Results 141 to 150 of about 428,674 (286)
An Engineered Supramolecular Pathway for Enhanced Electrochemiluminescence
Advanced Science, EarlyView.A supramolecular electrochemiluminescent (ECL) system is presented in which cucurbit[7]uril (CB7) is covalently linked to [Ru(bpy)3]2+, forming a recognition‐responsive emitter. Host‒guest preorganization of tri‐n‐propylamine enables intramolecular ECL, boosting intensity by 162% compared to the standard system.
Maria Vittoria Balli +7 more
wiley +1 more source
Advanced Science, EarlyView.A charge‐transfer‐engineered Ni catalyst derived from an atomically mixed layered precursor enables efficient ammonia‐to‐hydrogen conversion. Cr‐to‐Ni electron transfer creates electron‐rich Ni active sites that favor NH3 adsorption, modify the dehydrogenation energetics, and weaken N2 binding to facilitate product desorption. This electronically tuned
Donghyeok Kim +9 more
wiley +1 more source
Ruthenium Catalysts in Regioselective Hydrogenative Metathesis
SynOpen, 2021 Vaezeh Fathi Vavsari
doaj +1 more source
Molecular Rectification: Mechanisms, Modulation Strategies, and Device Realization
Advanced Science, EarlyView.This review focuses on molecular rectification, from its fundamental mechanisms and modulation strategies to device realization. It summarizes the theoretical framework, modulation strategies, fabrication techniques, characterization methods, and modeling and simulation of molecular rectifiers, while discussing challenges and future directions for ...
Junnan Guo +8 more
wiley +1 more source
Chemical Engineering TransactionsAmmonia cracking is a promising method for carbon-free hydrogen production, crucial for sustainable energy applications. This study investigates the catalytic performance of two commercially available catalysts—ruthenium-based (3% wt.
Chiara Anfosso +3 more
doaj
AI‐EXAFS: Physics‐Informed Prediction of EXAFS from Atomic Structure
Advanced Science, EarlyView.AI‐EXAFS presents a neural network to reproduce EXAFS. Trained on synthetic data and with a careful selection of the settings both for the physical representation of the system and following the experimental heuristic loss functions, the model is capable of reproducing EXAFS spectra for molecules from the tridimensional structure.
Javier Heras‐Domingo +6 more
wiley +1 more source
Effect of support acidity during selective hydrogenolysis of glycerol over supported palladium-ruthenium catalysts. [PDF]
Philos Trans A Math Phys Eng Sci, 2020 Guadix-Montero S +3 more
europepmc +1 more source
High‐Density‐Cluster Ru Catalyst Substitute for Pt/C Benchmark Improves Membrane Water Electrolysis
Advanced Science, EarlyView.Yuan et al. report a high‐density, monodispersed Ru cluster catalyst featuring interfacial covalent bonds that modulate the electronic structure and optimize intermediate adsorption–desorption, thereby conferring pH‐universal HER activity with ampere‐level current densities and enabling the development of Pt‐free membrane electrodes.
Zhen Yuan +7 more
wiley +1 more source
Hydrogen Production from Ammonia Electrochemical Cracking
Advanced Science, EarlyView.NH3 electrochemical cracking (e‐cracking) is a complementary technique to centralized thermal cracking for releasing H2 from NH3. In this article, we review recent advances in catalyst development for these cracking techniques and conduct a techno‐economic analysis (TEA) to evaluate the economic feasibility of e‐cracking.
Yike Ye +4 more
wiley +1 more source
Advanced Science, EarlyView.This Review shows how cerium oxide helps water‐splitting catalysts work better and last longer. It explains how CeO2 tunes electronic structure, oxygen‐vacancy behavior, and surface reconstruction, while adapting to alkaline, acidic, and seawater conditions.
Zhen Cui +9 more
wiley +1 more source