Results 121 to 130 of about 428,674 (286)

Predicting the Reactivity of Acyclic Silylenes and Germylenes in Hydrogen Activation Using Machine Learning

Advanced Science, EarlyView.
Statistical models for the prediction of the energy profile of H2 activation by silylenes and germylenes were developed. A simple model based on increments of the elements in α‐position enabled robust energy prediction, extrapolation to new structures, and transferability to new tetrylenes and substrates.
Michelle Kleinhaus, Henning Remm, Prasenjit Palui, Alexander Linke, Viktoria H. Gessner   +4 more
wiley   +1 more source

Decomposition Pathways of Z-Selective Ruthenium Metathesis Catalysts

, 2016
The decomposition of a Z-selective ruthenium metathesis catalyst and structurally similar analogues has been investigated utilizing X-ray crystallography and density functional theory.
Peng Liu (120506), Myles B. Herbert (1580422), Robert H. Grubbs (1318044), Yu Lan (132241), Benjamin K. Keitz (1837204), K. N. Houk (1247004), Koji Endo (1908718), Michael W. Day (1873888)   +7 more
core   +2 more sources

EXAFS STRUCTURAL STUDIES OF AROMATIC POLYMERS/RUTHENIUM CATALYSTS

, 1986
The coordination of ruthenium in polystyrene/ruthenium catalysts has been studied by EXAFS. Ru atoms result complexed to the phenyl rings and tend to group in small clusters. The extent of the clustering depends on the Ru concentration and grows when the
P. PERTICI, F. ROCCA, E. BURATTINI, P. FORNASINI, G. DALBA   +4 more
core   +1 more source

Controlled Atom Transfer Radical Depolymerization

Advanced Science, EarlyView.
Controlled atom transfer radical depolymerization allows for precise, uniform shortening of polymer chains to yield monomers on demand. By tuning catalyst concentration and temperature, this strategy prioritizes deactivation to maintain molecular weight control throughout depolymerization.
Dimitra Mantzara, Richard Whitfield, Glen R. Jones, Nghia P. Truong, Athina Anastasaki   +4 more
wiley   +1 more source

An ATP7A‐Mediated Endogenous Regulation Bio‐Clay Enzyme Enables Self‐Amplified Copper Accumulation for Immunogenic Pyrop

Advanced Science, EarlyView.
A self‐amplifying bio‐clay nanozyme (Bio‐Clayzyme) disrupts tumor metabolic homeostasis through endogenous copper transporter ATPase (ATP7A) downregulation, enhancing cascade catalysis and triggering immunogenic pyroptosis for effective tumor immunotherapy.
Weimin Xie, Yan Li, Guangyao Li, Ying Chen, Huaming Yang   +4 more
wiley   +1 more source

Osmium Nanoparticle Anchoring on CoFe Layered Double Hydroxides Enables High‐Valent Species Stabilization and Efficient Seawater Oxygen Evolution

Advanced Science, EarlyView.
Osmium nanoparticles anchored on CoFe layered double hydroxide (Os/CoFe LDH) stabilize high‐valent Co/Fe species and modulate the interfacial water configuration via surface engineering. This work presents a facile surface engineering strategy for constructing efficient and durable OER electrocatalysts for alkaline seawater, and expands the ...
Xindong She, Guosheng Zhou, Kanghua Miao, Junjie Gong, Mingzhe Jiang, Xueting Zhu, Zhenzhen Wang, Shijie Shen, Wenwu Zhong   +8 more
wiley   +1 more source

Engineering an Artificial Metalloenzyme for Efficient Photo‐Enzymatic CO2 Conversion

Advanced Science, EarlyView.
We built a light‐driven artificial metalloenzyme by covalently conjugating formate dehydrogenase (FDH) with a tailored rhodium complex (Rh‐L6) to overcome spatial‐separation‐limited electron transfer. This integration boosts NADH regeneration and CO2 conversion, giving 2.31‐fold higher formate yield than physical mixtures, due to a narrowed bandgap and
Mengxue Kang, Yan Chu, Zhichun Xu, Jiao Feng, Ganlu Li, Kequan Chen, Hui Li   +6 more
wiley   +1 more source

Bimetallic ZIF-Derived Co/N-Codoped Porous Carbon Supported Ruthenium Catalysts for Highly Efficient Hydrogen Evolution Reaction. [PDF]

Nanomaterials (Basel), 2021
Qi H, Guan X, Lei G, Zhao M, He H, Li K, Zhang G, Zhang F, Fan X, Peng W, Li Y.   +10 more
europepmc   +1 more source

A ROS‐Responsive and Mucoadhesive Thermosensitive Hydrogel Encapsulated with Mizoribine for Synergistic Dry Eye Therapy

Advanced Science, EarlyView.
The ROS‐responsive in situ thermosensitive MZR@SPPP hydrogel system enables dual‐stage drug loading and sustained ocular delivery. Upon administration, it gelates at ocular surface temperature, enhancing ocular adhesion. By scavenging free radicals, restoring NRF2‐mediated antioxidant defense and mitochondrial homeostasis, and suppressing inflammatory ...
Danyi Qin, Jiani Li, Panqin Ma, Shinan Wu, Wenying Guan, Yimin Huang, Ke Feng, Mingyan Wei, Zixuan Yang, Shujia Guo, Caihong Huang, Yun‐Long Wu, Yi Han, Zuguo Liu   +13 more
wiley   +1 more source

Magnetic‐Field‐Tuned Spin‐Dependent D‐Band and Bifunctionality in L10‐FeCoPt for Enhanced Methanol Oxidation

Advanced Science, EarlyView.
The d‐band center and bifunctional mechanism jointly regulate the amounts of adsorbed OH* and CO*, thereby enhancing electrocatalytic performance, while the application of an external magnetic field further boosts this performance. ABSTRACT The spin‐dependent electronic structure of transition‐metal alloys plays a key role in tuning the magnetic‐field ...
Qiqi Mo, Kaijie Liu, Ruixi Liu, Yong Juan, Sihan Wang, Jialong Liu, Wei Wang   +6 more
wiley   +1 more source