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Criegee intermediates meet rotational spectroscopy
, 2020Carbonyl oxides, R1R2COO, alternatively known as Criegee intermediates (CIs), are short-lived molecules produced from ozonolysis of alkenes. These ozonolysis reactions yield highly excited CIs, and most of them promptly decay with emission of the OH ...
C. Cabezas, M. Nakajima, Y. Endo
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2016
This chapter derives expressions for the rotational energy levels of diatomic and polyatomic molecules. It shows how to interpret rotational spectra, in which only the rotational state of a molecule changes. It also emphasizes how rotational spectroscopy provides very precise details of bond lengths and bond angles of molecules in the gas phase.
Peter Atkins +2 more
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This chapter derives expressions for the rotational energy levels of diatomic and polyatomic molecules. It shows how to interpret rotational spectra, in which only the rotational state of a molecule changes. It also emphasizes how rotational spectroscopy provides very precise details of bond lengths and bond angles of molecules in the gas phase.
Peter Atkins +2 more
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Methylsalicylate: A Rotational Spectroscopy Study
The Journal of Physical Chemistry A, 2007We report the free-jet rotational spectra of methylsalicylate, a molecule with a possible tautomeric and conformational equilibrium. In the ground electronic state, the molecule adopts a form stabilized by an intramolecular hydrogen bond between the phenolic hydrogen and the carbonylic oxygen, and this structure is characterized as the lowest-energy ...
MELANDRI, SONIA +6 more
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Rotational spectroscopy of the two higher energy conformers of 2-cyanobutane
Journal of Molecular Spectroscopy, 2019We present high-resolution rotational spectroscopy of the two higher energy conformers of 2-cyanobutane (C4H9CN). We analysed spectra starting from 12 to 27 GHz using the Cologne chirped-pulse (CP) Fourier transform microwave spectrometer, which we ...
M. Hermanns +4 more
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Double resonance rotational spectroscopy of He-HCO.
Physical Chemistry, Chemical Physics - PCCP, 2019The ground state of He-HCO+ is investigated using a recently developed double resonance technique, consisting of a rotational transition followed by a vibrational transition into a dissociative state.
T. Salomon +6 more
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Journal of Chemical Education, 1987
Representative examples of the spectra and the analyses for a linear molecule (HCl), a symmetric top molecule (NH3), and an assymetric top (H2O).
Ron Woods, Giles Henderson
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Representative examples of the spectra and the analyses for a linear molecule (HCl), a symmetric top molecule (NH3), and an assymetric top (H2O).
Ron Woods, Giles Henderson
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Vibration-Rotation Spectroscopy
Annual Review of Physical Chemistry, 1956Approximately four hundred titles pertaining to the topic of vibration rotation spectra appeared during the calendar year 1955 among the contents of the forty-three periodicals that we attempted to survey. Merely to list this bibliography without comment, in the conventional style, would con sume more than half of the printed pages assigned to this ...
R S Halford, I Ichishima
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Physical Review Letters, 2018
A novel rotational spectroscopy method applicable to ions stored in cold traps is presented. In a double resonance scheme, rotational excitation is followed by vibrational excitation into a dissociative resonance.
Matthias Töpfer +6 more
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A novel rotational spectroscopy method applicable to ions stored in cold traps is presented. In a double resonance scheme, rotational excitation is followed by vibrational excitation into a dissociative resonance.
Matthias Töpfer +6 more
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2013
Contents Microwave spectroscopy 396 Selection rules 396 Brief illustration 42.1: Gross selection rules for microwave spectroscopy 397 The appearance of microwave spectra 398 Example 42.1: Predicting the appearance of a rotational spectrum 398
Peter Atkins +2 more
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Contents Microwave spectroscopy 396 Selection rules 396 Brief illustration 42.1: Gross selection rules for microwave spectroscopy 397 The appearance of microwave spectra 398 Example 42.1: Predicting the appearance of a rotational spectrum 398
Peter Atkins +2 more
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Rotational spectroscopy meets theory
Physical Chemistry Chemical Physics, 2013Rotational spectroscopy is known to be a technique that is widely used to infer information on molecular structure and dynamics. In the last few decades, its role in the field of atmospheric and astrophysical investigations has rapidly grown. However, several are the challenging aspects in rotational spectroscopy, since the detection and analysis of ...
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