Results 21 to 30 of about 17,683 (202)

Thermotropic Liquid-Crystalline and Light-Emitting Properties of Bis(4-aalkoxyphenyl) Viologen Bis(triflimide) Salts

open access: yesMolecules, 2020
A series of bis(4-alkoxyphenyl) viologen bis(triflimide) salts with alkoxy chains of different lengths were synthesized by the metathesis reaction of respective bis(4-alkoxyphenyl) viologen dichloride salts, which were in turn prepared from the reaction ...
Pradip K. Bhowmik   +17 more
doaj   +1 more source

Ruthenium Olefin Metathesis Catalysts Bearing Carbohydrate-Based N-Heterocyclic Carbenes [PDF]

open access: yes, 2010
Ru-based olefin metathesis catalysts containing carbohydrate-derived NHCs from glucose and galactose were synthesized and characterized by NMR spectroscopy. 2D-NMR spectroscopy revealed the presence of Ru−C (benzylidene) rotamers at room temperature, and
Grubbs, Robert H., Keitz, Benjamin K.
core   +2 more sources

Poly[1-ethyl-3-methylimidazolium [tri-μ-isothiocyanato-manganate(II)]]

open access: yesIUCrData, 2019
The title compound, {(C9H11N2)[Mn(NCS)3]}n, has been obtained as a side product of the salt metathesis reaction of 1-ethyl-3-methylimidazolium bromide, (EMIm)Br, and K2[Mn(NCS)4]. The structure consists of discrete 1-ethyl-3-methylimidazolium cations and
Tim Peppel, Martin Köckerling
doaj   +1 more source

Holmium(III) Supermesityl-Imide Complexes Bearing Methylaluminato/Gallato Ligands

open access: yesInorganics, 2015
Heterobimetallic µ2-imide complexes [Ho(µ2-Nmes*){Al(CH3)4}]2 (1, supermesityl = mes* = C6H2tBu3-2,4,6) and [Ho(µ2-Nmes*){Ga(CH3)4}]2 (2) have been synthesized from homoleptic complexes Ho[M(CH3)4]3 (M = Al, Ga) via deprotonation of H2Nmes* or with K[NH ...
Dorothea Schädle   +3 more
doaj   +1 more source

Transition metal complexes of the weakly coordinating carborane anion [CB11H12]−: the first isolation and structural characterisation of an intermediate in a silver salt metathesis reaction

open access: yesChemical Communications, 2000
Reaction between CpMo(CO)3I and Ag[CB11H12] eventually affords CpMo(CO)3(η1-CB11H12), via the dimeric compound [CpMo(CO)3I·Ag{CB11H12}] 2 which represents the first structurally characterised intermediate in a silver salt metathesis reaction.
Patmore, N, Steed, J, Weller, A
openaire   +1 more source

Crystal structure of the high-energy-density material guanylurea dipicrylamide

open access: yesActa Crystallographica Section E, 2014
The title compound, 1-carbamoylguanidinium bis(2,4,6-trinitrophenyl)amide [H2NC(=O)NHC(NH2)2]+[N{C6H2(NO2)3-2,4,6}2]− (= guanylurea dipicrylamide), was prepared as dark-red block-like crystals in 70% yield by salt-metathesis reaction between guanylurea ...
Raik Deblitz   +3 more
doaj   +1 more source

Synthesis and Study of Olefin Metathesis Catalysts Supported by Redox-Switchable Diaminocarbene 3 Ferrocenophanes [PDF]

open access: yes, 2013
A redox-switchable ligand, N,N'-dimethyldiaminocarbene[3]ferrocenophane (5), was synthesized and incorporated into a series of Ir- and Ru-based complexes.
Bielawski, Christopher W.   +4 more
core   +1 more source

Synthesis of 7,7,14,14-tetrachlorodinaphtho[1,8bc:1′,8′-fg][1,5]distannocine. Molecular structure of the di-water tetra-THF adduct

open access: yesMain Group Metal Chemistry, 2013
The salt metathesis reaction of 1,8-dilithionaphthalene with tributyltin chloride provided 1,8-bis(tributyltin)naphthalene (1) in 41% yield. The transmetallation of 1 with tin tetrachloride gave rise to the formation of 7,7,14,14-tetrachlorodinaphtho[1 ...
Beckmann Jens, Hupf Emanuel, Lork Enno
doaj   +1 more source

Solid-state metathesis reactions under pressure: A rapid route to crystalline gallium nitride [PDF]

open access: yes, 1998
High pressure chemistry has traditionally involved applying pressure and increasing temperature until conditions become thermodynamically favorable for phase transitions or reactions to occur.
Heath, James R.   +6 more
core   +1 more source

Crystal structure of a salt with a protonated sugar cation and a cobalt(II) complex anion: (GlcN–H, K)[Co(NCS)4]·2H2O

open access: yesIUCrData, 2019
The title compound, d-(+)-glucosammonium potassium tetrathiocyanatocobaltate(II) dihydrate, K(C6H14NO5)[Co(NCS)4]·2H2O or (GlcNH)(K)[Co(NCS)4]·2H2O, has been obtained as a side product of an incomplete salt metathesis reaction of d-(+)-glucosamine ...
Tim Peppel   +3 more
doaj   +1 more source

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