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Interplanar Potential Difference‐Mediated Efficient Charge Separation in SrLi2Ti6O14 Towards Optimized Photocatalytic Hydrogen Evolution

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
The periodic quantum well formed by alternative stacking of SrO and LTO layers facilitates efficient photoinduced charge separation and thus significantly improves its photocatalytic hydrogen production performance. SrLi2Ti6O14 porous microspheres (SLTO PMSs) and SrLi2Ti6O14/TiO2 hollow sphere heterojunctions (SLTO/TiO2 HSs) are fabricated via ...
Nan Zhao +6 more
wiley +1 more source

Single Atom‐Modified TiO2‐Based Catalysts for Photoelectrochemical Water Splitting: From Fundamentals to Future Prospects

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Hydrogen and oxygen generated from water splitting process by photoelectrocatalysis of single atom modified TiO2 based photoelectrocatalysts. The accelerating demand for green hydrogen has intensified the development of efficient and durable photoelectrocatalysts (PECs) for sustainable water splitting.
Zichu Zhao, Cheryl Suwen Law, Abel Santos +2 more
wiley +1 more source

Growth of water-insoluble rutile GeO2 thin films on (001) TiO2 substrates with graded Ge x Sn1−x O2 buffer layers

Applied Physics Express
Rutile GeO _2 (r-GeO _2 ) is an ultrawide bandgap semiconductor with the potential for ambipolar doping and bulk single-crystal growth. In this study, we investigated r-GeO _2 thin films grown on (001) TiO _2 substrates with graded Ge _x Sn _1− _x O _2 ...
Kazuki Shimazoe, Temma Ogawa, Hiroyuki Nishinaka +2 more
doaj +1 more source

Elementary Steps of Energy Conversion in Strongly Correlated Systems: Beyond Single Quasiparticles and Rigid Bands

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
This article reviews the fundamental consequences of strong correlations on excitations and elementary steps of energy conversion leading to new opportunities to control energy conversion. Examples include friction at surfaces, thermal transport, and photovoltaic energy conversion.
Vasily Moshnyaga +14 more
wiley +1 more source

Nanocubes and Cuboctahedra: Entropic Stabilization Versus Thermal Segregation in Rock Salt‐ and Spinel‐Type Multinary Oxides from Spray‐Flame Synthesis

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Spray‐flame synthesis enables highly flexible and scalable production of multinary and high‐entropy oxide nanoparticles due to high synthesis temperatures with subsequent quenching. Temperature‐dependent in situ diffraction of as‐synthesized materials clearly reveals entropy stabilization in rock salt lattices, while spinels—featuring tetrahedral and ...
Mohammed‐Ali Sheikh +7 more
wiley +1 more source

Toward a Paradigm Shift in Low‐Temperature SCR Catalyst Design: Defect Engineering and Data‐Driven Integration

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
This work systematically reviews the key factors influencing the performance of low‐temperature NH3‐SCR. The mechanism and challenges of defect engineering strategies, such as oxygen vacancies, heteroatom doping, crystal facet exposure, and surface reconstruction, in controlling both activity and selectivity were analyzed.
Rongrong Kan, Pinjing He, Fan Lü, Hua Zhang +3 more
wiley +1 more source

Origin of Physicochemical and Mechanical Stability of Low‐Temperature Prepared TiO2‐Based Photocatalytic Films: Surface Hydroxyl Density Matching

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Material science advances show how surface chemistry improves low‐temperature prepared TiO2‐SiO2 composite films. Using a colloidal‐based synthesis method instead of a powdered‐based one, researchers exploit hydroxyl groups' interfacial interactions to create nanoscale structures with superior physicochemical and mechanical stability.
Andraž Šuligoj +7 more
wiley +1 more source

Large Igneous Provinces (LIPs) and Anoxia Events in “The Boring Billion”

Geophysical Monograph Series, Page 449-486., 2021

Exploring the links between Large Igneous Provinces and dramatic environmental impact

An emerging consensus suggests that Large Igneous Provinces (LIPs) and Silicic LIPs (SLIPs) are a significant driver of dramatic global environmental and biological changes, including mass extinctions.
Shuan‐Hong Zhang +4 more
wiley

+1 more source

Revealing Structure–Performance Relations in Core‐Shell Catalyst‐Based PEM Water Electrolyzer Anodes with Low Iridium Loading

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Table of Contents The TiO2@IrO2 core–shell architecture ensures high electronic conductivity even at a low iridium content of 10 wt%. The resulting catalyst layer shows significantly higher iridium utilization than a commercial reference, leading to improved PEMWE single‐cell performance at low iridium loading.
Selina Finger +16 more
wiley +1 more source

Integrated Solvent‐Catalyst‐Dopant Strategy via Acidic DES for Synthesizing Lignin‐Derived Carbon Dots With High‐Quantum Yield to Achieve Efficient Photocatalytic Degradation of Tetracycline

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
A deep eutectic solvent (ChCl/pTSA) platform enables integrated solvent, catalyst, and dopant functions, producing sulfur‐doped carbon quantum dots with a high sp2‐C content (82.8%) and a quantum yield of 56.9%. When combined with TiO2, the CQDs form TiOC and TiOS interfacial bridges, achieving 97.3% tetracycline photodegradation with excellent ...
Xinhang Li +4 more
wiley +1 more source

anatase
titanium dioxide
photocatalyst

tio2
zircon
photocatalysis

ilmenite
titania