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Study of the Possibility of Using Salt Metathesis Reactions for the Synthesis of the Neodymium and Samarium β-Diketiminate Chalcogenide Complexes. Unexpected Reduction of Sm(III) to Sm(II)

Russian Journal of Coordination Chemistry, 2020
The possibilities of the ion exchange reactions between the neodymium(III) and samarium(III) diiodo-β-diketiminate complexes [Ln(Nacnac)I2(Тhf)2] (Ln = Nd (I), Sm (II); Nacnac is HC$$\left\{ {{\text{C}}\left( {{\text{Me}}} \right){\text{N}}\left( {{\text{2}},{\text{6}} - {{{\text{C}}}_{{\text{6}}}}{\text{H}}_{{\text{4}}}^{i}{\text{P}}{{{\text{r}}}_ ...
O. A. Mironova   +3 more
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Imidazolium‐Salt‐Functionalized Ionic‐CNT‐Supported RuCarbene/Palladium Nanoparticles for Recyclable Tandem Metathesis/Hydrogenation Reactions in Ionic Liquids

Chemistry – An Asian Journal, 2013
NP and tuck: Two different catalysts, a Ru-carbene complex and palladium nanoparticles, were immobilized onto the same imidazolium-salt-functionalized ionic CNTs. These supported dual-function catalysts showed excellent catalytic activity in tandem metathesis/hydrogenation reactions in an ionic liquid and could be recovered and reused four times. RCM =
Sujin, Lee, Ju Yeon, Shin, Sang-gi, Lee
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ChemInform Abstract: Ring‐Closing Metathesis Reactions on Azinium Salts: Straightforward Access to Quinolizinium Cations and Their Dihydro Derivatives.

ChemInform, 2009
AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
Ana Nunez   +4 more
openaire   +1 more source

ChemInform Abstract: Imidazolium‐Salt‐Functionalized Ionic‐CNT‐Supported Ru—Carbene/Palladium Nanoparticles for Recyclable Tandem Metathesis/Hydrogenation Reactions in Ionic Liquids.

ChemInform, 2014
AbstractRuthenium carbene and palladium nanoparticles are immobilized onto the same imidazolium‐functionalized ionic carbon nanotubes and the catalyst is showing high effectivity in tandem metathesis/hydrogenation reaction in an ionic liquid.
Sujin Lee, Ju Yeon Shin, Sang‐gi Lee
openaire   +1 more source

ChemInform Abstract: CHEMISTRY OF REACTIVE CATIONS DERIVED FROM SULFUR DIOXIDE ANALOGS. PART VIII. MINOSULFONIUM SALTS BY METATHESIS REACTIONS OF SULFINYL COMPOUNDS TEREOCHEMISTRY FOR CYCLIC DERIVATIVES

Chemischer Informationsdienst, 1982
AbstractAus den stereoisomeren Sulfoxiden (I) entstehen mit der N‐Sulfinyl‐Verbindung (II) die Amino‐sulfoniumsalze (III).
A. + SCHWOEBEL, G. KRESZE, M. A. PEREZ
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Synthesis and reactivity in salt metathesis reactions of trivalent [La(TpMe2)2X] (X=Cl, I) complexes: crystal structures of [La(TpMe2)2Cl] and [La(TpMe2)2(κ2-pzMe2)]

Polyhedron, 2004
Abstract Reaction of LaX3(THF)n (X = Cl, I) with two equiv. of K(TpMe2) gave good yields of the bis-Tp complexes [La(TpMe2)2X] (X = Cl (1); I (3)). However, the formation of 1 and 3 is always accompanied by significant amounts of La(TpMe2)2(κ2-pzMe2) ([pzMe2]− = 3,5-dimethyl-pyrazolato) (2).
Kunrath, F. A.   +3 more
openaire   +2 more sources

Salt Metathesis and Direct Reduction Reactions Leading to Group 3 Metal Complexes with a N,N′-Bis(2,6-diisopropylphenyl)-1,4-diaza-1,3-butadiene Ligand and Their Solid-State Structures

Organometallics, 2010
We successfully prepared and characterized a wide variety of group 3 metal complexes containing a dianionic or monoanionic glyoxal-based N,N′-bis(2,6-diisopropylphenyl)-1,4-diaza-1,3-butadiene (DAD) ligand using a salt metathesis reaction of group 3 metal trichlorides with the dipotassium salt of the DAD ligand or a direct reduction of the DAD ligand ...
Tarun K. Panda   +4 more
openaire   +1 more source

Novel reactions of the [BPh4]- salt of the bifunctional complex [(triphos)Rh(S2CO)]+ (triphos = MeC(CH2PPh2)3): one-electron reduction, cleavage of B-H and B-C bonds, and metathesis of CS2-like heteroallene molecules

Inorganic Chemistry, 1989
Etude des proprietes oxydoreductrices du complexe du titre au moyen de la voltammetrie cyclique.
Claudio Bianchini   +4 more
openaire   +1 more source

Reactions of K2[Fe(CO)3(PPh3)]: Reductive Sb−Sb Coupling with Ph2SbCl To Form trans‐[Fe(CO)3(PPh3)(Sb2Ph4)] and Salt Metathesis with Me3SbCl2 To Yield trans‐[Fe(CO)3(PPh3)(SbMe3)]

European Journal of Inorganic Chemistry, 2004
AbstractIn contrast to the ferrate K2[Fe(CO)4], the phosphane‐substituted ferrate K2[Fe(CO)3(PPh3)] (1) reacts with the stibane derivative Ph2SbCl by metal‐assisted reductive Sb−Sb coupling to give the distibane complex trans‐[Fe(CO)3(PPh3)(Sb2Ph4)] (3). The distibane ligand in 3 is terminally η1‐coordinated trans to the phosphane ligand.
Ingo‐Peter Lorenz   +3 more
openaire   +1 more source

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