Results 171 to 180 of about 4,881,160 (251)

A Cyclic {NiII8DyIII4} Cluster Where the DyIII Moments Are Organized by the Transition Metal Spins

open access: yesChemistry – A European Journal, EarlyView.
The synthesis, structural characterisation, and magnetic properties of a cyclic Ni8Dy4 coordination cluster are reported. Ab initio CASSCF and DFT calculations help rationalize the shape of the microSQUID hysteresis and the competing magnetic interactions within the compound. ABSTRACT A series of [Ni8Ln4(CO3)4(L)8(NO3)2(H2O)8 (MeOH)4](NO3)2 (Ln = Dy (1)
Imon J. Dutta   +7 more
wiley   +1 more source

Multi‐Scale Investigation of Supramolecular Organogels Assembled From Pt(II)‐Salphen Complexes

open access: yesChemistry – A European Journal, EarlyView.
A family of Pt(II)‐salphen complexes with long alkyl chains is investigated as low‐molecular‐weight organogelators. Multi‐scale characterization of their supramolecular gels reveals how the chain length, Pt‐Pt interactions, and π–π stacking direct self‐assembly and tune gel mechanics.
Pablo Msellem   +7 more
wiley   +1 more source

Large Magnetocaloric Effect in a Ferromagnetically Coupled [Mn3Gd] Complex With a Spin Ground State of S = 11

open access: yesChemistry – A European Journal, EarlyView.
Systematic studies of a series of new 3d–4f tetranuclear complexes revealed that the ferromagnetically coupled [Mn3Gd] complex exhibits large magnetic entropy changes, especially at higher temperatures and under lower magnetic fields. ABSTRACT A series of 3d‐4f heterometallic tetranuclear complexes, (TEA)[Mn3Gd(L)3(NO3)4(CH3CN)2] ([Mn3Gd]), (TEA)[Mn3La(
Takuya Shiga   +6 more
wiley   +1 more source

Turning Bonding Into Function: The Emerging Role of the Bioactive Selenium─Metal Motif in Toxicology and Medicinal Chemistry

open access: yesChemistry – A European Journal, EarlyView.
Balancing Act: Se─M bond serving as the fulcrum of the balance scale to compare the different weight of toxicity and therapeutic effects in biological environment. ABSTRACT The synthesis and characterization of organo‐selenium compounds have attracted considerable interest for decades, driven by the search for efficient catalysts and bioinspired ...
Matteo Filippi   +6 more
wiley   +1 more source

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