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Oxygenation of a Ruthenium(II) Thiolate to a Ruthenium(II) Sulfinate Proceeds via Ruthenium(III)
Inorganic Chemistry, 2005Exposure of acetonitrile/methanol solutions of [PPN][Ru(DPPBT)3] [PPN = bis(triphenylphosphoranylidene); DPPBT = 2-diphenylphosphinobenzene thiolate] to oxygen initiates metal-centered oxidation, yielding the ruthenium(III) thiolate Ru(DPPBT)3. Ru(DPPBT)3 further reacts with oxygen, at sulfur, to give the ruthenium(III) sulfinate complex [Ru(DPPBT-O2)2(
Selma Poturovic +2 more
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Inorganic Chemistry, 1992
AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
Angus P. Wilkinson +4 more
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AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
Angus P. Wilkinson +4 more
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On the volatility of ruthenium [PDF]
Journal of Radioanalytical Chemistry, 1978 When annealing the evaporation residue formed by evaporating a solution containing ruthenium, phosphates and nitrates, ruthenium volatilizes. The amount of volatilized ruthenium (both106Ru traces and milligram amuonts of Ru) depends on the solution composition before evaporation and on the temperature and time of annealing.
M. Křivánek, Z. Hölgye
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ChemInform Abstract: RUTHENIUM AQUA IONS ‐ THEIR COMPARISON TO RUTHENIUM AMMINES
Chemischer Informationsdienst, 1983Abstract Similarities and contrasts in the descriptive chemistry of aqua and ammine complexes of mthenium are discussed. The reactivities of the two classes of coordination compounds are compared; both show a remarkable tendency to form complexes with π-accepting ligands, including alkenes and alkynes.
Andreas Ludi +2 more
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2004
Several ruthenium-based compounds have been proven to posses interesting biological properties that can lead to innovative drugs, particularly in the field of cancer treatment. The capacity of such compounds to bind to imine groups with a relatively high affinity has raised a great interest about the possibility to develop anticancer agents.
ALESSIO, ENZO +3 more
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Several ruthenium-based compounds have been proven to posses interesting biological properties that can lead to innovative drugs, particularly in the field of cancer treatment. The capacity of such compounds to bind to imine groups with a relatively high affinity has raised a great interest about the possibility to develop anticancer agents.
ALESSIO, ENZO +3 more
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The Microbiology of Ruthenium Complexes
2017Ruthenium is seldom mentioned in microbiology texts, due to the fact that this metal has no known, essential roles in biological systems, nor is it generally considered toxic. Since the fortuitous discovery of cisplatin, first as an antimicrobial agent and then later employed widely as an anticancer agent, complexes of other platinum group metals, such
Southam, HM +3 more
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Electrodeposition of Ruthenium
Transactions of the IMF, 1961SYNOPSISExploratory plating tests have been carried out on a number of aqueous electrolytes based on simple ruthenium salts and nitrosyl derivatives. The nitrosyl sulphamate electrolyte emerges as the most immediately useful solution, furnishing smooth, bright deposits of ruthenium up to 0·0002 in thick over a fairly wide range of operating conditions.
J. C. Blake, F. H. Reid
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Epitaxial graphene on ruthenium
Nature Materials, 2008Graphene has been used to explore the fascinating electronic properties of ideal two-dimensional carbon, and shows great promise for quantum device architectures. The primary method for isolating graphene, micromechanical cleavage of graphite, is difficult to scale up for applications.
Eli Sutter, Jan Ingo Flege, Peter Sutter
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Electrodeposition of Ruthenium
Transactions of the IMF, 1969SummaryA new electrolyte has been developed for the electrodeposition of ruthenium. Deposits are bright at cathode current efficiencies up to 100%, the bath is stable in operation and has a useful working life, expressed as total deposit weight, of over 50 g ruthenium per litre of electrolyte.
Gadhireddy Satyanarayan Reddy +1 more
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Nature, 1984
Ruthenium, one of the rarest metals of the platinum group, has not previously been investigated in ocean waters and sediments because of its low concentration therein and the lack of sensitive analytical methods. However, the study of ruthenium distribution in the ocean is of interest not only in oceanology but also in geology, geochemistry and ...
V. A. Narseyev +6 more
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Ruthenium, one of the rarest metals of the platinum group, has not previously been investigated in ocean waters and sediments because of its low concentration therein and the lack of sensitive analytical methods. However, the study of ruthenium distribution in the ocean is of interest not only in oceanology but also in geology, geochemistry and ...
V. A. Narseyev +6 more
openaire +2 more sources