Results 31 to 40 of about 17,314 (301)

THERMODYNAMICS OF THE POINT DEFECTS IN THE METALLIC PHASE OF THE SAMARIUM MONOSULPHIDE

open access: yesJournal of Vasyl Stefanyk Precarpathian National University, 2016
The equilibrial values of the vacancy concentration of chalcogen and antistructural samarium atoms in metallic phase of SmS were calculated by minimization the crystal thermodynamic potential. It was determined that the dominant defects are
I. V. Gorichok   +2 more
doaj   +1 more source

Tripyrrolidinophosphoric acid triamide as an activator in samarium diiodide reductions

open access: yes, 2010
The electrochemical and spectrophotometric characterization of the complex formed from samarium diiodide and 4 equiv of tripyrrolidinophosphoric acid triamide (TPPA) is presented. Kinetic studies indicate that the SmI(2)/TPPA complex possesses reactivity
Ramsey, Jeremy D   +10 more
core   +1 more source

Reductive Samarium Catalysis Enabled By A Thermochemical Roadmap [PDF]

open access: yes
Samarium diiodide is a versatile single-electron reductant. Its reactivity is modulated by recruitment of a wide range of additives to its large coordination sphere. Binding of strong Lewis bases produces more potent Sm(II) reductants, while polar protic
Boyd, Emily A.
core   +1 more source

Particle-Size-Induced Valence Changes in Samarium Clusters [PDF]

open access: yes, 1981
Samarium clusters exhibit mixed-valence behavior which is sensitive to particle size. XPS and UPS data show samarium to be primarily divalent (4f{sup 6} ) at small particle size.
Franciosi, A.   +6 more
core   +1 more source

Reactivity of a Sterical Flexible Pentabenzylcyclopentadienyl Samarocene

open access: yesInorganics, 2022
Reactivity studies of the classical divalent lanthanide compound [CpBz52Sm] (CpBz5 = pentabenzylcyclopentadienyl-anion) towards diphenyl dichalcogenides and d-element carbonyl complexes led to remarkable results.
Niklas Reinfandt, Peter W. Roesky
doaj   +1 more source

Radioactivity of Samarium [PDF]

open access: yesNature, 1935
SEVERAL workers have investigated the radioactivity of samarium, and it is established that this element emits short-range-particles. Mader1 has also reported the existence of a group of particles of range 1.37 cm., which he believes to be protons. To obtain fuller information about these particles, I have introduced samarium sulphate into the emulsion
ERICH REGENER, H. J. TAYLOR
openaire   +1 more source

Synthesis and Properties of Polyaniline Samarium Nanocomposite [PDF]

open access: yes, 2012
209-216The main objective of this investigation is to study the effect of samarium nanoparticles on the optical and electrical transport properties of polyaniline.
Gupta, K, Meikap, A K, Jana, P C
core   +1 more source

Gamma, neutron, and heavy charged ion shielding properties of Er3+-doped and Sm3+-doped zinc borate glasses

open access: yesOpen Chemistry, 2022
This study aimed to investigate the nuclear radiation shielding properties of erbium (Er)-reinforced and samarium (Sm)-reinforced borate glasses. In the 0.015–15 MeV photon energy range, attenuation coefficients, as well as half-value layer tenth-value ...
Tekin Huseyin Ozan   +9 more
doaj   +1 more source

Hydrothermal synthesis, characterization and catalytic performance of La3+ and Sm3+ - doped Bi2Mn2O7 nanocatalysts for Biginelli reactions [PDF]

open access: yesJournal of Nanostructures, 2019
La3+ and Sm3+ - doped Bi2Mn2O7 nanocatalysts were synthesized in 1 M NaOH aqueous solution, via a stoichiometric 1:1 Bi:Mn molar ratio hydrothermal method at 180 °C for 48 h. Bi(NO3)3, MnO2, La(NO3)3 and Sm2O3 were used as raw materials.
Shahin Khademinia, Mahdi Behzad
doaj   +1 more source

Central Nervous System Tumors Among Infants in Canada: A Report From CYP‐C

open access: yesPediatric Blood &Cancer, EarlyView.
ABSTRACT Background Central nervous system (CNS) tumors in infants are rare, pose unique clinical challenges, and lack large‐scale evidence‐based data to guide management. This study seeks to describe CNS tumors in Canadian infants and to compare their outcomes with those of older children.
Samuel Sassine   +17 more
wiley   +1 more source

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