The negative electron affinity of diamond allows to emit highly reductive electrons. By introducing intra‐bandgap states and an optimized electron transfer mechanism by surface functionalization with Ru(bpy)3, the formation of solvated electrons is achieved upon solar irradiation.
Benjamin Kiendl +20 more
wiley +1 more source
Self‐Refreshing Bi‐Based Active Sites for Efficient and Durable Electrochemical CO2 Reduction
A self‐refreshing Bi‐based catalyst is developed through the fabrication of a novel basic bismuth nitrate pre‐catalyst, which exhibits differential active sites of Bi2O2CO3 at low potentials and metallic Bi phases at high potentials, self‐repairing capability, and thus wide‐potential‐window efficiency and ultralong durability toward electrochemical CO2
Yuxuan Xiao +7 more
wiley +1 more source
M12L24 nanospheres as supramolecular templates for the controlled synthesis of Ir-nanoclusters and their use in the chemo-selective hydrogenation of nitro styrene. [PDF]
Metz LL +8 more
europepmc +1 more source
Fluoride‐Free Adhesives for Low Surface Energy Fluorinated Substrates
A universal, fluoride‐free adhesive achieves a record 4.91 MPa bond strength on PTFE by leveraging amine/amide dipole–dipole interactions, without fluorinated components. This sustainable strategy overcomes the environmental and performance limits of PFAS‐based adhesives, enabling robust, eco‐conscious bonding across diverse materials.
Siqi Zheng +7 more
wiley +1 more source
Solvent-free selective hydrogenation of nitroaromatics to azoxy compounds over Co single atoms decorated on Nb2O5 nanomeshes. [PDF]
Li Z +13 more
europepmc +1 more source
Predicting Atomic Charges in MOFs by Topological Charge Equilibration
An atomic charge prediction method is presented that is able to accurately reproduce ab‐initio‐derived reference charges for a large number of metal–organic frameworks. Based on a topological charge equilibration scheme, static charges that fulfill overall neutrality are quickly generated.
Babak Farhadi Jahromi +2 more
wiley +1 more source
Chiral SURMOFs for Vibrational Circular Dichroism: Multiscale Modeling and Experimental Insights
The use of solid‐state vibrational circular dichroism (VCD) for MOFs is still somewhat unexplored, and in this work, it is shown that chiral surface‐anchored MOFs (SURMOFs) grown on CaF2 provide an excellent platform for VCD. Experimental results are validated through multiscale modeling, showing strong agreement across multiple spectroscopic ...
Ana C. Fingolo +9 more
wiley +1 more source
Highly Efficient and Selective Hydrogenation of Biomass-Derived Furfural Using Interface-Active Rice Husk-Based Porous Carbon-Supported NiCu Alloy Catalysts. [PDF]
Ding Z, Gao Y, Hu L, Yang X.
europepmc +1 more source
Hydrogen Selective Exfoliated Zeolite Membranes
Michael Tsapatsis +6 more
openaire +2 more sources

