Ruthenium-Catalyzed Enantioselective Hydrogenation of Phenanthridine Derivatives [PDF]
The first asymmetric hydrogenation of phenanthridines catalyzed by chiral cationic ruthenium diamine complexes has been developed with up to 92% ee and full conversions.
Fei Chen (13690) +5 more
core +3 more sources
Ruthenium-Catalyzed C–H Alkynylation of Aromatic Amides with Hypervalent Iodine–Alkyne Reagents [PDF]
An efficient C–H activation method for the ortho alkynylation of aromatic N-methoxyamides with hypervalent iodine–alkyne reagent using a ruthenium catalyst is described. The reaction proceeds under mild reaction conditions with broad substrate scope.
Parthasarathy Gandeepan (1429120) +2 more
core +1 more source
Ruthenium complexes are well known for their electrochemical activity, which could be attributed to the presence of stable ruthenium complexes with divalent ruthenium center, Ru2+.
Eyad S.M. Abu-Nameh +4 more
doaj +1 more source
Ruthenium-Mediated Regio- and Stereoselective Alkenylation of Pyridine [PDF]
A novel alkenylation reaction of pyridine is developed. Heating a cationic ruthenium vinylidene complex [CpRu(CCHR)(PPh3)2]PF6 in pyridine at 100−125 °C for 24 h affords (E)-2-alkenylpyridine.
Seiji Hori (2991612) +1 more
core +1 more source
Ruthenium-Catalyzed Transformation of Ethylene Glycol for Selective Hydrogen Gas Production in Water [PDF]
We developed an efficient process for producing hydrogen gas from aqueous ethylene glycol (EG) at 90–160 °C over a ruthenium catalyst. We achieved a high yield of hydrogen gas (up to 3.0 n(H2)/n(EG)) and formic acid (85% yield) from ethylene glycol in ...
Bhanu Priya (8490312) +2 more
core +1 more source
Ruthenium-Catalyzed Intramolecular Double Hydroalkoxylation of Internal Alkynes [PDF]
Intramolecular double hydroalkoxylation of internal alkynes could be achieved using a Grubbs-type ruthenium carbene complex or its modified species to deliver a series of bridged- and spiroacetal derivatives in moderate to good yields.
Shusuke Sachimori (6052535) +3 more
core +1 more source
Ruthenium-Catalyzed [3 + 2] Cycloaddition of 2H‑Azirines with Alkynes: Access to Polysubstituted Pyrroles [PDF]
A ruthenium-catalyzed intermolecular [3 + 2] cycloaddition of 2H-azirines and activated alkynes is reported, which provides polysubstituted pyrroles in moderate to good yields.
Hao Yan (134033) +4 more
core +3 more sources
Ruthenium-Catalyzed Asymmetric Hydrosilylation of Ketones and Imine [PDF]
Ruthenium complexes with (oxazolinylferrocenyl)phosphines, RuCl2(PPh3)((oxazolinylferrocenyl)phosphine), have been prepared and characterized by spectroscopy.
Masanobu Hidai (2426068) +3 more
core +1 more source
Unusual DNA binding modes for metal anticancer complexes [PDF]
DNA is believed to be the primary target for many metal-based drugs. For example, platinum-based anticancer drugs can form specific lesions on DNA that induce apoptosis.
Pizarro, Ana M., Sadler, P. J.
core +1 more source
Ruthenium Sensitizers and Their Applications in Dye-Sensitized Solar Cells
Dye-sensitized solar cells (DSSCs) have attracted considerable attention in recent years due to the possibility of low-cost conversion of photovoltaic energy. The DSSCs-based ruthenium complexes as sensitizers show high efficiency and excellent stability,
Yuancheng Qin, Qiang Peng
doaj +1 more source

