Results 191 to 200 of about 8,156 (254)

Metal-Chelating Macroalgal Extract as a Marine Antioxidant for Stabilizing DHA Nanoemulsions. [PDF]

open access: yesAntioxidants (Basel)
Ghelichi S   +6 more
europepmc   +1 more source

1,7‐Digallatetracarborane: Between Nucleophilic closo‐Cluster and “Inverse Sandwich” Digallylene

open access: yesAngewandte Chemie, EarlyView.
A dianionic π‐ligand is used to make a Janus‐type twofold complex with low‐valent gallium Ga(+I). The resulting compound can be seen as and reveals the reactivity of both: a Wade‐type closo‐carborane cluster with nucleophilic Ga‐sites, as well as π‐ligand stabilized Ga(I) atoms in an inverse sandwich compound.
Julijan Sarcevic   +4 more
wiley   +1 more source

Unlocking the Silent Proteome: Chemoselective Asn/Gln Activation for Multidimensional Protein Diversification. [PDF]

open access: yesJ Am Chem Soc
Emenike B   +7 more
europepmc   +1 more source

Enhanced Formation of Dicarboxylic Acids in the Catalytic Oxidation of Polyethylene With O2 and NOx

open access: yesAngewandte Chemie, EarlyView.
The oxidation of polyethylene in the presence of a mixture of O2 and NOx and with Cu2+/V5+ as catalyst yields ∼51 mol% diacids, while retaining ∼80 mol% of the carbon in the oil fraction. The developed method is robust and tolerates several polymer types as well as impurities.
Tom J. Smak   +3 more
wiley   +1 more source

Impact of iron chelation therapy on mitochondrial function, vascular integrity and inflammation in transfusion-dependent myelodysplastic syndromes. [PDF]

open access: yesFront Immunol
García-Delgado R   +8 more
europepmc   +1 more source

Heavier Alkyne‐Ni0 Complexes, [R2E2·Ni] (E = Sn, Pb), Exhibiting σ‐Complex Character

open access: yesAngewandte Chemie, EarlyView.
Using a reductive group elimination strategy, heavier alkyne (LEEL; E = Sn, Pb) complexes of Ni0 are accessed. In contrast to classical alkyne coordination, these systems are best described as σ‐complexes, driven by ligand‐induced constraints and the established poor π‐bonding in heavier alkyne analogues.
Leopold Junge   +3 more
wiley   +1 more source

Matching the Coupling of Valence Electrons in the Oxide Interface to Perturb the Magnetic Order Enhancing Oxygen Reduction in Zinc–Air Batteries

open access: yesAngewandte Chemie, EarlyView.
Sub‐5 nm Fe2O3/Sm2O3 heterojunction nanoparticles are anchored on nitrogen‐doped carbon nanofibers, featuring coupled Fe(3d)‐O(2p)‐Sm(4f) orbitals at the interface. The resulting super‐exchange induces antiparallel magnetic ordering at heterointerfaces, suppressing spin‐dependent interaction between surface OH* species and Fe sites to facilitate OH ...
Jing Li   +9 more
wiley   +1 more source

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