Instability of Amorphous Ru-Si-O Thin Films under Thermal Oxidation [PDF]
Ternary films about 200 nm thick of composition Ru20Si15O65 have been synthesized by reactive rf magnetron sputtering of a Ru1Si1 target in an argon-oxygen gas. As-deposited, the films are X-ray-amorphous.
Gasser, S. M. +3 more
core +1 more source
Ruthenium polypyridyl complexes and their modes of interaction with DNA : is there a correlation between these interactions and the antitumor activity of the compounds? [PDF]
Various interaction modes between a group of six ruthenium polypyridyl complexes and DNA have been studied using a number of spectroscopic techniques.
Eva Corral +75 more
core +3 more sources
Double Carbon−Hydrogen Activation of 2-Vinylpyridine: Synthesis of Tri- and Pentanuclear Clusters Containing the μ-NC\u3csub\u3e5\u3c/sub\u3eH\u3csub\u3e4\u3c/sub\u3eCH═C Ligand [PDF]
Reactions of 2-vinylpyridine with the triruthenium complexes [Ru3(CO)12] and [Ru3(CO)10(μ-dppm)] leads to a previously unknown double carbon−hydrogen bond activation of the β-carbon of the vinyl group to afford the pentaruthenium and triruthenium ...
Azam, Kazi A. +9 more
core +1 more source
Oxophilic Ce single atoms-triggered active sites reverse for superior alkaline hydrogen evolution
The state-of-the-art alkaline hydrogen evolution catalyst of united ruthenium single atoms and small ruthenium nanoparticles has sparked considerable research interest.
Fengyi Shen +12 more
doaj +1 more source
Chemical Vapour Deposition of Amorphous Ru(P) Thin Films from Ru Trialkylphosphite Hydride Complexes [PDF]
The ruthenium phosphite hydride complexes H2Ru(P(OR)(3))(4) (R = Me (1), Et (2), Pr-i (3)) were used as CVD precursors for the deposition of films of amorphous ruthenium-phosphorus alloys.
Anderson, Lauren J. D. +3 more
core +1 more source
Synthesis of Active Carbon and Ruthenium Oxide for Electrochemical Performance
Amorphous hydrous active carbon and ruthenium oxide composite electrodes were prepared. Amorphous hydrous Ruthenium oxide was formed by a sol-gel process. In this paper, some different proportions of composite electrodes were fabricated with the RuO2 and
Kai Wang, Liwei Li, Xinzhen Wu
doaj +1 more source
Ruthenium-Based Photoactivated Chemotherapy
Ruthenium(II) polypyridyl complexes form a vast family of molecules characterized by their finely tuned photochemical and photophysical properties. Their ability to undergo excited-state deactivation via photosubstitution reactions makes them quite unique in inorganic photochemistry.
openaire +3 more sources
Conformational control of anticancer activity: the application of arene-linked dinuclear ruthenium(II) organometallics [PDF]
Dinuclear metal complexes have emerged as a promising class of biologically active compounds which possess unique anticancer activity. Here, we describe a novel series of arene-linked dinuclear organometallic Ru(II) complexes, where the relative ...
Dyson, Paul J. +3 more
core +2 more sources
SYNTHESIS AND CHARACTERIZATION OF FULLERENE-PYRIDYL ARENE RUTHENIUM COMPLEXES
Association of [60]fullerene with arene ruthenium moieties has been achieved for the first time. Two fullerenopyrrolidine derivatives (Npyr-C60) were synthesized via a 1,3-dipolar cycloaddition, and coordinated to arene ruthenium complexes to form two ...
Divambal APPAVOO +2 more
doaj
Energy-efficient CO2 hydrogenation with fast response using photoexcitation of CO2 adsorbed on metal catalysts. [PDF]
Many heterogeneous catalytic reactions occur at high temperatures, which may cause large energy costs, poor safety, and thermal degradation of catalysts.
Hyeon, Seokwon +6 more
core +1 more source

