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Cyclopentadienyl-ruthenium complexes
Journal of Organometallic Chemistry, 1981Abstract Several ruthenium complexes of the CpRuX(PPh3)2 type, where X = Cl, Br, I, NCS, NCO, CN, BH4, H, D, and some of the CpRuS2CZ(PPh3) type, where Z = NR2 or OR, were obtained. The hydride CpRuH(PPh3)2 was obtained in high yield by reaction of CpRuCl(PPh3)2 with ROM (R = alkyl, M = alkali metal).
Tadeusz Wilczewski +2 more
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Electroluminescence in Ruthenium(II) Complexes
Journal of the American Chemical Society, 2002We have investigated the electrochemical, spectroscopic, and electroluminescent properties of a family of diimine complexes of Ru featuring various aliphatic side chains as well as a more extended pi-conjugated system. The performance of solid-state electroluminescent devices fabricated from these complexes using indium tin oxide (ITO) and gold ...
Stefan, Bernhard +6 more
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Tethered Arene Complexes of Ruthenium
ChemInform, 2003AbstractFor Abstract see ChemInform Abstract in Full Text.
Martin A. Bennett, Joanner R. Harper
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Making Oxygen with Ruthenium Complexes
Accounts of Chemical Research, 2009Mastering the production of solar fuels by artificial photosynthesis would be a considerable feat, either by water splitting into hydrogen and oxygen or reduction of CO(2) to methanol or hydrocarbons: 2H(2)O + 4hnu --> O(2) + 2H(2); 2H(2)O + CO(2) + 8hnu --> 2O(2) + CH(4).
Javier J, Concepcion +7 more
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Polypyrazolylmethane complexes of ruthenium
Journal of the Chemical Society, Dalton Transactions, 2001A series of ruthenium(II) complexes with the pyrazolyl alkane ligands tris(1-pyrazolyl)methane 1 (TPM) and bis(1-pyrazolyl)methane 2 (BPM) have been synthesized and characterised. The complex [RuCl(PPh3)2(TPM)]+X (X = Cl 3a or BF43b) was formed by the reaction of TPM with RuCl2(PPh3)3 and [Ru(CO)H(PPh3)(TPM)]+X (X = Cl 4a or BF44b) by the reaction of ...
Leslie D. Field +4 more
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The Microbiology of Ruthenium Complexes
2017Ruthenium is seldom mentioned in microbiology texts, due to the fact that this metal has no known, essential roles in biological systems, nor is it generally considered toxic. Since the fortuitous discovery of cisplatin, first as an antimicrobial agent and then later employed widely as an anticancer agent, complexes of other platinum group metals, such
Southam, HM +3 more
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Cyclopentadienyl ruthenium alkynyldithiocarboxylate complexes
Journal of Organometallic Chemistry, 2006Abstract Treatment of the ruthenium chloride, CpRu(PPh3)2Cl, with the alkynyldithiocarboxylate anions, RC CCS 2 - , in refluxing THF affords the chelate complexes CpRu(PPh3)(κ2S,S-S2CC CR) (1) (R = But (a), Bun (b), Ph (c), SiMe3 (d)) in high yield.
Mohammad El-khateeb +2 more
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ChemInform Abstract: Sulfato Complexes of Ruthenium with a Ruthenium‐Ruthenium Bond.
ChemInform, 1989AbstractThe ruthenium complexes (IV) are prepared as shown in the scheme.
A. N. ZHILYAEV +4 more
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Cyclopentadienyl-ruthenium and -osmium complexes
Journal of Organometallic Chemistry, 1982Abstract Ruthenium and osmium complexes of the type CpMX(PPh 3 )L (M = Ru; X = Cl, H, S 2 COC 10 H 19 , S 2 COMe; L & PPh 3 and PHPh 2 ; M = Os, X = Cl, Br, I, H, D, xanthogenate, dithiocarbamate, BPh 4 , L = PPh 3 ). The compound CpOsCl(PPh 3 ) 2 is readily soluble in MeOH and in the solution the cation [CpOs(PPh 3 ) 2 ] + is present.
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Electrochemiluminescence: Ruthenium Complexes
2000Electrochemiluminescence (ECL) is the generation of emitting excited Principle and states from electron transfer reactions of species that are generated electro-applications chemically at the surface of an electrode on application of applied potentials (Faulkner and Bard, 1977). These reactions have been the subject of theoretical study for a number of
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