Results 111 to 120 of about 38,933 (302)

Transition Metal Compounds as Thermochromic Materials: Classification, Properties, Limitations, and Applications

open access: yesEcoEnergy, EarlyView.
This review systematically examines how different transition metal compounds—such as binary and multinary metal oxides, halides, sulfides, and salts—exhibit thermochromism based on the d‐electron configurations of their transition metal cations. It focuses on three main mechanisms of thermochromism: phase transition, charge transfer, and bandgap change.
Jie Wang   +5 more
wiley   +1 more source

First-principles study of native defects in rutile TiO2

open access: yes, 2008
Native point defects in the rutile TiO2 are studied via first-principles pseudopotential calculations. Except for the two antisite defects, all the native point defects have low formation energies.
Peng, H, Chinese Acad Sci, Inst Semicond, State Key Lab Superlattices & Microstruct, POB 912, Beijing 100083, Peoples R China. 电子邮箱地址: mypen-cn@semi.ac.cn   +1 more
core  

Co‐Catalyst/Semiconductor Interface Coupling Design for Efficient Solar‐Driven Photocatalysis

open access: yesEcoEnergy, EarlyView.
Interfacial coupling strength is proposed as a unifying descriptor governing charge‐transfer behavior in co‐catalyst/semiconductor photocatalytic systems. This review establishes a coupling‐strength‐guided framework that correlates interface engineering strategies with charge transport pathways, electronic structure regulation, and photocatalytic ...
Fangxu Dai   +7 more
wiley   +1 more source

Metasomatism and Mélange Development at the Conditions of Modern Deep Slow Slip: P‐T‐t Evolution of Metasomatic Rocks (Pimu'nga/Santa Catalina Island, CA)

open access: yesGeochemistry, Geophysics, Geosystems
The subduction interface hosts megathrust earthquakes and ductile creep, is fluid‐rich and chemically dynamic, and produces metasomatic rocks that may host episodic tremor and slow slip (ETS).
W. Hoover   +5 more
doaj   +1 more source

Coupling Selective Organic Oxidation With Hydrogen Evolution Over Metal Halide Perovskite Photocatalysts: Halide‐Dependent Design, Mechanisms, and Stability Challenges

open access: yesEcoEnergy, EarlyView.
This Review highlights how metal halide perovskites enable coupled selective organic oxidation and hydrogen evolution under visible light. It summarizes halide‐dependent design principles, surface engineering strategies, reaction mechanisms, and stability challenges, providing guidance for developing efficient and durable photocatalytic systems ...
Jutarat Jitrada   +4 more
wiley   +1 more source

Breaking the Activity–Stability Scaling in RuO2 via Single‐ and Dual‐Doping Strategies

open access: yesEcoEnergy, EarlyView.
Single and dual heteroatom doping redefines RuO2 for acidic oxygen evolution by synergistically tuning the electronic structure, lattice stability, and reaction pathways. Although single dopants optimize specific catalytic properties, dual dopants overcome the activity–stability trade‐off through cooperative electronic and geometric regulation ...
Ashish Gaur   +4 more
wiley   +1 more source

Lattice and Surface Engineering of Transition Metal Oxide Photoanodes for Efficient Photoelectrochemical Water Splitting

open access: yesEcoEnergy, EarlyView.
This review highlights phase control, facet control, and atomic vacancy engineering as key strategies to enhance charge transport, light harvesting, and surface activity in PEC photoanodes. ABSTRACT Photoelectrochemical (PEC) water splitting is a promising approach for converting solar energy into hydrogen, yet the performance of transition metal oxide
Seonmi Ko   +5 more
wiley   +1 more source

Large Igneous Provinces (LIPs) and Anoxia Events in “The Boring Billion”

open access: yesGeophysical Monograph Series, Page 449-486., 2021

Exploring the links between Large Igneous Provinces and dramatic environmental impact

An emerging consensus suggests that Large Igneous Provinces (LIPs) and Silicic LIPs (SLIPs) are a significant driver of dramatic global environmental and biological changes, including mass extinctions.
Shuan‐Hong Zhang   +4 more
wiley  

+1 more source

Durable Thin‐Film Porous Transport Electrodes for High Current Density PEM Water Electrolysis

open access: yesAdvanced Science
Proton exchange membrane water electrolyzers rely on relatively expensive Ir‐based catalysts for efficient and durable hydrogen production. To reduce system costs, Ir loadings can be reduced if performance and durability are maintained.
James L. Young   +18 more
doaj   +1 more source

Nanocubes and Cuboctahedra: Entropic Stabilization Versus Thermal Segregation in Rock Salt‐ and Spinel‐Type Multinary Oxides from Spray‐Flame Synthesis

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Spray‐flame synthesis enables highly flexible and scalable production of multinary and high‐entropy oxide nanoparticles due to high synthesis temperatures with subsequent quenching. Temperature‐dependent in situ diffraction of as‐synthesized materials clearly reveals entropy stabilization in rock salt lattices, while spinels—featuring tetrahedral and ...
Mohammed‐Ali Sheikh   +7 more
wiley   +1 more source

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