Structure of the Cytoplasmic Loop between Putative Helices II and III of the Mannitol Permease of Escherichia coli: A Tryptophan and 5-Fluorotryptophan Spectroscopy Study [PDF]
In this work, four single tryptophan (Trp) mutants of the dimeric mannitol transporter of Escherichia coli, EIImtl, are characterized using Trp and 5-fluoroTrp (5-FTrp) fluorescence spectroscopy.
Broos J. +32 more
core +3 more sources
Functional Metal Complexes for Solar–Light‐Driven Energy Conversion
This review provides an exhaustive summary of the recent advancements of functional metal complexes in solar‐to‐electrical, ‐chemical, and ‐thermal energy conversion, comprising material categories, design strategies, underlying principles of operation, and identified improvement of performances.
Yanyan Qin +3 more
wiley +1 more source
Hydrogen Atom Transfer Induces Photodegradation in Carbonyl‐Based Multi‐Resonance TADF Emitters
Boosting triplet harvesting in N/C═O MR‐TADF emitters unexpectedly induces rapid photodegradation under oxygen‐free conditions. Spectroscopic studies reveal that triplet excited states trigger hydrogen‐atom transfer from solvent to the carbonyl unit, driven by triplet energetics and hydrogen electrophilicity.
Changfeng Si +4 more
wiley +2 more sources
Efficient Room-Temperature Luminescence of Indole-5-Carboxamide in Poly(vinyl alcohol) Films
N-phenyl-1H-Indole-5-carboxamide (Ind-CA) exhibits previously unknown room-temperature phosphorescence (RTP) when immobilized in poly (vinyl alcohol) film (PVA film).
Bong Lee +7 more
doaj +1 more source
Continuous Condensed Triplet Accumulation for Irradiance‐Induced Anticounterfeit Afterglow
Afterglow room‐temperature emission that is independent of autofluorescence after ceasing excitation is a promising technology for state‐of‐the‐art bioimaging and security devices.
Ende Hopsah Badriyah +5 more
doaj +1 more source
Deactivation of biacetyl triplets by cyanocobaltate(III) complexes [PDF]
The rate of electronic energy transfer from biacetyl triplets to Co(CN)_(5)(X)^(n–)(X = CN^–, MeCN, pyridine, N_(3)^–, H_(2)O, or SCN^–) is strongly dependent on the energy of the first spin-allowed d–d transition of Co(CN)_(5)(X)^(n–), and (for X = CN^–,
Bredesen, Dale +3 more
core +1 more source
Transparent Perovskite Light‐Emitting Diodes with Conductive Oxide Top Electrodes
Transparent perovskite light‐emitting diodes (TrPeLEDs) enable simultaneous display and transparency, expanding application possibilities. Using a metal oxide buffer layer and pulsed laser deposition, TrPeLEDs with diverse compositions and architectures are demonstrated.
Michele Forzatti +11 more
wiley +1 more source
A novel carbon dots material (BUL‐CDs) with an initial afterglow brightness (406 cd m−2) far exceeding that of other afterglow luminescent materials was developed. Furthermore, the BUL‐CDs exhibited time‐dependent afterglow colors, excitation‐dependent afterglow colors, and thermochromic afterglow in response to triplet variables.
Yupeng Liu +13 more
wiley +2 more sources
Iridium complex, a phosphorescent light-emitting diode material, serves as a novel chemical probe for imaging hypoxic tumor tissues [PDF]
Iridium complex, a promising organic light-emitting diode for next generation television displays, emits phosphorescence. Phosphorescence is quenched by oxygen. We used this oxygen-quenching feature for imaging tumor hypoxia.
Keigo Endo +6 more
core +1 more source
A hybridized charge‐transfer window combining short‐range and long‐range charge transfer is realized within a fully conjugated multi‐resonance thermally activated delayed fluorescence framework. The resulting excited‐state hybridization minimizes the singlet–triplet energy gap (0.04 eV) and enables ultrafast reverse intersystem crossing (krISC = 2.1 ...
Uisung Lee +3 more
wiley +1 more source

