Results 131 to 140 of about 3,352,928 (273)

Readily Accessible bTurea‐Derived Nitroxide Polarizing Agents for Dynamic Nuclear Polarization: bcTCOOKs and bcTmols

open access: yesChemistry – A European Journal, EarlyView.
Two families of bTurea‐derived biradicals, bcTmols and bcTCOOKs, were prepared as polarizing agents for dynamic nuclear polarization (DNP)‐enhanced NMR through short and efficient synthetic routes. The best‐performing biradical, bcTCOOK‐M2, containing two methyl groups on the urea bridge, provided signal enhancements of up to ∼220 at 14.1 T and 100 K ...
Ancy T. Wilson   +3 more
wiley   +1 more source

Synthesis and Photophysical Properties of Star‐Shaped Triphenylamine Trimers Functionalized With BODIPY and Subphthalocyanine Chromophores

open access: yesChemistry – A European Journal, EarlyView.
This study investigates how molecular topology influences the photophysical properties of star‐shaped, threefold‐symmetric triphenylamine (TPA) derivatives functionalized with three BODIPY or SubPc units. Their absorption spectra exhibit minimal solvatochromism, whereas their fluorescence intensity is strongly dependent on solvent polarity.
Habiba Boughanmi   +4 more
wiley   +1 more source

Long Fluorescence Lifetime Molecular Rotors Based on the 4,4‐Dicyano‐BODIPY Core

open access: yesChemistry – A European Journal, EarlyView.
Substituting fluorine with cyano groups in BODIPY‐based fluorescent molecular rotors yields viscosity‐sensitive dyes with significantly enhanced fluorescence lifetimes that can be used for viscosity mapping in living cells using FLIM microscopy. ABSTRACT Environmentally sensitive fluorescent probes with extended emission lifetimes are highly valuable ...
Yelyzaveta Denysieva   +4 more
wiley   +1 more source

Structure–Activity Relationships in Methyl‐Driven Overhauser Effect DNP

open access: yesChemistry – A European Journal, EarlyView.
Dynamic nuclear polarization (DNP) was investigated in a wide array of methyl‐containing Blatter radicals to identify design principles for the synthesis of an Overhauser DNP polarizing agent. Fourteen different radicals were synthesized, which revealed that only radicals possessing sterically unhindered methyl groups in sites of high spin density were
Ananya Mukherji   +15 more
wiley   +1 more source

Fe–Ca‐Catalyzed Conversion of Cellulose Into Highly Ordered Graphitic Carbon Revealed by Solid‐State 13C NMR and Mössbauer Spectroscopy

open access: yesChemistry – A European Journal, EarlyView.
New insights into the mechanism of the structural transformation of cellulose into highly ordered graphitic carbon using an Fe–Ca bimetallic catalyst were obtained through complementary spectroscopic techniques, including Raman, solid‐state NMR, and Mössbauer.
Shamala Gowri Krishnan   +3 more
wiley   +1 more source

Reverse Engineering and Performance Evaluation of a Pump Impeller Fabricated With Additive Manufacturing

open access: yesChemie Ingenieur Technik, EarlyView.
This study explores the process chain for reverse engineering and additive manufacturing of a water pump impeller in a process plant. Key aspects include digital twin creation, CAD redesign, material certification, Hirtisation postprocessing, and performance testing. Insights highlight iterative design for improved precision and reliability.
Michael Stadler   +3 more
wiley   +1 more source

Sliding Mode Observer with Exponential Reaching Law for Speed Estimation of a Six-Phase Induction Machine. [PDF]

open access: yesSensors (Basel)
Delorme L   +6 more
europepmc   +1 more source

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