crystals Leading to Efficient Persistent Room‐Temperature Phosphorescence

open access: yesAdvanced Science, 2019
Conjugated molecular crystals with persistent room‐temperature phosphorescence (RTP) are promising materials for sensing, security, and bioimaging applications.
Shuzo Hirata
doaj   +1 more source

Synthesis and charaterisation of phosphorescent copper (I) complexes for light emitting devices [PDF]

open access: yes, 2013
This thesis was submitted for the degree of Doctor of Philosophy and awarded by Brunel University.Over the last decade, many significant developments have been made to improve the active materials in a new generation of organic light emitting devices ...
Andrés-Tomé, María Inmaculada
core   +2 more sources

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