Results 151 to 160 of about 47,611 (304)
Advanced Materials, EarlyView.AI‐Assisted Workflow for (Scanning) Transmission Electron Microscopy: From Data Analysis Automation to Materials Knowledge Unveiling. Abstract (Scanning) transmission electron microscopy ((S)TEM) has significantly advanced materials science but faces challenges in correlating precise atomic structure information with the functional properties of ...
Marc Botifoll +19 more
wiley +1 more source
Advanced Materials, EarlyView.The water permeability of amorphous carbon dots (CDs) is demonstrated by investigating their plasticization. Novel polyamide‐based and amorphous nanoparticles are synthesized by controlling their inner packing density. Water plasticization is evidenced by the decrease of the CDs glass transition temperature with increasing the hydration degree.
Elisa Sturabotti +8 more
wiley +1 more source
Nonlinear rotational spectroscopy reveals many-body interactions in water molecules. [PDF]
Proc Natl Acad Sci U S A, 2021 Zhang Y +5 more
europepmc +1 more source
Solvent‐Free Thermal Defect Engineering in Molecular Frameworks With Volatile Linkers
Advanced Materials, EarlyView.Thermal removal of neutral volatile linkers enables precise and solvent‐free generation of metal vacancies in MOFs. This strategy affords redox‐stable, coordinatively unsaturated FeII sites with tunable spin, ligand coordination, and catalytic behavior. The approach offers a general route to design defect‐functional materials through local coordination
Sonia Martínez‐Giménez +9 more
wiley +1 more source
Benchmark Structures and Conformational Landscapes of Amino Acids in the Gas Phase: A Joint Venture of Machine Learning, Quantum Chemistry, and Rotational Spectroscopy. [PDF]
J Chem Theory Comput, 2023 Barone V, Fusè M, Lazzari F, Mancini G.
europepmc +1 more source
In Situ Amine Formation to Modulate MOF‐Derived PdIn N‐Doped Carbon Catalysts
Advanced Materials, EarlyView.An amine‐assisted approach converts PdIn‐MOF into PdIn intermetallic nanoparticles embedded in N‐doped carbon. In situ‐generated amines trigger early Pd nucleation, producing smaller PdIn domains than direct pyrolysis. Amine sterics and basicity tune composition and particle size, while solvent and amine co‐determine textural features.
Gonzalo Egea +9 more
wiley +1 more source
High Charge Carrier Mobility in Non‐Conjugated 3D Covalent Organic Frameworks
Advanced Materials, EarlyView.A non‐conjugated 3D COF constructed via boronate ester linkages from tetraphenylene and pyrene‐based monomers is reported, which exhibits a high charge carrier mobility of 14 ± 1 cm2 V−1 s−1. ABSTRACT π‐Conjugation, π–π stacking, and long‐range order play a central role in determining charge transport efficiency in organic materials.
Joaquín Almarza +11 more
wiley +1 more source
The Astrophysical JournalWe synthesized the astrochemically relevant molecule 3-hydroxypropanal (HOCH _2 CH _2 CHO) and subsequently measured and analyzed its rotational spectrum in several frequency regions ranging from 130 to 485 GHz.
Zachary T. P. Fried +14 more
doaj +1 more source
DESIGNING CHIRAL TAGS TO IMPROVE ABSOLUTE CONFIGURATION DETERMINATION BY ROTATIONAL SPECTROSCOPY
Determining the absolute configuration (AC) of a chiral analyte is a challenging analytical problem. In 2013, Patterson, Schnell, and Doyle showed that molecular rotational spectroscopy can be used to determine AC through the phase of a coherent emission
West, Channing
core +1 more source
Advanced Materials, EarlyView.We introduce a molecular strategy to assemble one‐dimensional (1D) materials into two‐dimensional (2D) van der Waals metal–organic frameworks (MOFs). Crystals of [FeX(pzX)(bpy)] (X = Cl, F) form anisotropic 2D layers that can be mechanically exfoliated into thin sheets.
Eleni C. Mazarakioti +12 more
wiley +1 more source