Results 71 to 80 of about 4,426,538 (221)

Immediate Organic Room‐Temperature Phosphorescence in Programmable Luminescent Tags Enabled by Oxygen‐Free Fabrication

Advanced Materials Technologies, EarlyView.
Programmable luminescent tags based on organic room‐temperature phosphorescence are shown to be governed by oxygen incorporation during fabrication. Oxygen‐free processing enables immediate phosphorescence activation, controlled thermal preconditioning, and tunable activation doses.
Lucy Winkler, Karl Sebastian Schellhammer, Sebastian Reineke   +2 more
wiley   +1 more source

Mechanical Stretch α‐Cyclodextrin Pseudopolyrotaxane Elastomer with Reversible Phosphorescence Behavior

Advanced Science
Polyethylene glycol chains in two terminals of the naphthalene functional group are threaded into α‐cyclodextrin cavities to form the pseudopolyrotaxane (NPR), which not only effectively induces the phosphorescence of the naphthalene functional group by ...
Yi Zhang, Yong Chen, Jian‐Qiu Li, Song‐En Liu, Yu Liu   +4 more
doaj   +1 more source

Room temperature phosphorescence lifetime and spectrum tuning of substituted thianthrenes [PDF]

, 2017
A group of thianthrene derivatives has been studied to investigate the effect of different substituents and substitution positions on their photophysical behavior.
Piotr Pander, Fernando B. Dias, Swist, Agnieszka, Soloducho, Jadwiga, Agnieszka Swist, Dias, Fernando B., Jadwiga Soloducho, Pander, Piotr   +7 more
core   +1 more source

Photoluminescence Reshaping via Structural Confinement and Local Density of Optical States Control in Ir(III)‐Doped Biodegradable Metasurfaces

Advanced Materials Technologies, EarlyView.
Phosphorescent biodegradable metasurface showing vibronic selection and spectral photoluminescence narrowing. Anti‐correlation between experimental LDOS and measured lifetimes. ABSTRACT Metasurfaces incorporating phosphorescent emitters offer a route to engineer radiative and vibronic processes beyond chemical design.
Vincenzo Caligiuri, Andrea Smeriglio, Svetlana Siprova, Olga Favale, Francesca Leone, Roberto Termine, Debora Policastro, Alessandra Crispini, Attilio Golemme, Nicolas Godbert, Iolinda Aiello, Antonio De Luca   +11 more
wiley   +1 more source

Continuous Condensed Triplet Accumulation for Irradiance‐Induced Anticounterfeit Afterglow

Advanced Science, 2023
Afterglow room‐temperature emission that is independent of autofluorescence after ceasing excitation is a promising technology for state‐of‐the‐art bioimaging and security devices.
Ende Hopsah Badriyah, Kikuya Hayashi, Bahadur Sk, Rina Takano, Takayuki Ishida, Shuzo Hirata   +5 more
doaj   +1 more source

Tailoring Amine Substitution in Fluorene and Dibenzothiophene: A Molecular Strategy for Ultralong Organic Phosphorescence

Advanced Optical Materials, EarlyView.
Tailored amine substitution in fluorene and dibenzothiophene derivatives enables systematic control of excited‐state properties and triplet population. Combined photophysical studies, TD‐DFT calculations and time‐resolved EPR reveal how charge‐transfer character, sulfur‐induced spin–orbit coupling and triplet manifold engineering cooperate to promote ...
Francesco Ruighi, Gianluca Accorsi, Eduardo Fabiano, Lorenzo Franco, Alessandro Agostini, Samuel Zatta, Leonard E. Cleve, Federica Angilè, Francesco Paolo Fanizzi, Gustavo Fernández, Agostina L. Capodilupo   +10 more
wiley   +1 more source

DataSheet1_Modulating Room-Temperature Phosphorescence-To-Phosphorescence Mechanochromism by Halogen Exchange.PDF

, 2022
Modulating the stimulus-responsiveness of a luminescent crystal is challenging owing to the complex interdependent nature of its controlling factors, such as molecular structure, molecular conformation, crystal packing, optical properties, and ...
Yosuke Tani (1699978), Takuji Ogawa (1716853), Yoshika Takewaki (11941070)   +2 more
core   +1 more source

Revealing Mechanofluorochromism and Intricate Long‐lived Decay Pathways in Keto‐Coumarin‐Based Molecular Crystals

Advanced Optical Materials, EarlyView.
Donor–acceptor organic emissive materials show great promise in cutting‐edge optical applications. Herein, the photophysical properties of two keto‐coumarin organic materials are studied in detail. Both show mechanofluorochromism, but a diphenylamine donor derivative exhibits intricate decay pathways in the crystal form, including decays ranging from ...
Peter W. McDonald, Subhadeep Das, Arnab Mandal, Gilles Clavier, Clémence Allain, Abhijit Patra, Rémi Métivier   +6 more
wiley   +1 more source

Activating Triplet Excitons in COFs via Layer‐Bridging Co Single Atoms for Photocatalytic H2O2 Production and Tandem C─N Coupling

Angewandte Chemie, EarlyView.
This work demonstrates a layer‐bridging coordination strategy of Co single atoms in COFs that promotes the formation and utilization of triplet excited states. The introduction of Co single atoms induces pronounced energy‐level splitting and enhanced spin–orbit coupling, facilitating the generation of 1O2 and O2•– for efficient photocatalytic H2O2 ...
Guoen Tang, Jianjun Zhang, Guijie Liang, Jinfeng Zhang, Chuanbiao Bie, Jiaguo Yu, Hermenegildo García   +6 more
wiley   +2 more sources

Efficient Polaron Recombination and Fast Energy Transfer in a Deep Blue Phosphorescent Pt(II) Complex via Covalently Fused p‐Type Host

Advanced Science, EarlyView.
Achieving high‐efficiency deep‐blue phosphorescent OLEDs is limited by intermolecular kinetic bottlenecks. We overcome this using a single‐molecule fused emitter architecture, Pt‐SP‐tCz, combining a p‐type host and Pt(II) dopant. This design enables zero‐radius intramolecular energy transfer (ZRIET) and a novel ZETPLEX mechanism.
You Na Song, Bubae Park, Garam Han, Eun Bi Kim, Junseop Lim, Wan Pyo Hong, Sunwoo Kang, Jae‐Min Kim, Hyung Youn Oh, Taekyung Kim   +9 more
wiley   +1 more source