Results 101 to 110 of about 56,849 (307)

Stabilizing Electrochemical Interfaces With Multifunctional Cobalt Nitride Layers

open access: yesAdvanced Materials Interfaces, EarlyView.
Cobalt nitrides emerged recently as an interesting class of earth‐abundant oxygen evolution catalysts. Herein, plasma‐enhanced atomic layer deposition is used to synthesize multifunctional cobalt nitride layers that simultaneously protect and catalytically activate photoelectrode surfaces.
Matthias Kuhl   +7 more
wiley   +1 more source

Probing ground and excited state properties of ruthenium (II) and osmium (II) polypyridyl complexes [PDF]

open access: yes, 2002
The area of ruthenium(H) and osmium(H) polypyridyl chemistry has been the subject of intense investigation over the last half century. In chapter 1, topics relevant to the studies presented in this thesis are introduced.
Browne, Wesley R.
core  

Sensitive and Spatially‐Resolved Electrochemiluminescence via Micropatterning

open access: yesAdvanced Materials Interfaces, EarlyView.
The use of a simple silica nanoparticle surface coating and patterning process can transform ordinary gold electrodes into multiplexed ECL sensing electrodes. Through spatially confined droplet formation and local ECL emission, it is possible to perform multiple analyses simultaneously from individual locations as well as intensify the ECL signal by as
Yuliang Shao   +12 more
wiley   +1 more source

Heteroleptic Complexes of Ruthenium Nitrosyl with Pyridine and Bypiridine—Synthesis and Photoisomerization

open access: yesMolecules
The reaction of [RuNO(Py)2Cl2OH] with bipyridine in water–ethanol media results in trans-(NO, OH)-[RuNO(Py)(Bpy)ClOH]+ with an acceptable yield (60–70%) as hexafluorophosphate salt.
Anastasiya O. Brovko   +3 more
doaj   +1 more source

Light Switchable Ionic Conductivity of Arylazopyrazole Modified Polysiloxanes

open access: yesAdvanced Materials Technologies, EarlyView.
We present a polysiloxane functionalized with a novel arylazopyrazole dye that undergoes reversible photoisomerization. Upon lithium bis(trifluoromethanesulfonyl)imide addition and UV irradiation, the polymer exhibits a shift in tan(d) toward higher frequencies and enhanced ionic conductivity.
Malte S. Beccard   +7 more
wiley   +1 more source

Shaping Carbon Nitrides for Advanced Macrostructures

open access: yesAdvanced Materials Technologies, EarlyView.
This review examines how carbon nitride can be shaped through a range of printing and interfacial assembly methods. By bringing together additive manufacturing and liquid–liquid structuring concepts, carbon nitride is moving beyond its traditional powder‐based photocatalyst form toward digitally designed robust macroscale architectures with high design
Simona Baluchová, Baris Kumru
wiley   +1 more source

Recent Developments in Energy Storage and Conversion Applications of Multifunctional Vanadium Carbides

open access: yesAdvanced Materials Technologies, EarlyView.
This review systematically explains the synthesis, properties, and energy storage and conversion applications of vanadium carbides. We introduce the structural and the synthetic strategies and reviewed recent developments in the material synthesis processes. The emerging applications of vanadium carbides in energy storage and conversion are highlighted.
Swathy B. Saseendran   +2 more
wiley   +1 more source

Ruthenium-Catalyzed Cyclopropanation of Alkenes Using Propargylic Carboxylates as Precursors of Vinylcarbenoids

open access: yes, 2016
Intermolecular cyclopropanation reactions of various alkenes with propargylic carboxylates 1 are catalyzed by [RuCl2(CO)3]2 to give vinylcyclopropanes 2 in good yields.
Kouichi Ohe (1470874)   +2 more
core   +3 more sources

Chlorido{2-[(4-chlorophenyl)iminomethyl]pyridine-κ2N,N′}(η6-toluene)ruthenium(II) hexafluoridophosphate

open access: yesIUCrData
The asymmetric unit of the title compound, [RuCl(C7H8)(C12H9ClN2)]PF6, contains two cationic ruthenium(II) complexes and two [PF6]− anions. One of the anions exhibits disorder over two positions.
Joel Gichumbi   +2 more
doaj   +1 more source

Thickness‐Dependent Infrared Emissivity of Ultrathin Freestanding MoSiN Nanocomposite Membranes

open access: yesAdvanced Optical Materials, EarlyView.
ABSTRACT Metals and dielectrics show opposite trends in thickness‐dependent infrared emissivity: metallic films exhibit a rise in emissivity below a critical thickness, while dielectric films show a corresponding decline. For applications demanding both high emissivity and mechanical strength in membranes with nanoscale thickness, combining these ...
Reethu Sebastian   +3 more
wiley   +1 more source

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