Sulfur‐Boron Lewis Pair‐Catalyzed Hydrohalogenation of Alkynes via Formal Hydrogen Atom Transfer
A sulfur‐boron Lewis pair enables the stereodivergent hydrohalogenation of alkynes with exclusive Markovnikov selectivity. Mechanistic studies support a proton transfer‐electron transfer (PT‐ET) sequence for vinyl radical formation rather than a concerted hydrogen atom transfer (HAT) pathway.
Yun Soo Shim +4 more
wiley +2 more sources
A framework for enhancing pharmaceutical integrity and patient safety: novel mobile health solution integrating smart packaging and computer vision. [PDF]
K H, Parikh V, K PS, D S, S RVI.
europepmc +1 more source
KO‐NH2 is a synthetic metallophore that preferentially binds Ga3+ over Fe3+ and is recognized by bacterial transporters. Photocrosslinking identifies CirA and Fiu as key uptake proteins in E. coli. KO‐NH2 enables targeted imaging and treatment of E. coli soft tissue infections.
Phuong Nguyen Tran +5 more
wiley +2 more sources
Delirium in Hospitalized Older Adults: A Narrative Review. [PDF]
Jeyakanthan J +4 more
europepmc +1 more source
Intramolecular chemically induced dimerisation transforms FK506‐ and cyclosporine A‐responsive protein pairs into high‐affinity pseudo‐allosteric switches. Holo‐selective binders isolated by mRNA display convert these switches into gain‐of‐signal biosensors and ultrasensitive ELISAs, enabling direct quantification of both immunosuppressants in ...
Zhenling Cui +15 more
wiley +2 more sources
CSF-net: a color space fusion network with self-attention-driven feature learning for feline ocular diseases classification. [PDF]
S P D, Lee M, Yang HJ.
europepmc +1 more source
Explainable Artificial Intelligence in Dentistry: A Systematic Review of Its Trust and Translation. [PDF]
Thaweesapphithak S +5 more
europepmc +1 more source
Large-scale high-throughput screen for cardiac ryanodine receptor targeted therapeutics. [PDF]
Nikolaienko R +13 more
europepmc +1 more source
Digital workflow with intraoral scanning and CAD/CAM PMMA crowns in a non-cooperative pediatric patient with early childhood caries: a case report. [PDF]
Reytor-González C +5 more
europepmc +1 more source
Glutaredoxins Rapidly Reduce Glutathione Hydroper‐ and Polysulfides
Glutaredoxins (Grx) rapidly reduce glutathione polysulfides (GSSnSG) to glutathione hydroper/polysulfides (GSSnH) or GSSnH to hydrogen (poly)sulfides (H2Sn). Reduction of glutathionylated glutaredoxins by reduced glutathione (GSH) yields glutathione disulfide (GSSG).
Philipp Reinert +6 more
wiley +1 more source

